Epitaxial thin films of ordered double perovskite Sr2FeMoO6

1999 ◽  
Vol 74 (15) ◽  
pp. 2215-2217 ◽  
Author(s):  
Takashi Manako ◽  
Makoto Izumi ◽  
Yoshinori Konishi ◽  
Kei-Ichiro Kobayashi ◽  
Masashi Kawasaki ◽  
...  
2010 ◽  
Vol 97 (7) ◽  
pp. 072511 ◽  
Author(s):  
S. Kazan ◽  
F. A. Mikailzade ◽  
M. Özdemir ◽  
B. Aktaş ◽  
B. Rameev ◽  
...  

2020 ◽  
Vol 26 (42) ◽  
pp. 9338-9347 ◽  
Author(s):  
Hailin Wang ◽  
Carlos Frontera ◽  
Javier Herrero‐Martín ◽  
Alberto Pomar ◽  
Pere Roura ◽  
...  

2009 ◽  
Vol 105 (6) ◽  
pp. 061621 ◽  
Author(s):  
Riad Nechache ◽  
Catalin Harnagea ◽  
Louis-Philippe Carignan ◽  
Olivier Gautreau ◽  
Lucian Pintilie ◽  
...  

2007 ◽  
Vol 22 (8) ◽  
pp. 2102-2110 ◽  
Author(s):  
Riad Nechache ◽  
Louis-Philippe Carignan ◽  
Lina Gunawan ◽  
Catalin Harnagea ◽  
Gianluigi A. Botton ◽  
...  

Epitaxial thin films of Bi2FeCrO6 (BFCO) have been synthesized by pulsed laser deposition on SrRuO3 on (100)- and (111)-oriented SrTiO3 substrates. Detailed x-ray diffraction and cross-section transmission electron microscopy analysis revealed a double perovskite crystal structure of the BFCO epitaxial films very similar to that of BiFeO3 along with a particularly noteworthy Fe3+/Cr3+ cation ordering along the [111] direction. The films contain no detectable magnetic iron oxide impurities and have the correct cationic average stoichiometry throughout their thickness. They however exhibit a slight modulation in the Fe and Cr compositions forming complementary stripe patterns, suggesting minor local excess or depletion of Fe and Cr. The epitaxial BFCO films exhibit good ferroelectric and piezoelectric properties, in addition to magnetic properties at room temperature, as well as an unexpected crystallographic orientation dependence of their room-temperature magnetic properties. Our results qualitatively confirm the predictions made using the ab initio calculations: the double perovskite structure of BFCO films exhibit a Fe3+/Cr3+ cation ordering and good multiferroic properties, along with the unpredicted existence of magnetic ordering at room temperature.


2012 ◽  
Vol 1454 ◽  
pp. 21-26
Author(s):  
Katsutoshi. Sanbou ◽  
Keita. Sakuma ◽  
Tetsuya. Miyawaki ◽  
Kenji. Ueda ◽  
Hidefumi. Asano

ABSTRACTEpitaxial thin films of SrLaVMoO6 with an ordered double perovskite structure have been grown on (001) and (111) SrTiO3 substrates by magnetron sputtering. The optimized (111) film exhibited a clear (111) diffraction peak, which is a superlattice reflection of double perovskite unite cell, indicating clear B-site ordering. Temperature dependences of resistivity ρ show metallic behavior and transition point at 140~150 K, of which behavior is reminiscent of the electrical properties of materials showing long-range magnetic or antiferromagnetic order. XPS results of the Mo 3d core level spectra are discussed in terms of the B-site ordering and oxygen nonstoichiometry.


2006 ◽  
Vol 89 (2) ◽  
pp. 022509 ◽  
Author(s):  
H. Guo ◽  
J. Burgess ◽  
S. Street ◽  
A. Gupta ◽  
T. G. Calvarese ◽  
...  

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4966
Author(s):  
Hailin Wang ◽  
Carlos Frontera ◽  
Benjamín Martínez ◽  
Narcís Mestres

The annealing process is an important step common to epitaxial films prepared by chemical solution deposition methods. It is so because the final microstructure of the films can be severely affected by the precise features of the thermal processing. In this work we analyze the structural and magnetic properties of double perovskite La2CoMnO6 and La2NiMnO6 epitaxial thin films prepared by polymer-assisted deposition (PAD) and crystallized by rapid thermal annealing (RTA). It is found that samples prepared by RTA have similar values of saturation magnetization and Curie temperature to their counterparts prepared by using conventional thermal annealing (CTA) processes, thus indicating low influence of the heating rates on the B-B’ site cationic ordering of the A2BB’O6 double perovskite structure. However, a deeper analysis of the magnetic behavior suggested some differences in the actual microstructure of the films.


2021 ◽  
Vol 207 ◽  
pp. 116683
Author(s):  
Jun Young Lee ◽  
Gopinathan Anoop ◽  
Sanjith Unithrattil ◽  
WooJun Seol ◽  
Youngki Yeo ◽  
...  

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