253. The compounds of lithium chloride with cobalt chloride. Water as a linking agent in polynuclear kations

1932 ◽  
pp. 1855 ◽  
Author(s):  
Henry Bassett ◽  
Isabella Sanderson
Keyword(s):  
Lithium Chloride ◽  
Cobalt Chloride ◽  
Chloride Water

Existence of Two Liquid Phases in the System Cobalt Chloride–Water–Acetone

Nature ◽  
1959 ◽  
Vol 183 (4659) ◽  
pp. 459-460
Author(s):  
J. N. MURRELL ◽  
L. I. KATZIN ◽  
B. L. DAVIES
Keyword(s):  
Cobalt Chloride ◽  
Liquid Phases ◽  
Chloride Water

System Lithium Chloride–Water

1956 ◽  
Vol 60 (12) ◽  
pp. 1666-1667 ◽  
Author(s):  
H. E. Moran
Keyword(s):  
Lithium Chloride ◽  
Chloride Water

The Systems Lithium Chloride-Water-Ethyl Alcohol and Lithium Bromide-Water-Ethyl Alcohol1,2

1936 ◽  
Vol 58 (9) ◽  
pp. 1692-1695 ◽  
Author(s):  
John P. Simmons ◽  
Henry Freimuth ◽  
Harry Russell
Keyword(s):  
Lithium Chloride ◽  
Ethyl Alcohol ◽  
Lithium Bromide ◽  
Chloride Water

THE SYSTEM LITHIUM CHLORATE – LITHIUM CHLORIDE – WATER AT VARIOUS TEMPERATURES

1956 ◽  
Vol 34 (11) ◽  
pp. 1647-1661 ◽  
Author(s):  
A. N. Campbell ◽  
J. E. Griffiths
Keyword(s):  
Diffraction Pattern ◽  
Lithium Chloride ◽  
Equilibrium Diagram ◽  
X Ray Diffraction ◽  
X Ray ◽  
Chloride Form ◽  
Double Salts ◽  
Chloride Water

The equilibrium diagram of the system lithium chlorate – water has been determined at all temperatures and that of the system lithium chlorate – lithium chloride – water at the temperatures 3.0°, 6.0°, 8.5°, and 25.0 °C.Lithium chlorate forms three hydrates having the formulae:(i) (LiClO3)4.H2O—stable in contact with solution from 20.5° to 42.0 °C.(ii) LiClO3.H2O—stable in contact with solution from −0.1° to 20.5 °C.(iii) LiClO3.3 H2O—melts congruently at 8.4 °C.Hydrate (i) was discovered by Berg but he gave to it the formula (LiClO3)3.H2O.Lithium chlorate and lithium chloride form no double salts at the temperatures of investigation.Lithium chlorate exists in two enantiotropic forms, namely the α and the β forms. The transition, α ↔ β, takes place at 99.8 °C. and the α form has the lower density. The γ form, proposed by Kraus and Burgess, does not exist either stably or metastably. The X-ray diffraction pattern of β-LiClO3 has been obtained.

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