The First Facile Synthesis of Some 1,2a,3,8b-Tetrahydro-2H-Cyclobuta[c] Chromenes Through Intramolecular Alkylation of an Aromatic Ring by a Cyclobutanone

Synlett ◽  
2002 ◽  
Vol 2002 (05) ◽  
pp. 0796-0798 ◽  
Author(s):  
Angela M. Bernard ◽  
Costantino Floris ◽  
Angelo Frongia ◽  
Pier P. Piras
Keyword(s):  
Aromatic Ring ◽  
Facile Synthesis ◽  
Intramolecular Alkylation

Facile Synthesis of Thiols and Sulfides

1975 ◽  
Vol 53 (10) ◽  
pp. 1480-1483 ◽  
Author(s):  
Jean-Rock Brindle ◽  
Jean-Louis Liard
Keyword(s):  
Aromatic Ring ◽  
Sodium Borohydride ◽  
Facile Synthesis ◽  
Experimental Conditions ◽  
The Stability ◽  
High Yields

Sulfurated sodium borohydride reacts with benzylic halides to give high yields of α-toluenethiol or benzylic polysulfldes depending upon the experimental conditions and the mode of hydrolysis.Aliphatic halides and dibenzylic halides react in the same manner as benzylic halides for a given experimental condition whereas benzylic halides substituted with other groups can be totally or partially reduced depending on the stability of the substituent towards NaBH2S3.Halogens directly attached on the aromatic ring do not react with NaBH2S3.

Studies on intramolecular alkylation. V. Intramolecular alkylation of the aromatic ring in tetrahydronaphthyl diazomethyl ketones

1974 ◽  
Vol 27 (6) ◽  
pp. 1269 ◽  
Author(s):  
DJ Beames ◽  
TR Klose ◽  
LN Mander
Keyword(s):  
Aromatic Ring ◽  
Methyl Ether ◽  
Intramolecular Alkylation ◽  
Acid Catalysed Reactions ◽  
Diazomethyl Ketones

The acid-catalysed reactions in weakly nucleophilic environments of 2-diazoacetyl-l,2,3,4-tetrahydronaphthalene (ll), of 6-diazoacetyl-5,6,7,8-tetrahydro-2-naphthol (2), of 6-diazoacetyl-5,6,7,8- tetrahydro-2-naphthyl methyl ether (3) and its 2,8 and 2,5 isomers (14) and (17), and of 6-diazo- acetyl-5,6,7,8-tetrahydro-6-trifluoroacetoxy-2-naphthyl methyl ether (9) have been studied. Several of the spirocyclohexa-2,5-dienone derivatives prepared thus, (4), (8) and (16), provide potential intermediates or models for the synthesis of tetracyclic diterpenoids.

Heavy Alkali Metal Arenedithiocarboxylates:  A Facile Synthesis, Dimeric Structure, and Nonbonding Interaction between the Metals and Aromatic Ring Carbons

1999 ◽  
Vol 38 (3) ◽  
pp. 496-506 ◽  
Author(s):  
Shinzi Kato ◽  
Nobuyuki Kitaoka ◽  
Osamu Niyomura ◽  
Yuka Kitoh ◽  
Takahiro Kanda ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Aromatic Ring ◽  
Facile Synthesis ◽  
Dimeric Structure ◽  
Nonbonding Interaction

A Facile Synthesis of 5,6-Dihydro-4H-pyrrolo[3,4-d]thiazole and Other Pyrrolidine-Fused Aromatic Ring Systems via One-Step Cyclization from Diols

Heterocycles ◽  
2012 ◽  
Vol 85 (7) ◽  
pp. 1711 ◽  
Author(s):  
Kenji Yoshikawa ◽  
Tsutomu Nagata ◽  
Toshiharu Yoshino ◽  
Noriyasu Haginoya ◽  
Ryo Muto ◽  
...  
Keyword(s):  
Aromatic Ring ◽  
Facile Synthesis ◽  
Ring Systems ◽  
One Step

scholarly journals Atomically thin Pt shells on Au nanoparticle cores: facile synthesis and efficient synergetic catalysis

2016 ◽  
Vol 4 (9) ◽  
pp. 3278-3286 ◽  
Author(s):  
C. Engelbrekt ◽  
N. Šešelj ◽  
R. Poreddy ◽  
A. Riisager ◽  
J. Ulstrup ◽  
...  
Keyword(s):  
Gold Nanoparticles ◽  
Electrochemical Oxidation ◽  
Aromatic Ring ◽  
Au Nanoparticle ◽  
Core Shell ◽  
Facile Synthesis ◽  
One Pot ◽  
Mild Conditions ◽  
The Core ◽  
Thin Platinum

Atomically thin platinum shells on gold nanoparticles (NPs) are synthesized in one pot under mild conditions. The core-shell NPs exhibit excellent catalysis for energy related processes such as electrochemical oxidation of biofuels, aromatic ring hydrogenation, and γ-valerolactone production.

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