Organometallic amido nitrosyl complexes of molybdenum and tungsten

Peter Legzdins; Steven J. Rettig; Kevin J. Ross

doi:10.1021/om00030a021

Molybdenum and Tungsten Nitrosyl Complexes with Dithiocarbamate Ligands

Australian Journal of Chemistry ◽

10.1071/ch9791187 ◽

1979 ◽

Vol 32 (6) ◽

pp. 1187 ◽

Cited By ~ 7

Author(s):

JA Broomhead ◽

JR Budge

Keyword(s):

Photochemical Reactions ◽

Molybdenum Complexes ◽

Tungsten Complexes ◽

Nitrosyl Complexes ◽

Infrared Studies ◽

In Cis ◽

And Tungsten

Molybdenum and tungsten nitrosyl complexes with dithiocarbamato ligands have been prepared and characterized by analysis, and 1H n.m.r, and infrared studies. The molybdenum complexes are formulated as seven-coordinate species [Mo(NCO)L(S2CNEt2)2NO]- (L = Cl-, N3-, NCS-),{Mo(NCO)(S2CNEt2)2NO}2N2H4 and [Mo(NCO)B(S2CNEt2)2NO](B = NH3, pyridine). Likely stereochemistries are discussed. New tungsten complexes have been prepared by photochemical reactions of cis-[W(S2CNEt2)2(NO)2] to give [WL2(S2CNEt2)2NO]-, [WL(S2CNEt2)2(Me2SO)NO](L = NCO-, N3-, NCS-) and [W(NCO)(S2CNEt2)2(MeCONMe2)NO]. Assignments for the nitrosyl infrared bands in cis-[MO(S2CNEt2)2(NO)2] and [Mo(NCO)(S,CNEt2)2(Me2SO)NO] havebeen made by using 15NO labelled ligands.

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Nitrosyl complexes of molybdenum and tungsten. Part 16. Symmetrical and unsymmetrical bis-alkoxo- and mixed alkoxo-amido-complexes of tris(3,5-dimethylpyrazolyl) boratomolybdenum, related tungsten species, and the structure of bis(ethoxo)-, bis(isopropoxo)-, and ethoxo(isopropoxo)-nitrosyl[tris(3,5-dimethylpyrazolyl)borato]-molybdenum

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9820000951 ◽

1982 ◽

pp. 951-965 ◽

Cited By ~ 22

Author(s):

Jon A. McCleverty ◽

A. Elizabeth Rae ◽

Iwona Wołochowicz ◽

Neil A. Bailey ◽

John M. A. Smith

Keyword(s):

Amido Complexes ◽

Nitrosyl Complexes ◽

Tungsten Species ◽

And Tungsten

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Reductive nitrosation of molybdenum and tungsten halides. III. Intramolecular redox reactions of molybdenum and tungsten halo nitrosyl complexes

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)89828-x ◽

1975 ◽

Vol 12 (1) ◽

pp. 5-7 ◽

Cited By ~ 10

Author(s):

L. Bencze ◽

B. Mohai

Keyword(s):

Redox Reactions ◽

Nitrosyl Complexes ◽

And Tungsten

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Molybdenum and Tungsten Nitrosyl Complexes in Hydrogen Activation

European Journal of Inorganic Chemistry ◽

10.1002/ejic.201000301 ◽

2010 ◽

Vol 2010 (21) ◽

pp. 3328-3337 ◽

Cited By ~ 6

Author(s):

Alexander Dybov ◽

Olivier Blacque ◽

Heinz Berke

Keyword(s):

Hydrogen Activation ◽

Nitrosyl Complexes ◽

And Tungsten

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ChemInform Abstract: NITROSYL COMPLEXES OF MOLYBDENUM AND TUNGSTEN

Chemischer Informationsdienst ◽

10.1002/chin.197720313 ◽

1977 ◽

Vol 8 (20) ◽

pp. no-no

Author(s):

F. KING ◽

G. J. LEIGH

Keyword(s):

Nitrosyl Complexes ◽

And Tungsten

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Molybdenum and tungsten nitrosyl complexes containing bulky alkoxy, aryloxy, and arylamido ligands: their electrochemical behaviour and the structure of [Mo{HB(Me2pz)3}(NO)I(OCH2CH2CH2Br)]

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9860000733 ◽

1986 ◽

pp. 733 ◽

Cited By ~ 23

Author(s):

Christopher J. Jones ◽

Jon A. McCleverty ◽

Bryan D. Neaves ◽

Sarah J. Reynolds ◽

Harry Adams ◽

...

Keyword(s):

Electrochemical Behaviour ◽

Nitrosyl Complexes ◽

And Tungsten

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Nitrosyl complexes of molybdenum and tungsten. Part 15. Iodo(monoalkylamido)nitrosyl[tris(3,5-dimethylpyrazolyl)borato]molybdenum complexes, some related tungsten compounds, and the crystal and molecular structure of ethylamido(iodo)nitrosyl[tris(3,5-dimethyl-pyrazolyl) borato]molybdenum

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9820000429 ◽

1982 ◽

pp. 429-438 ◽

Cited By ~ 22

Author(s):

Jon A. McCleverty ◽

A. Elizabeth Rae ◽

Iwona Wołochowicz ◽

Neil A. Bailey ◽

John M. A. Smith

Keyword(s):

Molecular Structure ◽

Crystal And Molecular Structure ◽

Molybdenum Complexes ◽

Nitrosyl Complexes ◽

And Tungsten

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Organometallic nitrosyl chemistry. 45. Improved syntheses of cyclopentadienyl dichloro nitrosyl complexes of molybdenum and tungsten. Utility of phosphorus pentachloride as a chlorinating agent

Organometallics ◽

10.1021/om00052a067 ◽

1991 ◽

Vol 10 (6) ◽

pp. 2077-2081 ◽

Cited By ~ 22

Author(s):

Neil H. Dryden ◽

Peter. Legzdins ◽

Raymond J. Batchelor ◽

Frederick W. B. Einstein

Keyword(s):

Phosphorus Pentachloride ◽

Nitrosyl Complexes ◽

And Tungsten

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Organometallic nitrosyl chemistry. 43. Synthesis, characterization, and physical properties of unusual cyclopentadienyl bis(benzyl) nitrosyl complexes of molybdenum and tungsten

Organometallics ◽

10.1021/om00050a034 ◽

1991 ◽

Vol 10 (4) ◽

pp. 986-1002 ◽

Cited By ~ 23

Author(s):

Peter. Legzdins ◽

Everett C. Phillips ◽

James. Trotter ◽

Vivien C. Yee ◽

Frederick W. B. Einstein ◽

...

Keyword(s):

Physical Properties ◽

Nitrosyl Complexes ◽

And Tungsten

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Nitrosyl complexes of molybdenum and tungsten. Part 17. Hydrazido(1–) complexes of [tris(3,5-dimethylpyrazolyl)borato]molybdenum, related tungsten compounds, and the structures of NN-dimethylhydrazido(1–)- and N-methyl-N-phenylhydrazido(1–)iodo(nitrosyl)[tris(3,5-dimethylpyrazol-1-yl)borato]molybdenum

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9830000071 ◽

1983 ◽

pp. 71-80 ◽

Cited By ~ 16

Author(s):

Jon A. McCleverty ◽

A. Elizabeth Rae ◽

Iwona Wołochowicz ◽

Neil A. Bailey ◽

John M. A. Smith

Keyword(s):

Nitrosyl Complexes ◽

And Tungsten

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