Bis[o-phenylenebis(dimethylarsine)]Fe(II) complexes: structure and bonding from 57Fe Mössbauer spectra
Keyword(s):
57Fe Mössbauer spectra are reported for neutral FeX2(diars)2 (X = Cl, Br, I, NCS) complexes and newly prepared cationic [FeClL(diars)2]Y (L = CO, P(OMe)3, P(OPh)3; Y = SnCl3, BPh4) compounds. Using partial quadrupole splittings to calculate quadrupole splittings, all compounds are assigned the trans structure. From 57Fe centre shifts and quadrupole splittings, diars is found to be an appreciably poorer σ donor than analogous chelating phosphines, and a very similar σ donor and π acceptor to o-phenanthroline.
2009 ◽
Vol 192
(1-3)
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pp. 77-83
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1969 ◽
Vol 47
(0)
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pp. 126-135
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Keyword(s):
2004 ◽
Vol 65
(11)
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pp. 1913-1915
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