Solution-processed perovskite thin-films: the journey from lab- to large-scale solar cells

Author(s):  
Zahra Saki ◽  
Mahdi Malekshahi Byranvand ◽  
Nima Taghavinia ◽  
Mayank Kedia ◽  
Michael Saliba

This review explores perovskite crystallization in scalable deposition techniques, including blade, slot-die, spray coating, and inkjet printing.

2021 ◽  
pp. 2100193
Author(s):  
Peng Liu ◽  
Bingqian Zhang ◽  
Qing Liao ◽  
Guifen Tian ◽  
Chunling Gu ◽  
...  

2021 ◽  
Vol 136 ◽  
pp. 106151
Author(s):  
Nutcha Khambunkoed ◽  
Saowalak Homnan ◽  
Atcharawon Gardchareon ◽  
Narupon Chattrapiban ◽  
Prayoon Songsiriritthigul ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 757
Author(s):  
Ohchan Kwon ◽  
Yunkyu Choi ◽  
Eunji Choi ◽  
Minsu Kim ◽  
Yun Chul Woo ◽  
...  

Graphene oxide (GO) has been a prized material for fabricating separation membranes due to its immense potential and unique chemistry. Despite the academic focus on GO, the adoption of GO membranes in industry remains elusive. One of the challenges at hand for commercializing GO membranes lies with large-scale production techniques. Fortunately, emerging studies have acknowledged this issue, where many have aimed to deliver insights into scalable approaches showing potential to be employed in the commercial domain. The current review highlights eight physical methods for GO membrane fabrication. Based on batch-unit or continuous fabrication, we have further classified the techniques into five small-scale (vacuum filtration, pressure-assisted filtration, spin coating, dip coating, drop-casting) and three large-scale (spray coating, bar/doctor blade coating, slot die coating) approaches. The continuous nature of the large-scale approach implies that the GO membranes prepared by this method are less restricted by the equipment’s dimensions but rather the availability of the material, whereas membranes yielded by small-scale methods are predominately limited by the size of the fabrication device. The current review aims to serve as an initial reference to provide a technical overview of preparing GO membranes. We further aim to shift the focus of the audience towards scalable processes and their prospect, which will facilitate the commercialization of GO membranes.


Solar RRL ◽  
2021 ◽  
Author(s):  
Liangxin Zhu ◽  
Junwei Chen ◽  
Rong Liu ◽  
Chao Dong ◽  
Shangfeng Yang ◽  
...  

2019 ◽  
Vol 3 (1) ◽  
pp. 32 ◽  
Author(s):  
Lisa Merklein ◽  
Dominik Daume ◽  
Felix Braig ◽  
Stefan Schlisske ◽  
Tobias Rödlmeier ◽  
...  

In this study, multilayer organic light-emitting diodes (OLEDs) consisting of three solution-processed layers are fabricated using slot die coating, gravure printing, and inkjet printing, techniques that are commonly used in the industry. Different technique combinations are investigated to successively deposit a hole injection layer (poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS)), a cross-linkable hole transport layer (N,N′-bis(4-(6-((3-ethyloxetan-3-yl)methoxy)-hexyloxy)phenyl)-N,N′-bis(4-methoxyphenyl)biphenyl-4,4′-diamin (QUPD)), and a green emissive layer (TSG-M) on top of each other. In order to compare the application techniques, the ink formulations have to be adapted to the respective process requirements. First, the influence of the application technique on the layer homogeneity of the different materials is investigated. Large area thickness measurements of the layers based on imaging color reflectometry (ICR) are used to compare the application techniques regarding the layer homogeneity and reproducible film thickness. The total stack thickness of all solution-processed layers of 32 OLEDs could be reproduced homogeneously in a process window of 30 nm for the technique combination of slot die coating and inkjet printing. The best efficiency of 13.3 cd A−1 is reached for a process combination of slot die coating and gravure printing. In order to enable a statistically significant evaluation, in total, 96 OLEDs were analyzed and the corresponding 288 layers were measured successively to determine the influence of layer homogeneity on device performance.


2017 ◽  
Vol 32 (10) ◽  
pp. 1899-1907 ◽  
Author(s):  
Dounya Barrit ◽  
Arif D. Sheikh ◽  
Rahim Munir ◽  
Jérémy M. Barbé ◽  
Ruipeng Li ◽  
...  

Abstract


Nanomaterials ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 614 ◽  
Author(s):  
Xianglin Mei ◽  
Bin Wu ◽  
Xiuzhen Guo ◽  
Xiaolin Liu ◽  
Zhitao Rong ◽  
...  

Nanocrystal solar cells (NCs) allow for large scale solution processing under ambient conditions, permitting a promising approach for low-cost photovoltaic products. Although an up to 10% power conversion efficiency (PCE) has been realized with the development of device fabrication technologies, the open circuit voltage (Voc) of CdTe NC solar cells has stagnated below 0.7 V, which is significantly lower than most CdTe thin film solar cells fabricated by vacuum technology (around 0.8 V~0.9 V). To further improve the NC solar cells’ performance, an enhancement in the Voc towards 0.8–1.0 V is urgently required. Given the unique processing technologies and physical properties in CdTe NC, the design of an optimized band alignment and improved junction quality are important issues to obtain efficient solar cells coupled with high Voc. In this work, an efficient method was developed to improve the performance and Voc of solution-processed CdTe nanocrystal/TiO2 hetero-junction solar cells. A thin layer of solution-processed CdS NC film (~5 nm) as introduced into CdTe NC/TiO2 to construct hetero-junction solar cells with an optimized band alignment and p-n junction quality, which resulted in a low dark current density and reduced carrier recombination. As a result, devices with improved performance (5.16% compared to 2.63% for the control device) and a Voc as high as 0.83 V were obtained; this Voc value is a record for a solution-processed CdTe NC solar cell.


2014 ◽  
Vol 5 (4) ◽  
pp. 1401539 ◽  
Author(s):  
Doojin Vak ◽  
Kyeongil Hwang ◽  
Andrew Faulks ◽  
Yen-Sook Jung ◽  
Noel Clark ◽  
...  

RSC Advances ◽  
2014 ◽  
Vol 4 (18) ◽  
pp. 9118-9125 ◽  
Author(s):  
Si-Nae Park ◽  
Shi-Joon Sung ◽  
Dae-Ho Son ◽  
Dae-Hwan Kim ◽  
Mungunshagai Gansukh ◽  
...  

Effective adding/removal of organic chemicals to/from CZTS precursor thin films for preparing uniform CZTS thin films with optimal photovoltaic properties was achieved by pre-annealing of CZTS precursors containing thiourea.


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