Synthesis and characterization of an homologous series of bis(amido)diazadipnictetidines (Pnict = P, As, Sb, Bi)

2001 ◽  
Vol 79 (3) ◽  
pp. 342-348 ◽  
Author(s):  
Neil Burford ◽  
T Stanley Cameron ◽  
Kim-Chung Lam ◽  
Daren J LeBlanc ◽  
Charles LB Macdonald ◽  
...  
Keyword(s):  
Key Words ◽  
General Formula ◽  
Homologous Series ◽  
Spectroscopic Characterization ◽  
Structural Features ◽  
Synthesis And Characterization ◽  
General Reaction ◽  
Coordinative Unsaturation

Spectroscopic and structural features are presented for the first homologous series of diazadipnictetidines, which have the general formula [DipNPnN(H)Dip]2 (Pn = P, As, Sb, Bi; Dip = 2,6-diisopropylphenyl). The compounds are obtained from a general reaction of the corresponding halopnictine with excess LiN(H)Dip, which was previously reported for [DipNBiN(H)Dip]2. However, isolation is improved by the introduction of LiN(H)-t-Bu (at the appropriate stoichiometry) following the addition of LiN(H)Dip. The intermediate steric presence of the Dip substituent is suitable to support the heterocatenate framework for all homologues. This is in contrast to the small substituents (e.g. alkyl), which enable both bis- and tris-amination, and the larger substituent (Mes* = tri-tert-butylphenyl), which can impose coordinative unsaturation (aminoiminopnictine) for the smaller congeners (P and As).Key words: phosphorus, arsenic, antimony, bismuth, phosphazanes, phosphetidines, synthesis, structures, spectroscopic characterization.

Synthesis and characterization of layered bismuth vanadates

1990 ◽  
Vol 5 (11) ◽  
pp. 2718-2722 ◽  
Author(s):  
K. B. R. Varma ◽  
G. N. Subbanna ◽  
T. N. Guru ◽  
C. N. R. Rao
Keyword(s):  
Curie Temperature ◽  
General Formula ◽  
Layered Structure ◽  
Synthesis And Characterization ◽  
Structure And Properties ◽  
Bismuth Vanadates

Bi2VO5.5 (Bi4O11), which is the vanadium analog of the first member of the Aurivillius family of oxides of the general formula Bi2An−1BnO3n+3, has been prepared and characterized. The vanadate has the expected layered structure and is ferroelectric with a Curie temperature of 720 K. While we have not been able to synthesize the vanadium analog of the n = 2 member of the Aurivillius family, we have examined the structure and properties of a vanadate of the composition Bi2V3O9.

scholarly journals Arene Ruthenium Metalla-Assemblies with Anthracene Moieties for PDT Applications

Inorganics ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 97 ◽  
Author(s):  
Marie Gaschard ◽  
Farzaneh Nehzat ◽  
Thomas Cheminel ◽  
Bruno Therrien
Keyword(s):  
Molecular Structure ◽  
Single Crystal ◽  
General Formula ◽  
Structure Analysis ◽  
White Light ◽  
Light Irradiation ◽  
Synthesis And Characterization ◽  
X Ray

The synthesis and characterization of three metalla-rectangles of the general formula [Ru4(η6-p-cymene)4(μ4-clip)2(μ2-Lanthr)2][CF3SO3]4 (Lanthr: 9,10-bis(3,3’-ethynylpyridyl) anthracene; clip = oxa: oxalato; dobq: 2,5-dioxido-1,4-benzoquinonato; donq: 5,8-dioxido-1,4-naphthoquinonato) are presented. The molecular structure of the metalla-rectangle [Ru4(η6-p-cymene)4(μ4-oxa)2(μ2-Lanthr)2]4+ has been confirmed by the single-crystal X-ray structure analysis of [Ru4(η6-p-cymene)4(μ4-oxa)2(μ2-Lanthr)2][CF3SO3]4 · 4 acetone (A2 · 4 acetone), thus showing the anthracene moieties to be available for reaction with oxygen. While the formation of the endoperoxide form of Lanthr was observed in solution upon white light irradiation, the same reaction does not occur when Lanthr is part of the metalla-assemblies.

