Electrochemical reduction mechanism of rotenone. Part 2. Effect of proton donors

1982 ◽  
pp. 545 ◽  
Author(s):  
Giulio Capobianco ◽  
Giuseppe Farnia ◽  
Alessandro Gambaro ◽  
Maria Gabriella Severin
Keyword(s):  
Electrochemical Reduction ◽  
Reduction Mechanism ◽  
Proton Donors

Electrochemical reduction of maleic and fumaric acids and their dimethyl esters in methanol at a mercury electrode

1987 ◽  
Vol 52 (9) ◽  
pp. 2132-2141
Author(s):  
Dimitra Sazou ◽  
Pantelis Karabinas
Keyword(s):  
Double Bond ◽  
Electrochemical Reduction ◽  
Mercury Electrode ◽  
Cyclic Voltammograms ◽  
Reduction Mechanism ◽  
Proton Donors ◽  
Carboxylic Groups ◽  
One Step ◽  
Pure Methanol ◽  
Successive Reduction

The electrochemical reduction of maleic and fumaric acids and their dimethyl esters have been investigated by cyclic voltammetry on HMDE in pure methanol. The cyclic voltammograms of the free acids show two successive reduction waves due to the influence of the different strength of the carboxylic groups on the double bond reduction. The reduction mechanism is verified by examining the effect of different supporting electrolytes, proton donors, and strong bases on the reduction waves. The double bond reduction of the corresponding dimethyl esters takes place in one step.

Electrochemical tools to disclose the electrochemical reduction mechanism of CO2 in aprotic solvents and ionic liquids

2021 ◽  
pp. 115411
Author(s):  
Silvia Mena ◽  
Esteve Ribas ◽  
Clara Richard ◽  
Iluminada Gallardo ◽  
Jordi Faraudo ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Electrochemical Reduction ◽  
Aprotic Solvents ◽  
Reduction Mechanism

Electrochemical reduction mechanism of camptothecin at glassy carbon electrode

2010 ◽  
Vol 79 (2) ◽  
pp. 173-178 ◽  
Author(s):  
Afzal Shah ◽  
Victor C. Diculescu ◽  
Rumana Qureshi ◽  
Ana Maria Oliveira-Brett
Keyword(s):  
Electrochemical Reduction ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Carbon Electrode ◽  
Reduction Mechanism

Investigation of the electrochemical reduction mechanism of 1-[N-(2-pyridyl)aminomethylidene]-2(1H)-naphthalenone (PN)

2005 ◽  
Vol 581 (1) ◽  
pp. 46-53 ◽  
Author(s):  
Faruk Gökmeşe ◽  
Ebru Gökmeşe ◽  
Ali Osman Solak ◽  
Muhammet Işıklan ◽  
Zeynel Kılıç
Keyword(s):  
Electrochemical Reduction ◽  
Reduction Mechanism
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