Stability of ultrathin amorphous carbon films deposited on smooth silicon substrates by radio frequency sputtering

2001 ◽  
Vol 89 (4) ◽  
pp. 2422-2433 ◽  
Author(s):  
W. Lu ◽  
K. Komvopoulos ◽  
S. W. Yeh
2008 ◽  
Vol 23 (3) ◽  
pp. 700-703 ◽  
Author(s):  
D. Wan ◽  
K. Komvopoulos

Transmission electron microscopy (TEM) and fast Fourier transformation (FFT) analysis were used to examine the microstructures of amorphous carbon (a-C) films deposited on Si(100) by radio-frequency (rf) sputtering without magnetron. TEM analysis revealed that a-C films synthesized under certain deposition conditions contained randomly dispersed nanocrystallites ∼35 Å in size. FFT results indicated that the nanocrystallites possessed diamondlike cubic structures with their close-packed {111} planes parallel to the film surface. The formation of diamondlike nanocrystallites is attributed to metastable carbon atom clusters of trigonal carbon hybridization that were sputtered off from the graphite target under certain process conditions. Cluster distortion upon deposition onto the growing film surface by the bombarding Ar+ ions promoted tetrahedral carbon atom hybridization and, possibly, epitaxial growth of diamondlike nanocrystallites for a short duration.


2011 ◽  
Vol 47 (10) ◽  
pp. 2732-2734 ◽  
Author(s):  
Caihua Wan ◽  
Xiaozhong Zhang ◽  
Johan Vanacken ◽  
Xili Gao ◽  
Xinyu Tan ◽  
...  

2009 ◽  
Vol 95 (2) ◽  
pp. 022105 ◽  
Author(s):  
Caihua Wan ◽  
Xiaozhong Zhang ◽  
Xin Zhang ◽  
Xili Gao ◽  
Xinyu Tan

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