Electrochemical reduction of 2-nitroimidazole in aprotic medium: Influence of its dissociation equilibrium on the reduction mechanism

2006 ◽  
Vol 52 (2) ◽  
pp. 511-518 ◽  
Author(s):  
J.A. Squella ◽  
A. Campero ◽  
J. Maraver ◽  
J. Carbajo
Keyword(s):  
Electrochemical Reduction ◽  
Reduction Mechanism ◽  
Dissociation Equilibrium ◽  
Aprotic Medium ◽  
Medium Influence

Electrochemical reduction of benzenediazonium salts in aprotic medium

1989 ◽  
Vol 54 (6) ◽  
pp. 1496-1507
Author(s):  
Pavel Janderka ◽  
Igor Cejpek
Keyword(s):  
Cyclic Voltammetry ◽  
Electrochemical Reduction ◽  
Differential Pulse ◽  
Differential Pulse Polarography ◽  
Reduction Mechanism ◽  
Aprotic Medium ◽  
Pulse Polarography ◽  
Dc Polarography ◽  
Donor Numbers

DC polarography, TAST polarography, differential pulse polarography, polarography with superimposed alternating current, slow cyclic voltammetry with a hanging Hg drop electrode and a Pt electrode, rapid cyclic voltammetry with a hanging Hg drop, and coulometry were used to study the electrochemical reduction of p-methoxy- and p-nitrobenzenediazonium cations in aprotic medium. A reduction mechanism involving two separate one-electron steps is proposed, the first of which being complicated by adsorption and follow-up chemical reaction leading to evolution of nitrogen. The basicity of the aprotic solvents, expressed by donor numbers according to Gutman, influences the reduction mechanism of these cations.

Electrochemical tools to disclose the electrochemical reduction mechanism of CO2 in aprotic solvents and ionic liquids

2021 ◽  
pp. 115411
Author(s):  
Silvia Mena ◽  
Esteve Ribas ◽  
Clara Richard ◽  
Iluminada Gallardo ◽  
Jordi Faraudo ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Electrochemical Reduction ◽  
Aprotic Solvents ◽  
Reduction Mechanism

Electrochemical reduction mechanism of camptothecin at glassy carbon electrode

2010 ◽  
Vol 79 (2) ◽  
pp. 173-178 ◽  
Author(s):  
Afzal Shah ◽  
Victor C. Diculescu ◽  
Rumana Qureshi ◽  
Ana Maria Oliveira-Brett
Keyword(s):  
Electrochemical Reduction ◽  
Glassy Carbon Electrode ◽  
Glassy Carbon ◽  
Carbon Electrode ◽  
Reduction Mechanism

Investigation of the electrochemical reduction mechanism of 1-[N-(2-pyridyl)aminomethylidene]-2(1H)-naphthalenone (PN)

2005 ◽  
Vol 581 (1) ◽  
pp. 46-53 ◽  
Author(s):  
Faruk Gökmeşe ◽  
Ebru Gökmeşe ◽  
Ali Osman Solak ◽  
Muhammet Işıklan ◽  
Zeynel Kılıç
Keyword(s):  
Electrochemical Reduction ◽  
Reduction Mechanism

Electrochemical reduction of some compounds of two-coordinate phosphorus and arsenic in an aprotic medium

1992 ◽  
Vol 41 (8) ◽  
pp. 1358-1362
Author(s):  
T. V. Troepol'skaya ◽  
G. A. Vagina ◽  
�. I. Yakusheva ◽  
A. S. Ionkin ◽  
N. V. Nikolaeva ◽  
...  
Keyword(s):  
Electrochemical Reduction ◽  
Aprotic Medium
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