Synthesis and characterization of the binuclear diamido titanium chalcogenides [(Ar)NCH2CH2CH2N(Ar)]2Ti(µ-E)2 (E = Se, Te)

2002 ◽  
Vol 80 (11) ◽  
pp. 1524-1529 ◽  
Author(s):  
Tianle Zhang ◽  
Warren E Piers ◽  
Masood Parvez
Keyword(s):  
Solid State ◽  
Key Words ◽  
Synthesis And Characterization ◽  
Catalyst Precursor ◽  
Tellurium Atom ◽  
Titanium Complex ◽  
X Ray ◽  
X Ray Crystallography ◽  
Atom Source

Reaction of McConville's chelating amido titanium complex [(Ar)NCH2CH2CH2N(Ar)]Ti(CH3)2 (Ar = 2,6-i-Pr2C6H3) with either elemental Se or the tellurium atom source Te=PBu3 resulted in the formation of bis-µ-chalcogenido dimers [(Ar)NCH2CH2CH2N(Ar)]2Ti(µ-E)2 (E = Se, 2; Te, 3) with concommitant loss of EMe2. The dimers 2 and 3 were characterized spectroscopically and via X-ray crystallography. The two compounds are isostructural in the solid state. The tellurido dimer 3 may also be synthesized by reduction of the diamido dichloride [(Ar)NCH2CH2CH2N(Ar)]2TiCl2 with Na–Hg amalgam followed by treatment with Te=PBu3. This dimer is unreactive toward further Te=PBu3 or stannanes such as HSnBu3. Unlike decamethyltitanocene derivatives, the diamido complex is not an effective catalyst precursor for the heterohydrodecoupling of Te=PBu3 and HSnBu3.Key words: diamido titanium complexes, selenides, tellurides.

scholarly journals Synthesis and characterization of new complexes of Co+2 , Ni+2 , Cu+2 and Zn+2 with (Sodium acetate thio ) ethylene ligands

2013 ◽  
Vol 10 (3) ◽  
pp. 650-657
Author(s):  
Baghdad Science Journal
Keyword(s):  
Content Analysis ◽  
General Formula ◽  
Metal Content ◽  
Sodium Acetate ◽  
Magnetic Measurement ◽  
Synthesis And Characterization ◽  
Square Planar ◽  
Square Planar Complexes ◽  
Uv Visible

This research involves the preparation of new ligands 1,1,2,2- tetrakis (sodium acetate thio)ethylene(L1) and 1,1,2- tris(sodiumacetatethio) ethylene(L2), through the reaction of disodium thioglycolate) with tetra chloro ethylene or tri chloro ethylene in (1:4) or (1:3) moler ratio . Homodinucliar complexes of general formlu [M2(L1)] and [M2(L2)ClH2O] , when M= Co(II), Ni(II), Cu (II) and Zn(II) also mono nuclear complexes of general formula [M(L2)] . The prepared complexes were characterized using spectral method (UV/Visible/ IR) , metal content analysis , magnetic and atomic measurements . The spectral and magnetic measurement indicats that some complexes have tetrahedral or square planar complexes environtment .

Synthesis and characterization of kesterite Cu2ZnSnTe4via ball-milling of elemental powder precursors

RSC Advances ◽  
2016 ◽  
Vol 6 (73) ◽  
pp. 68754-68759 ◽  
Author(s):  
Devendra Pareek ◽  
K. R. Balasubramaniam ◽  
Pratibha Sharma
Keyword(s):  
Solar Cells ◽  
Ball Milling ◽  
Homologous Series ◽  
Elemental Powder ◽  
Synthesis And Characterization ◽  
Chemical Route ◽  
Light Absorber ◽  
Absorber Material

Cu2ZnSnTe4 was synthesized using mechano-chemical route from its elemental precursors. A homologous series of kesterite light absorber material Cu2ZnSnX4 (X: S, Se, Te) can be used for realization of multi-junction solar cells.

