Surface activity of zinc oxide. Examination of the effect of γ-irradiation by electron spin resonance, electrical conductivity, reflectance spectroscopy and gas adsorption

Author(s):  
Michael J. Duck ◽  
Robert L. Nelson
1968 ◽  
Vol 46 (16) ◽  
pp. 2749-2752 ◽  
Author(s):  
L. Fabes ◽  
J. K. S. Wan

γ-Irradiation of polycrystalline tetraethylammonium iodide at 77°K leads to the breaking of a C—C bond and the primary radicals ĊH3 and [Formula: see text] were detected by electron spin resonance. The methyl radicals were found to disappear readily at 120°K. In the range of 263–273°K a secondary reaction between [Formula: see text] and the parent ion [Formula: see text] was observed; the resulting secondary radical [Formula: see text] was found to be stable up to 373°K.


1997 ◽  
Vol 101 (3) ◽  
pp. 309-316 ◽  
Author(s):  
W. Sjoerd Kijlstra ◽  
Eduard K. Poels ◽  
Alfred Bliek ◽  
Bert M. Weckhuysen ◽  
Robert A. Schoonheydt

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