Origin of the Ir-Si Bond Shortening in Ir-NSiN complexes
Keyword(s):
The Ir-Si bond distances reported for Ir-(fac-k3-NSiNOPy) and Ir-(fac-k3-NSiN4MeOPy) species (NSiNOPy = bis(pyridine-2-yloxy)methylsilyl and NSiN4MeOPy = bis(4-methyl-pyridine-2-yloxy)methylsily) are in the range of 2.220-2.235 Å. These values are in the lowest...
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