Mössbauer spectra, structure, and bonding in iron carbonyl derivatives

1969 ◽  
Vol 47 (0) ◽  
pp. 126-135 ◽  
Author(s):  
R. Greatrex ◽  
N. N. Greenwood
Author(s):  
Geoffrey C. H. Jones ◽  
Peter G. Jones ◽  
Alfred G. Maddock ◽  
Martin J. Mays ◽  
Pauline A. Vergnano ◽  
...  

1976 ◽  
Vol 54 (8) ◽  
pp. 1285-1289 ◽  
Author(s):  
G. Michael Bancroft ◽  
Gary Cerantola

57Fe Mössbauer spectra are reported for neutral FeX2(diars)2 (X = Cl, Br, I, NCS) complexes and newly prepared cationic [FeClL(diars)2]Y (L = CO, P(OMe)3, P(OPh)3; Y = SnCl3, BPh4) compounds. Using partial quadrupole splittings to calculate quadrupole splittings, all compounds are assigned the trans structure. From 57Fe centre shifts and quadrupole splittings, diars is found to be an appreciably poorer σ donor than analogous chelating phosphines, and a very similar σ donor and π acceptor to o-phenanthroline.


1983 ◽  
Vol 247 (1) ◽  
pp. 61-70 ◽  
Author(s):  
R.P. Brint ◽  
K. O'Cuill ◽  
T.R. Spalding ◽  
F.A. Deeney

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