Solution-processed Cu2ZnSnS4 absorbers prepared by appropriate inclusion and removal of thiourea for thin film solar cells

RSC Advances ◽  
2014 ◽  
Vol 4 (18) ◽  
pp. 9118-9125 ◽  
Author(s):  
Si-Nae Park ◽  
Shi-Joon Sung ◽  
Dae-Ho Son ◽  
Dae-Hwan Kim ◽  
Mungunshagai Gansukh ◽  
...  

Effective adding/removal of organic chemicals to/from CZTS precursor thin films for preparing uniform CZTS thin films with optimal photovoltaic properties was achieved by pre-annealing of CZTS precursors containing thiourea.

2011 ◽  
Vol 2011 ◽  
pp. 1-10 ◽  
Author(s):  
Hongxia Wang

The research in thin film solar cells has been dominated by light absorber materials based on CdTe and Cu(In,Ga)Se2(CIGS) in the last several decades. The concerns of environment impact of cadmium and the limited availability of indium in those materials have driven the research towards developing new substitute light absorbers made from earth abundant, environment benign materials. Cu2ZnSnS4(CZTS) semiconductor material has emerged as one of the most promising candidates for this aim and has attracted considerable interest recently. Significant progress in this relatively new research area has been achieved in the last three years. Over 130 papers on CZTS have been published since 2007, and the majority of them are on the preparation of CZTS thin films by different methods. This paper, will review the wide range of techniques that have been used to deposit CZTS semiconductor thin films. The performance of the thin film solar cells using the CZTS material will also be discussed.


2012 ◽  
Vol 182-183 ◽  
pp. 237-240
Author(s):  
Nian Jing Ji ◽  
Ke Gao Liu ◽  
Zhong Quan Ma

CZTS thin film, a potential candidate for application as absorber layer in thin film solar cells, has drawn much attention in these years due to its excellent photoelectric performance and nontoxic components. It provides a brief description of the development of CZTS thin film for solar cells, and surveys several methods of depositing CZTS films, then introduces the crystal structure of CZTS which is a problem for composition ratio affecting the properties of CZTS thin films. Here we also outline the development and the structure of solar cells based on CZTS thin films.


2009 ◽  
Vol 1165 ◽  
Author(s):  
Hironori Katagiri ◽  
Kazuo Jimbo ◽  
Masami Tahara ◽  
Hideaki Araki ◽  
Koichiro Oishi

AbstractCu2ZnSnS4 (CZTS) thin films were fabricated by using three RF co-sputtering continued with sulfurization method. The new type of thin film solar cells using CZTS as an absorber consists of buffer-layer and window-layer on CZTS films that were fabricated on a Mo-coated Soda Lime Glass (SLG) substrate. It was confirmed that CZTS solar cells with high conversion efficiency existed in a relatively narrow composition region. In this paper, the fabrication method of CZTS-based thin film solar cells in our laboratory was stated briefly and the influence of the composition ratio on the photovoltaic properties were presented. Furthermore, the properties of a genuine non-toxic solar cell using a Cd-free buffer-layer were introduced.


2018 ◽  
Vol 6 (18) ◽  
pp. 8682-8692 ◽  
Author(s):  
Gustavo H. Albuquerque ◽  
Ki-Joong Kim ◽  
Jonathon I. Lopez ◽  
Arun Devaraj ◽  
Sandeep Manandhar ◽  
...  

Optimized sulfurization process and final spectrum of the absorption coefficient of the Cu3SbS4 thin films.


2016 ◽  
Vol 18 (2) ◽  
pp. 550-557 ◽  
Author(s):  
Jiahua Tao ◽  
Junfeng Liu ◽  
Leilei Chen ◽  
Huiyi Cao ◽  
Xiankuan Meng ◽  
...  

Cu2ZnSnS4 (CZTS) thin films with fine control over composition and pure phase were fabricated by sulfurization of co-electroplated Cu–Zn–Sn–S precursors.


2014 ◽  
Vol 47 (13) ◽  
pp. 135105 ◽  
Author(s):  
Se Jin Park ◽  
Yunae Cho ◽  
Sung Hwan Moon ◽  
Ji Eun Kim ◽  
Doh-Kwon Lee ◽  
...  

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