Bis[o-phenylenebis(dimethylarsine)]Fe(II) complexes: structure and bonding from 57Fe Mössbauer spectra

1976 ◽  
Vol 54 (8) ◽  
pp. 1285-1289 ◽  
Author(s):  
G. Michael Bancroft ◽  
Gary Cerantola

57Fe Mössbauer spectra are reported for neutral FeX2(diars)2 (X = Cl, Br, I, NCS) complexes and newly prepared cationic [FeClL(diars)2]Y (L = CO, P(OMe)3, P(OPh)3; Y = SnCl3, BPh4) compounds. Using partial quadrupole splittings to calculate quadrupole splittings, all compounds are assigned the trans structure. From 57Fe centre shifts and quadrupole splittings, diars is found to be an appreciably poorer σ donor than analogous chelating phosphines, and a very similar σ donor and π acceptor to o-phenanthroline.

2021 ◽  
Author(s):  
Natalia Kazak ◽  
Yurii V. Knyazev ◽  
Vyacheslav Zhandun ◽  
Juan Bartolomé ◽  
Ana Arauzo ◽  
...  

The ludwigite Co2FeBO5 has been studied experimentally using 57Fe Mössbauer spectroscopy and theoretically by means of the DFT+GGA calculations. The room-temperature Mössbauer spectra are composed of four quadrupole doublets corresponding...


ICAME 2005 ◽  
2006 ◽  
pp. 1085-1089
Author(s):  
P. Bonville ◽  
V. Dupuis ◽  
E. Vincent ◽  
P. E. Lippens ◽  
A. S. Wills

ISIAME 2008 ◽  
2009 ◽  
pp. 579-585
Author(s):  
K. Szymański ◽  
D. Satuła ◽  
L. Dobrzyński

2008 ◽  
pp. 462-466
Author(s):  
Harald Stger ◽  
Hermann Rautz ◽  
Guido Kickelbick ◽  
Claus Pietzsch

2009 ◽  
Vol 192 (1-3) ◽  
pp. 77-83 ◽  
Author(s):  
K. Szymański ◽  
D. Satuła ◽  
L. Dobrzyński

1993 ◽  
Vol 46 (5) ◽  
pp. 679 ◽  
Author(s):  
JM Cadogan ◽  
SJ Campbell ◽  
XL Zhao ◽  
E Wu

Mossbauer spectra of YC012B6 and NdCo12B6 doped with enriched 57Fe have been obtained at various temperatures between 4�2 K and room temperature. The spectrum of YC012B6 at 4�2 K indicates that the Co sublattice orders in the crystallographic basal plane. NdCo12B6 orders along or close to the crystallographic c-axis at 4�2 K and undergoes a spin-reorientation with increasing temperature until at ~55 K the magnetisation lies in or near the basal plane.


1996 ◽  
Vol 62 (6) ◽  
pp. 525-528
Author(s):  
Haosheng Fei ◽  
Mingyuan Gao ◽  
Xicheng Ai ◽  
Yangqiang Yang ◽  
Tieqiao Zhang ◽  
...  

2004 ◽  
Vol 65 (11) ◽  
pp. 1913-1915 ◽  
Author(s):  
E.J. Baran ◽  
R.C. Mercader ◽  
C. Cascales

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