Synthesis and characterization of new Pd(ii) and Pt(ii) complexes with 3-substituted 1-(2-pyridyl)imidazo[1,5-a]pyridine ligands

2021 ◽  
Vol 50 (14) ◽  
pp. 4859-4873
Author(s):  
Sara Pischedda ◽  
Sergio Stoccoro ◽  
Antonio Zucca ◽  
Giuseppe Sciortino ◽  
Fabrizio Ortu ◽  
...  
Keyword(s):  
General Formula ◽  
Synthesis And Characterization ◽  
Pyridine Ligands ◽  
Substituted 1

Several Pd(ii) and Pt(ii) complexes of general formula [M(Ln)(X)(Y)] have been synthesized by reaction of various palladium(ii) and platinum(ii) derivatives with 3-aryl or 3-benzyl 1-(2-pyridyl)-imidazo[1,5-a]pyridines (Ln).

Synthesis and characterization of layered bismuth vanadates

1990 ◽  
Vol 5 (11) ◽  
pp. 2718-2722 ◽  
Author(s):  
K. B. R. Varma ◽  
G. N. Subbanna ◽  
T. N. Guru ◽  
C. N. R. Rao
Keyword(s):  
Curie Temperature ◽  
General Formula ◽  
Layered Structure ◽  
Synthesis And Characterization ◽  
Structure And Properties ◽  
Bismuth Vanadates

Bi2VO5.5 (Bi4O11), which is the vanadium analog of the first member of the Aurivillius family of oxides of the general formula Bi2An−1BnO3n+3, has been prepared and characterized. The vanadate has the expected layered structure and is ferroelectric with a Curie temperature of 720 K. While we have not been able to synthesize the vanadium analog of the n = 2 member of the Aurivillius family, we have examined the structure and properties of a vanadate of the composition Bi2V3O9.

scholarly journals Arene Ruthenium Metalla-Assemblies with Anthracene Moieties for PDT Applications

Inorganics ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 97 ◽  
Author(s):  
Marie Gaschard ◽  
Farzaneh Nehzat ◽  
Thomas Cheminel ◽  
Bruno Therrien
Keyword(s):  
Molecular Structure ◽  
Single Crystal ◽  
General Formula ◽  
Structure Analysis ◽  
White Light ◽  
Light Irradiation ◽  
Synthesis And Characterization ◽  
X Ray

The synthesis and characterization of three metalla-rectangles of the general formula [Ru4(η6-p-cymene)4(μ4-clip)2(μ2-Lanthr)2][CF3SO3]4 (Lanthr: 9,10-bis(3,3’-ethynylpyridyl) anthracene; clip = oxa: oxalato; dobq: 2,5-dioxido-1,4-benzoquinonato; donq: 5,8-dioxido-1,4-naphthoquinonato) are presented. The molecular structure of the metalla-rectangle [Ru4(η6-p-cymene)4(μ4-oxa)2(μ2-Lanthr)2]4+ has been confirmed by the single-crystal X-ray structure analysis of [Ru4(η6-p-cymene)4(μ4-oxa)2(μ2-Lanthr)2][CF3SO3]4 · 4 acetone (A2 · 4 acetone), thus showing the anthracene moieties to be available for reaction with oxygen. While the formation of the endoperoxide form of Lanthr was observed in solution upon white light irradiation, the same reaction does not occur when Lanthr is part of the metalla-assemblies.

scholarly journals Synthesis and characterization of new complexes of Co+2 , Ni+2 , Cu+2 and Zn+2 with (Sodium acetate thio ) ethylene ligands

2013 ◽  
Vol 10 (3) ◽  
pp. 650-657
Author(s):  
Baghdad Science Journal
Keyword(s):  
Content Analysis ◽  
General Formula ◽  
Metal Content ◽  
Sodium Acetate ◽  
Magnetic Measurement ◽  
Synthesis And Characterization ◽  
Square Planar ◽  
Square Planar Complexes ◽  
Uv Visible

This research involves the preparation of new ligands 1,1,2,2- tetrakis (sodium acetate thio)ethylene(L1) and 1,1,2- tris(sodiumacetatethio) ethylene(L2), through the reaction of disodium thioglycolate) with tetra chloro ethylene or tri chloro ethylene in (1:4) or (1:3) moler ratio . Homodinucliar complexes of general formlu [M2(L1)] and [M2(L2)ClH2O] , when M= Co(II), Ni(II), Cu (II) and Zn(II) also mono nuclear complexes of general formula [M(L2)] . The prepared complexes were characterized using spectral method (UV/Visible/ IR) , metal content analysis , magnetic and atomic measurements . The spectral and magnetic measurement indicats that some complexes have tetrahedral or square planar complexes environtment .

Chemistry of Alkoxo Complexes, Part III *Synthesis and Characterization of Some Mono(carboxylato)mono (alkoxo)nickel(II) Complexes

1979 ◽  
Vol 34 (3) ◽  
pp. 459-463 ◽  
Author(s):  
B. P. Baranwal ◽  
G. K. Parashar ◽  
R. C. Mehrotra
Keyword(s):  
Molecular Weight ◽  
Magnetic Susceptibility ◽  
General Formula ◽  
Synthesis And Characterization ◽  
Probable Structure ◽  
Equimolar Ratio ◽  
Elemental Analyses ◽  
Infra Red ◽  
Interchange Reactions

AbstractA number of mono(carboxylato)mono(alkoxo)nickel(II) complexes of the general formula, Ni(OR)(OOCR′), (with R′ = C13H27, C15H35 and C17H35) have been synthesized (where R = Me and Pri) by the reactions of nickel methoxide and isopropoxide with the respective carboxylic acids in equimolar ratio and (where R = Et and But) by alcohol interchange reactions. A study of the molecular weight, infra-red and electronic reflectance spectra and magnetic susceptibility in addition to elemental analyses has been carried out to throw some light on the probable structure of these derivatives.

