Molybdenum and tungsten nitrosyl complexes containing bulky alkoxy, aryloxy, and arylamido ligands: their electrochemical behaviour and the structure of [Mo{HB(Me2pz)3}(NO)I(OCH2CH2CH2Br)]

Author(s):  
Christopher J. Jones ◽  
Jon A. McCleverty ◽  
Bryan D. Neaves ◽  
Sarah J. Reynolds ◽  
Harry Adams ◽  
...  
1993 ◽  
Vol 12 (6) ◽  
pp. 2103-2110 ◽  
Author(s):  
Peter Legzdins ◽  
Steven J. Rettig ◽  
Kevin J. Ross

1979 ◽  
Vol 32 (6) ◽  
pp. 1187 ◽  
Author(s):  
JA Broomhead ◽  
JR Budge

Molybdenum and tungsten nitrosyl complexes with dithiocarbamato ligands have been prepared and characterized by analysis, and 1H n.m.r, and infrared studies. The molybdenum complexes are formulated as seven-coordinate species [Mo(NCO)L(S2CNEt2)2NO]- (L = Cl-, N3-, NCS-),{Mo(NCO)(S2CNEt2)2NO}2N2H4 and [Mo(NCO)B(S2CNEt2)2NO](B = NH3, pyridine). Likely stereochemistries are discussed. New tungsten complexes have been prepared by photochemical reactions of cis-[W(S2CNEt2)2(NO)2] to give [WL2(S2CNEt2)2NO]-, [WL(S2CNEt2)2(Me2SO)NO](L = NCO-, N3-, NCS-) and [W(NCO)(S2CNEt2)2(MeCONMe2)NO]. Assignments for the nitrosyl infrared bands in cis-[MO(S2CNEt2)2(NO)2] and [Mo(NCO)(S,CNEt2)2(Me2SO)NO] havebeen made by using 15NO labelled ligands.


2010 ◽  
Vol 2010 (21) ◽  
pp. 3328-3337 ◽  
Author(s):  
Alexander Dybov ◽  
Olivier Blacque ◽  
Heinz Berke

1991 ◽  
Vol 10 (4) ◽  
pp. 986-1002 ◽  
Author(s):  
Peter. Legzdins ◽  
Everett C. Phillips ◽  
James. Trotter ◽  
Vivien C. Yee ◽  
Frederick W. B. Einstein ◽  
...  

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