Dopant-induced cationic bivalency in hierarchical antimony-doped tin oxide nano-particles for room-temperature SO2 sensing

2021 ◽  
Vol 9 (38) ◽  
pp. 21824-21834
Author(s):  
Nirman Chakraborty ◽  
Pradeepta Kumar Ghose ◽  
Pratyasha Rudra ◽  
Sagnik Das ◽  
Debdulal Saha ◽  
...  

Antimony doping in tin oxide triggered generation of tin bivalency and it is the variation in ratio of 2+ and 4+ states of tin that determines the efficiency of room temperature SO2 sensing.

2017 ◽  
Vol 13 (2) ◽  
pp. 4671-4677 ◽  
Author(s):  
A. M. Abdelghany ◽  
A.H. Oraby ◽  
Awatif A Hindi ◽  
Doaa M El-Nagar ◽  
Fathia S Alhakami

Bimetallic nanoparticles of silver (Ag) and gold (Au) were synthesized at room temperature using Curcumin. Reduction process of silver and gold ions with different molar ratios leads to production of different nanostructures including alloys and core-shells. Produced nanoparticles were characterized simultaneously with FTIR, UV/vis. spectroscopy, transmission electron microscopy (TEM), and Energy-dispersive X-ray (EDAX). UV/vis. optical absorption spectra of as synthesized nanoparticles reveals presence of surface palsmon resonance (SPR) of both silver at (425 nm) and gold at (540 nm) with small shift and broadness of gold band after mixing with resucing and capping agent in natural extract which suggest presence of bimetallic nano structure (Au/Ag). FTIR and EDAX data approve the presence of bimetallic nano structure combined with curcumin extract. TEM micrographs shows that silver and gold can be synthesized separately in the form of nano particles using curcumin extract. Synthesis of gold nano particles in presence of silver effectively enhance and control formation of bi-metallic structure.


2003 ◽  
Vol 93 (1-3) ◽  
pp. 580-584 ◽  
Author(s):  
K. Anothainart ◽  
M. Burgmair ◽  
A. Karthigeyan ◽  
M. Zimmer ◽  
I. Eisele

2005 ◽  
Vol 486-487 ◽  
pp. 530-533 ◽  
Author(s):  
Yamato Hayashi ◽  
Hirotsugu Takizawa ◽  
Yoshitaka Saijo ◽  
Tohru Sekino ◽  
Katsuaki Suganuma ◽  
...  

Applications of silver nano-sized metal particles were investigated for a new, ecologically friendly and economical liquid-solid (silver oxide-alcohol) system. Silver metal oxides as starting materials have merits in metal particles fabrication because these materials are decomposed only by heating in air. That is, noble metal oxide does not use thestrong reduction atmosphere. This reduction is ecologically clean because many noble metal oxides are not toxic, and because O2 is evolved during decomposition. We reduced silver metal oxides by ultrasound and fabricated silver nano metal nanoparticles at room temperature, and various applications were investigated. By choosing a suitable process and conditions, it is reasonable to expect that ultrasonic eco-fabrications can be extended to obtain various silver nano-particles containing materials.


2003 ◽  
Vol 42 (Part 2, No. 5B) ◽  
pp. L546-L548 ◽  
Author(s):  
Yu Wang ◽  
Wan Ping Chen ◽  
Kei Chun Cheng ◽  
Helen Lai Wah Chan ◽  
Chung Loong Choy

Sensors ◽  
2018 ◽  
Vol 18 (10) ◽  
pp. 3246 ◽  
Author(s):  
Jan Maslik ◽  
Ivo Kuritka ◽  
Pavel Urbanek ◽  
Petr Krcmar ◽  
Pavol Suly ◽  
...  

This study is focused on the development of water-based ITO nanoparticle dispersions and ink-jet fabrication methodology of an indium tin oxide (ITO) sensor for room temperature operations. Dimensionless correlations of material-tool-process variables were used to map the printing process and several interpretational frameworks were re-examined. A reduction of the problem to the Newtonian fluid approach was applied for the sake of simplicity. The ink properties as well as the properties of the deposited layers were tested for various nanoparticles loading. High-quality films were prepared and annealed at different temperatures. The best performing material composition, process parameters and post-print treatment conditions were used for preparing the testing sensor devices. Printed specimens were exposed to toluene vapours at room temperature. Good sensitivity, fast responses and recoveries were observed in ambient air although the n-type response mechanism to toluene is influenced by moisture in air and baseline drift was observed. Sensing response inversion was observed in an oxygen and moisture-free N2 atmosphere which is explained by the charge-transfer mechanism between the adsorbent and adsorbate molecules. The sensitivity of the device was slightly better and the response was stable showing no drifts in the protective atmosphere.


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