Synthesis and characterization of an homologous series of bis(amido)diazadipnictetidines (Pnict = P, As, Sb, Bi)

2001 ◽  
Vol 79 (3) ◽  
pp. 342-348 ◽  
Author(s):  
Neil Burford ◽  
T Stanley Cameron ◽  
Kim-Chung Lam ◽  
Daren J LeBlanc ◽  
Charles LB Macdonald ◽  
...  
Keyword(s):  
Key Words ◽  
General Formula ◽  
Homologous Series ◽  
Spectroscopic Characterization ◽  
Structural Features ◽  
Synthesis And Characterization ◽  
General Reaction ◽  
Coordinative Unsaturation

Spectroscopic and structural features are presented for the first homologous series of diazadipnictetidines, which have the general formula [DipNPnN(H)Dip]2 (Pn = P, As, Sb, Bi; Dip = 2,6-diisopropylphenyl). The compounds are obtained from a general reaction of the corresponding halopnictine with excess LiN(H)Dip, which was previously reported for [DipNBiN(H)Dip]2. However, isolation is improved by the introduction of LiN(H)-t-Bu (at the appropriate stoichiometry) following the addition of LiN(H)Dip. The intermediate steric presence of the Dip substituent is suitable to support the heterocatenate framework for all homologues. This is in contrast to the small substituents (e.g. alkyl), which enable both bis- and tris-amination, and the larger substituent (Mes* = tri-tert-butylphenyl), which can impose coordinative unsaturation (aminoiminopnictine) for the smaller congeners (P and As).Key words: phosphorus, arsenic, antimony, bismuth, phosphazanes, phosphetidines, synthesis, structures, spectroscopic characterization.

ChemInform Abstract: REACTIVITY OF (CO4(CO)12). SYNTHESIS AND CHARACTERIZATION OF TETRACOBALT CARBONYL ANIONS OF GENERAL FORMULA (CO4(CO)11X)-

1981 ◽  
Vol 12 (1) ◽  
Author(s):  
G. LONGONI ◽  
S. CAMPANELLA ◽  
A. CERIOTTI ◽  
P. CHINI ◽  
V. G. ALBANO ◽  
...  
Keyword(s):  
General Formula ◽  
Synthesis And Characterization

Synthesis and Characterization of 4-Substituted 1-(4-Halogenophenyl)pyrrolidin-2-ones with Azole and Azine Moieties

Heterocycles ◽  
2013 ◽  
Vol 87 (5) ◽  
pp. 1059 ◽  
Author(s):  
Vytautas Mickevicius ◽  
Rita Vaickelioniene ◽  
Gema Mikulskiene
Keyword(s):  
Synthesis And Characterization ◽  
Substituted 1

Synthesis and characterization of Hg(II) complexes of Me3MCH2SeMe, (M = Si, Ge). Crystal structures of [HgX2(Me3SiCH2SeMe)]2, X = Cl, Br, I

1987 ◽  
Vol 65 (9) ◽  
pp. 2305-2311 ◽  
Author(s):  
Raj K. Chadha ◽  
John E. Drake ◽  
Neil T. McManus ◽  
Anil Mislankar
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Raman Spectroscopy ◽  
Magnetic Resonance ◽  
Crystal Structures ◽  
General Formula ◽  
Synthesis And Characterization ◽  
Nuclear Magnetic

Complexes of the general formula [HgX2(Me3MCH2SeMe)]2, where M = Si, Ge; X = Cl, Br, I, have been prepared and characterized by 1H nuclear magnetic resonance and Raman spectroscopy. Crystal structures of [HgX2(Me3SiCH2SeMe)]2, where X = Cl, Br, and I (1, 2, and 3 respectively), show that they have centrosymmetric dinuclear structures. The crystals of 1 and 2 are monoclinic, while those of 3 are triclinic. For 1: P21/c, a = 14.235(11), b = 6.551(6), c = 14.211(9) Å, β = 117.33(5)°, Z = 2, and R = 0.0560. For 2: P21/c, a = 14.329(6), b = 6.695(2), c = 14.819(4) Å, β = 118.47(2)°, Z = 2, and R = 0.0540. For 3: [Formula: see text], a = 7.651(2), b = 8.387(2), c = 12.321(4) Å, α = 90.07(2), β = 91.80(2), γ = 116.02(2)°, Z = 1, and R = 0.0565. All three complexes show the expected pseudotetrahedral geometry about mercury. The stereochemical differences arise in the arrangement of the bulky trimethylsilylmethyl groups, which in the HgI2 adduct are rotated away from the centre of the molecule but which in the HgCl2 and HgBr2 adducts are turned towards the centre. These are the first dinuclear structures reported of HgBr2 and HgI2 adducts since it was demonstrated 46 years ago by Evans etal. that [HgBr2(AsBu3)]2 was present in [HgBr2(AsBu3)2•HgBr2].

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