Chemistry of Alkoxo Complexes, Part III *Synthesis and Characterization of Some Mono(carboxylato)mono (alkoxo)nickel(II) Complexes

1979 ◽  
Vol 34 (3) ◽  
pp. 459-463 ◽  
Author(s):  
B. P. Baranwal ◽  
G. K. Parashar ◽  
R. C. Mehrotra
Keyword(s):  
Molecular Weight ◽  
Magnetic Susceptibility ◽  
General Formula ◽  
Synthesis And Characterization ◽  
Probable Structure ◽  
Equimolar Ratio ◽  
Elemental Analyses ◽  
Infra Red ◽  
Interchange Reactions

AbstractA number of mono(carboxylato)mono(alkoxo)nickel(II) complexes of the general formula, Ni(OR)(OOCR′), (with R′ = C13H27, C15H35 and C17H35) have been synthesized (where R = Me and Pri) by the reactions of nickel methoxide and isopropoxide with the respective carboxylic acids in equimolar ratio and (where R = Et and But) by alcohol interchange reactions. A study of the molecular weight, infra-red and electronic reflectance spectra and magnetic susceptibility in addition to elemental analyses has been carried out to throw some light on the probable structure of these derivatives.

Synthesis and Characterization of Tetrakis(pentafluoroethyl)germane

Synthesis ◽  
2017 ◽  
Vol 49 (11) ◽  
pp. 2389-2393 ◽  
Author(s):  
Stefanie Pelzer ◽  
Beate Neumann ◽  
Hans-Georg Stammler ◽  
Nikolai Ignat’ev ◽  
Reint Eujen ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Nmr Spectroscopy ◽  
Ir Spectroscopy ◽  
Diffraction Analysis ◽  
Spectroscopic Characterization ◽  
Synthesis And Characterization ◽  
X Ray Diffraction ◽  
X Ray ◽  
Comprehensive Characterization

This paper describes the synthesis and comprehensive characterization of tetrakis(pentafluoroethyl)germane. In addition to a complete NMR spectroscopic characterization, including the rarely used 73Ge NMR spectroscopy, Ge(C2F5)4 was studied by IR spectroscopy, mass spectrometry as well as X-ray diffraction analysis. A 73Ge NMR investigation as well as an X-ray diffraction study of the related germane Ge(CF3)4 are also included.

Synthesis and Characterization of a Novel Azoester Homologous Series

2015 ◽  
Vol 606 (1) ◽  
pp. 47-55
Author(s):  
V. C. Kotadiya ◽  
M. D. Khunt ◽  
U. C. Bhoya
Keyword(s):  
Homologous Series ◽  
Synthesis And Characterization

scholarly journals Using small molecule complexes to elucidate features of photosynthetic water oxidation

2007 ◽  
Vol 363 (1494) ◽  
pp. 1271-1281 ◽  
Author(s):  
Kristof Meelich ◽  
Curtis M Zaleski ◽  
Vincent L Pecoraro
Keyword(s):  
Water Oxidation ◽  
Spectroscopic Characterization ◽  
Structural Features ◽  
Oxygen Evolving Complex ◽  
Model Complexes ◽  
Small Model ◽  
Oxygen Evolving ◽  
Photosynthetic Water Oxidation ◽  
Insight Into

The molecular oxygen produced in photosynthesis is generated via water oxidation at a manganese–calcium cluster called the oxygen-evolving complex (OEC). While studies in biophysics, biochemistry, and structural and molecular biology are well known to provide deeper insight into the structure and workings of this system, it is often less appreciated that biomimetic modelling provides the foundation for interpreting photosynthetic reactions. The synthesis and characterization of small model complexes, which either mimic structural features of the OEC or are capable of providing insight into the mechanism of O 2 evolution, have become a vital contributor to this scientific field. Our group has contributed to these findings in recent years through synthesis of model complexes, spectroscopic characterization of these systems and probing the reactivity in the context of water oxidation. In this article we describe how models have made significant contributions ranging from understanding the structure of the water-oxidation centre (e.g. contributions to defining a tetrameric Mn 3 Ca-cluster with a dangler Mn) to the ability to discriminate between different mechanistic proposals (e.g. showing that the Babcock scheme for water oxidation is unlikely).

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