Influence of rapid thermal nitridation process in N2O ambient on the endurance performance of FLOTOX EEPROM cells

1993 ◽  
Vol 29 (2) ◽  
pp. 242 ◽  
Author(s):  
C. Papadas ◽  
P. Mortini ◽  
G. Ghibaudo ◽  
G. Pananakakis ◽  
F. Pio ◽  
...  
1989 ◽  
Vol 146 ◽  
Author(s):  
J.B. Oude Elferink ◽  
F.H.P.M. Habraken ◽  
W.F. van der Weg

ABSTRACTIn this paper we report on the composition of thermally nitrided silicon dioxide films on silicon. Nitridation temperatures ranging from 950 to 1150ºC and nitridation times ranging from 10 to 240 s were used. The purpose of this study is to reveal the mechanisms involved in the nitridation process with emphasis on the role of hydrogen. From the temperature dependence of the amount of nitrogen in the films the effective activation energy for nitrogen incorporation in this initial stage was deduced.


1994 ◽  
Vol 338 ◽  
Author(s):  
Constantin Papadas ◽  
Patrick Mortini

ABSTRACTThe necessity of employing nitridation process in advanced technologies will be underlined. The different technological alternatives for preparing oxinitride layers will be traced back, followed by a review of the methods currently available for assessing the degradation features of the Si/SiO2 system. Furthermore, comparison between pure SiO2 layers and nitridated films in N2O ambient will be conducted in terms of bulk/interface trapping properties and the obtained physical degradation data will be correlated with classical reliability results. Large emphasis will be given on the trapping properties of tunnel oxides used in non—volatile memory arrays and different technological alternatives will be exploited (i.e. Rapid Thermal Nitridation, Furnace Nitridation). In addition, a similar analysis will be carried out for gate oxides. Finally, some guidelines concerning the optimum selection of the furnace nitridation conditions will be given.


2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
L. A. Díaz ◽  
W. Solís ◽  
P. Peretyagin ◽  
A. Fernández ◽  
M. Morales ◽  
...  

Ceramic Si3N4/TiN (22 vol%) nanocomposites have been obtained by Spark Plasma Sintering (SPS). Our colloidal processing route allows obtaining dispersed nanoparticles of TiN smaller than 50 nm avoiding the presence of agglomerates. The nanostructured starting powders were obtained by using a colloidal method where commercial Si3N4submicrometer particles were coated with anatase TiO2nanocrystals. A later nitridation process led to the formation of TiN nanoparticles on the surface of Si3N4. A second set of powders was prepared by doping the above defined powders with yttrium and aluminium precursors using also a colloidal method as sources of alumina and yttria. After thermal nitridation and SPS treatment, it has been found that the addition of oxides dopants improves the mechanical performance (KIC,σf) but increases the electrical resistivity and significantly reduces the hardness. This is due to the formation of a continuous insulating glassy phase that totally envelops the conductive TiN nanoparticles, avoiding the percolative contact between them. The combination of colloidal processing route and SPS allows the designing of tailor-made free glassy phase Si3N4/TiN nanocomposites with controlled microstructure. The microstructural features and the thermoelectrical and mechanical properties of both kinds of dense SPSed compacts are discussed in this work.


Materials ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 359 ◽  
Author(s):  
Mei-Chen Sung ◽  
Ya-Fen Wang ◽  
Shang-Che Chen ◽  
Cheng-Hsien Tsai

The synthesis of aluminum nitride (AlN) powders is traditionally done via the thermal nitridation process, in which the reaction temperature reaches as high as 960 °C, with more than several hours of reaction time. Moreover, the occurrence of agglomeration in melting Al particles results in poor AlN quality and a low efficiency of nitridation. In this study, an atmosphere-pressure microwave-plasma preceded the pre-synthesis process. This process operates at 550 °C for 2–10 min with the addition of NH4Cl (Al: NH4Cl = 1:1) for generating a hard AlN shell to avoid the flow and aggregation of the melting Al metals. Then, the mass production of AlN powders by the thermal nitridation process can be carried out by rapidly elevating the reaction temperature (heating rate of 15 °C/min) until 1050 °C is reached. X-Ray Diffractometer (XRD) crystal analysis shows that without the peak, Al metals can be observed by synthesizing AlN via plasma nitridation (at 550 °C for 2 min, Al: NH4Cl = 1:1), followed by thermal nitridation (at 950 °C for 1 h). Moreover, SEM images show that well-dispersed AlN powders without agglomeration were produced. Additionally, the particle size of the produced AlN powder (usually < 1 μm) tends to be reduced from 2–5 μm (Al powders), resulting in a more efficient synthesizing process (lower reaction temperature, shorter reaction time) for mass production.


Molecules ◽  
2021 ◽  
Vol 26 (7) ◽  
pp. 2095
Author(s):  
Pedro Estevan Navarro ◽  
Isabel Sospedra ◽  
Alejandro Perales ◽  
Cristina González-Díaz ◽  
Rubén Jiménez-Alfageme ◽  
...  

Caffeine is a food supplement widely consumed by athletes, but it has not been established. So far, the veracity of their labeling in terms of the dosage and cause/effect relationship aimed at the consumer. The aim is to analyze the health claims and the dosage presented on the labeling of caffeine supplements and to evaluate if they follow the European Food Safety Authority (EFSA) and international criteria. A descriptive cross-sectional study of a sample of caffeine supplements was carried out. The search was done through the Amazon and Google Shopping web portals. In order to assess the adequacy of the health claims, the guidelines of reference established by European Food Safety Authority were compared to the Academy of Nutrition and Dietetics, International Olympic Committee, and Australian Institute of Sport guidelines; in addition, recent systematic reviews were addressed. A review of labels of 42 caffeine supplements showed that, in less than 3% of the products were the health claims supported by the recommendations and by the labeled quantity of caffeine. The claims that fully complied the recommendations were, “improves or increases endurance performance”, “improves strength performance”, or “improves short-term performance”. In most cases, the recommended dosage was 200 mg/day for these products, which is the minimum for the caffeine effects to be declared. The rest of the health claims were not adequate or need to be modified. Most of the health claims identified indicated an unproven cause and effect, which constitutes consumer fraud, and so must be modified or eliminated.


2021 ◽  
pp. 1-30
Author(s):  
A. Guo ◽  
Z. Zhou ◽  
R. Wang ◽  
X. Zhao ◽  
X. Zhu

Abstract The full-wing solar-powered UAV has a large aspect ratio, special configuration, and excellent aerodynamic performance. This UAV converts solar energy into electrical energy for level flight and storage to improve endurance performance. The UAV only uses a differential throttle for lateral control, and the insufficient control capability during crosswind landing results in a large lateral distance bias and leads to multiple landing failures. This paper analyzes 11 landing failures and finds that a large lateral distance bias at the beginning of the approach and the coupling of base and differential throttle control is the main reason for multiple landing failures. To improve the landing performance, a heading angle-based vector field (VF) method is applied to the straight-line and orbit paths following and two novel 3D Dubins landing paths are proposed to reduce the initial lateral control bias. The results show that the straight-line path simulation exhibits similar phenomenon with the practical failure; the single helical path has the highest lateral control accuracy; the left-arc to left-arc (L-L) path avoids the saturation of the differential throttle; and both paths effectively improve the probability of successful landing.


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