Heavy Alkali Metal Arenedithiocarboxylates:  A Facile Synthesis, Dimeric Structure, and Nonbonding Interaction between the Metals and Aromatic Ring Carbons

1999 ◽  
Vol 38 (3) ◽  
pp. 496-506 ◽  
Author(s):  
Shinzi Kato ◽  
Nobuyuki Kitaoka ◽  
Osamu Niyomura ◽  
Yuka Kitoh ◽  
Takahiro Kanda ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Aromatic Ring ◽  
Facile Synthesis ◽  
Dimeric Structure ◽  
Nonbonding Interaction

Facile Synthesis of Thiols and Sulfides

1975 ◽  
Vol 53 (10) ◽  
pp. 1480-1483 ◽  
Author(s):  
Jean-Rock Brindle ◽  
Jean-Louis Liard
Keyword(s):  
Aromatic Ring ◽  
Sodium Borohydride ◽  
Facile Synthesis ◽  
Experimental Conditions ◽  
The Stability ◽  
High Yields

Sulfurated sodium borohydride reacts with benzylic halides to give high yields of α-toluenethiol or benzylic polysulfldes depending upon the experimental conditions and the mode of hydrolysis.Aliphatic halides and dibenzylic halides react in the same manner as benzylic halides for a given experimental condition whereas benzylic halides substituted with other groups can be totally or partially reduced depending on the stability of the substituent towards NaBH2S3.Halogens directly attached on the aromatic ring do not react with NaBH2S3.

Facile Synthesis of Unsolvated Alkali Metal Octahydrotriborate Salts MB 3 H 8 (M=K, Rb, and Cs), Mechanisms of Formation, and the Crystal Structure of KB 3 H 8

2019 ◽  
Vol 131 (9) ◽  
pp. 2746-2750 ◽  
Author(s):  
Xi‐Meng Chen ◽  
Nana Ma ◽  
Xin‐Ran Liu ◽  
Changgeng Wei ◽  
Chong‐Chao Cui ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Alkali Metal ◽  
Facile Synthesis ◽  
Mechanisms Of Formation
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