Chemically Robust and Readily Available Quinoline-based PNN Iron Complexes: Application in C-H Borylation of Arenes

2021 ◽  
Author(s):  
Masahiro Kamitani
Keyword(s):  
Iron Complexes ◽  
Iron Catalysts

Iron catalysts have been used for over a century to produce ammonia industrially. However, the use of iron catalysts generally remained quite limited until relatively recently, when the abundance and...

scholarly journals Iron catalysts with N-ligands for carbene transfer of diazo reagents

2020 ◽  
Vol 49 (14) ◽  
pp. 4867-4905 ◽  
Author(s):  
Caterina Damiano ◽  
Paolo Sonzini ◽  
Emma Gallo
Keyword(s):  
Catalytic Activity ◽  
Reaction Mechanisms ◽  
Iron Complexes ◽  
Iron Catalysts ◽  
Nitrogen Ligands ◽  
Carbene Transfer ◽  
Diazo Reagents

This review provides an overview of the catalytic activity of iron complexes of nitrogen ligands in driving carbene transfers towards CC, C–H and X–H bonds. The reactivity of diazo reagents is discussed as well as the proposed reaction mechanisms.

Iron complexes used for the preparation of zeolites supported iron catalysts

1989 ◽  
Vol 56 (1) ◽  
pp. L1-L7
Author(s):  
Grigore Pop ◽  
Gavril Musca ◽  
Ecaterina Pop ◽  
Pavel Tomi ◽  
Adrian Sarǎu ◽  
...  
Keyword(s):  
Iron Complexes ◽  
Iron Catalysts ◽  
Supported Iron

Mechanism of water oxidation by non-heme iron catalysts when driven with sodium periodate

2014 ◽  
Vol 43 (33) ◽  
pp. 12501-12513 ◽  
Author(s):  
Alexander R. Parent ◽  
Takashi Nakazono ◽  
Shu Lin ◽  
Satoshi Utsunomiya ◽  
Ken Sakai
Keyword(s):  
Water Oxidation ◽  
Sodium Periodate ◽  
Iron Complexes ◽  
Heme Iron ◽  
Iron Catalysts ◽  
Dinuclear Complexes ◽  
Oxidation Catalysts ◽  
Monomeric Species ◽  
Non Heme Iron

Non-heme iron complexes were determined to serve as homogeneous water oxidation catalysts when driven with sodium periodate. Both mononuclear and dinuclear complexes were found to be active for water oxidation, with the monomeric species exhibiting higher rates.

A NGR STUDY OF IRON CATALYSTS IN CO HYDROCONDENSATION REACTIONS

1980 ◽  
Vol 41 (C1) ◽  
pp. C1-339-C1-340
Author(s):  
N. Nahon ◽  
V. Perrichon ◽  
P. Turlier ◽  
P. Bussière
Keyword(s):  
Iron Catalysts

ДИНИТРОЗИЛЬНЫЕ КОМПЛЕКСЫ ЖЕЛЕЗА C ТИОЛСОДЕРЖАЩИМИ ЛИГАНДАМИ ПРЕДСТАВЛЕНЫ В ЖИВЫХ ОРГАНИЗМАХ В ОСНОВНОМ ИХ БИЯДЕРНОЙ ФОРМОЙ

2020 ◽  
Vol 65 (6) ◽  
pp. 1142-1153
Author(s):  
В.Д. Микоян ◽  
◽  
Е.Н. Бургова ◽  
Р.Р. Бородулин ◽  
А.Ф. Ванин ◽  
...  
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Sodium Nitrite ◽  
Iron Complexes ◽  
Paramagnetic Resonance ◽  
First Case ◽  
Dinitrosyl Iron ◽  
Electron Paramagnetic ◽  
Dinitrosyl Complexes

The number of mononitrosyl iron complexes with diethyldithiocarbamate, formed in the liver of mice in vivo and in vitro after intraperitoneal injection of binuclear dinitrosyl iron complexes with N-acetyl-L-cysteine or glutathione, S-nitrosoglutathione, sodium nitrite or the vasodilating drug Isoket® was assessed by electron paramagnetic resonance (EPR). The number of the said complexes, in contrast to the complexes, formed after nitrite or Isoket administration, the level of which sharply increased after treatment of liver preparations with a strong reducing agent - dithionite, did not change in the presence of dithionite. It was concluded that, in the first case, EPR-detectable mononitrosyl iron complexes with diethyldithiocarbamate in the absence and presence of dithionite appeared as a result of the reaction of NO formed from nitrite with Fe2+-dieth- yldithiocarbamate and Fe3+-diethyldithiocarbamate complexes, respectively. In the second case, mononitrosyl iron complexes with diethyldithiocarbamate appeared as a result of the transition of iron-mononitosyl fragments from ready-made iron-dinitrosyl groups of binuclear dinitrosyl complexes, which is three to four times higher than the content of the mononuclear form of these complexes in the tissue...

Effect of Dinitrosyl Iron Complexes (NO Donors) on the Metabolic Processes of Human Fibroblasts

2018 ◽  
Vol 483 (4) ◽  
pp. 452-456
Author(s):  
A. Gizatullin ◽  
◽  
N. Akent'eva ◽  
N. Sanina ◽  
N. Shmatko ◽  
...  
Keyword(s):  
Human Fibroblasts ◽  
Iron Complexes ◽  
Dinitrosyl Iron Complexes ◽  
Metabolic Processes ◽  
No Donors ◽  
Dinitrosyl Iron

The Influence of the Nature of the Ligand on the Antitumor Activity and Cytotoxic Effect of Binuclear Dinitrosyl Iron Complexes

BIOPHYSICS ◽  
2020 ◽  
Vol 65 (5) ◽  
pp. 863-868
Author(s):  
A. F. Vanin ◽  
L. A. Ostrovskaya ◽  
D. B. Korman ◽  
E. I. Nekrasova ◽  
O. O. Riabaya ◽  
...  
Keyword(s):  
Antitumor Activity ◽  
Cytotoxic Effect ◽  
Iron Complexes ◽  
Dinitrosyl Iron Complexes ◽  
Dinitrosyl Iron

scholarly journals Multiple electrochemically accessible colour states in surface-confined metal-organic monolayers: Stepwise embedding individual metal centres

2021 ◽  
Author(s):  
Nadia O. Laschuk ◽  
Rana Ahmad ◽  
Iraklii I. Ebralidze ◽  
Jade Poisson ◽  
Franco Gaspari ◽  
...  
Keyword(s):  
Iron Complexes ◽  
Organic Monolayers ◽  
Individual Metal ◽  
Surface Enhanced ◽  
Metal Organic

Sequential covalent embedding of cobalt, osmium, and iron complexes of 4'-(pyridin-4-yl)-2,2':6',2''-terpyridine to surface-enhanced support pre-functionalized with a templating layer results in hetero-bimetallic (Os-Fe and Co-Fe) and hetero-trimetallic (Co-Os-Fe) monolayer materials....

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