Nitrosyl complexes of molybdenum and tungsten. Part 16. Symmetrical and unsymmetrical bis-alkoxo- and mixed alkoxo-amido-complexes of tris(3,5-dimethylpyrazolyl) boratomolybdenum, related tungsten species, and the structure of bis(ethoxo)-, bis(isopropoxo)-, and ethoxo(isopropoxo)-nitrosyl[tris(3,5-dimethylpyrazolyl)borato]-molybdenum

1982 ◽  
pp. 951-965 ◽  
Author(s):  
Jon A. McCleverty ◽  
A. Elizabeth Rae ◽  
Iwona Wołochowicz ◽  
Neil A. Bailey ◽  
John M. A. Smith
Keyword(s):  
Amido Complexes ◽  
Nitrosyl Complexes ◽  
Tungsten Species ◽  
And Tungsten

Organometallic amido nitrosyl complexes of molybdenum and tungsten

1993 ◽  
Vol 12 (6) ◽  
pp. 2103-2110 ◽  
Author(s):  
Peter Legzdins ◽  
Steven J. Rettig ◽  
Kevin J. Ross
Keyword(s):  
Nitrosyl Complexes ◽  
And Tungsten

Molybdenum and Tungsten Nitrosyl Complexes with Dithiocarbamate Ligands

1979 ◽  
Vol 32 (6) ◽  
pp. 1187 ◽  
Author(s):  
JA Broomhead ◽  
JR Budge
Keyword(s):  
Photochemical Reactions ◽  
Molybdenum Complexes ◽  
Tungsten Complexes ◽  
Nitrosyl Complexes ◽  
Infrared Studies ◽  
In Cis ◽  
And Tungsten

Molybdenum and tungsten nitrosyl complexes with dithiocarbamato ligands have been prepared and characterized by analysis, and 1H n.m.r, and infrared studies. The molybdenum complexes are formulated as seven-coordinate species [Mo(NCO)L(S2CNEt2)2NO]- (L = Cl-, N3-, NCS-),{Mo(NCO)(S2CNEt2)2NO}2N2H4 and [Mo(NCO)B(S2CNEt2)2NO](B = NH3, pyridine). Likely stereochemistries are discussed. New tungsten complexes have been prepared by photochemical reactions of cis-[W(S2CNEt2)2(NO)2] to give [WL2(S2CNEt2)2NO]-, [WL(S2CNEt2)2(Me2SO)NO](L = NCO-, N3-, NCS-) and [W(NCO)(S2CNEt2)2(MeCONMe2)NO]. Assignments for the nitrosyl infrared bands in cis-[MO(S2CNEt2)2(NO)2] and [Mo(NCO)(S,CNEt2)2(Me2SO)NO] havebeen made by using 15NO labelled ligands.

Molybdenum and Tungsten Nitrosyl Complexes in Hydrogen Activation

2010 ◽  
Vol 2010 (21) ◽  
pp. 3328-3337 ◽  
Author(s):  
Alexander Dybov ◽  
Olivier Blacque ◽  
Heinz Berke
Keyword(s):  
Hydrogen Activation ◽  
Nitrosyl Complexes ◽  
And Tungsten

Organometallic nitrosyl chemistry. 43. Synthesis, characterization, and physical properties of unusual cyclopentadienyl bis(benzyl) nitrosyl complexes of molybdenum and tungsten

1991 ◽  
Vol 10 (4) ◽  
pp. 986-1002 ◽  
Author(s):  
Peter. Legzdins ◽  
Everett C. Phillips ◽  
James. Trotter ◽  
Vivien C. Yee ◽  
Frederick W. B. Einstein ◽  
...  
Keyword(s):  
Physical Properties ◽  
Nitrosyl Complexes ◽  
And Tungsten
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