Magnetic exchange interaction in a pair of orbitally degenerate ions: Magnetic anisotropy of [Ti2Cl9]−3

2001 ◽  
Vol 114 (3) ◽  
pp. 1148-1164 ◽  
Author(s):  
J. J. Borrás-Almenar ◽  
J. M. Clemente-Juan ◽  
E. Coronado ◽  
A. V. Palii ◽  
B. S. Tsukerblat
2016 ◽  
Vol 45 (19) ◽  
pp. 8201-8214 ◽  
Author(s):  
Saurabh Kumar Singh ◽  
Kuduva R. Vignesh ◽  
Velloth Archana ◽  
Gopalan Rajaraman

Density functional calculations have been performed on a series of {ReIV–MII} (M = Mn(1), Fe(2), Co(3), Ni(4), Cu(5)) complexes to compute the magnetic exchange interaction between the ReIV and MII ions, and understand the mechanism of magnetic coupling in this series.


2018 ◽  
Vol 6 (25) ◽  
pp. 6619-6636 ◽  
Author(s):  
Meifang Sun ◽  
Wenbo Mi

The characteristics of organic molecular/ferromagnet spinterfaces are highlighted, including hybrid interface states, magnetic anisotropy, magnetic exchange interaction, etc.


2009 ◽  
Vol 81 (8) ◽  
pp. 1357-1383 ◽  
Author(s):  
Roman Boča ◽  
Ivan Nemec ◽  
Ivan Šalitroš ◽  
Ján Pavlik ◽  
Radovan Herchel ◽  
...  

In the dinuclear and polynuclear metal complexes exhibiting the low-spin (LS) to high-spin (HS) transition, the spin-crossover phenomenon interferes with the magnetic exchange interaction. The latter manifests itself in forming spin-multiplets, which causes a possible overlap of the band originating in different reference spin states (LL, LH, HL, and HH). A series of dinuclear Fe(III) complexes has been prepared; the iron centers are linked by a bidentate bridge (CN-, and diamagnetic metallacyanates {Fe(CN)5(NO)}, {Ni(CN)4}, {Pt(CN)4}, and {Ag(CN)2}). Magnetic measurements confirm that the spin crossover proceeds on the thermal propagation. This information has been completed also by the Mössbauer spectral (MS) data. A theoretical model has been developed that allows a simultaneous fitting of all available experimental data (magnetic susceptibility, magnetization, HS mole fraction) on a common set of parameters.


2000 ◽  
Vol 255 (2-3) ◽  
pp. 223-236 ◽  
Author(s):  
Nikolai Tyutyulkov ◽  
Fritz Dietz ◽  
Klaus Müllen

2016 ◽  
Vol 6 (1) ◽  
Author(s):  
Xiangang Wan ◽  
Hang-Chen Ding ◽  
Sergey Y. Savrasov ◽  
Chun-Gang Duan

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