Mechanism of water oxidation by non-heme iron catalysts when driven with sodium periodate

2014 ◽  
Vol 43 (33) ◽  
pp. 12501-12513 ◽  
Author(s):  
Alexander R. Parent ◽  
Takashi Nakazono ◽  
Shu Lin ◽  
Satoshi Utsunomiya ◽  
Ken Sakai
Keyword(s):  
Water Oxidation ◽  
Sodium Periodate ◽  
Iron Complexes ◽  
Heme Iron ◽  
Iron Catalysts ◽  
Dinuclear Complexes ◽  
Oxidation Catalysts ◽  
Monomeric Species ◽  
Non Heme Iron

Non-heme iron complexes were determined to serve as homogeneous water oxidation catalysts when driven with sodium periodate. Both mononuclear and dinuclear complexes were found to be active for water oxidation, with the monomeric species exhibiting higher rates.

Biologically inspired non-heme iron-catalysts for asymmetric epoxidation; design principles and perspectives

2015 ◽  
Vol 51 (76) ◽  
pp. 14285-14298 ◽  
Author(s):  
Olaf Cussó ◽  
Xavi Ribas ◽  
Miquel Costas
Keyword(s):  
Design Principles ◽  
Heme Iron ◽  
Asymmetric Epoxidation ◽  
Iron Catalysts ◽  
Biologically Inspired ◽  
Feature Article ◽  
Non Heme Iron

This feature article collects the progress in the development of non-heme iron catalysts for asymmetric epoxidation.

Olefin Cis-Dihydroxylation versus Epoxidation by Non-Heme Iron Catalysts:  Two Faces of an FeIII−OOH Coin

2002 ◽  
Vol 124 (12) ◽  
pp. 3026-3035 ◽  
Author(s):  
Kui Chen ◽  
Miquel Costas ◽  
Jinheung Kim ◽  
Adrianne K. Tipton ◽  
Lawrence Que
Keyword(s):  
Heme Iron ◽  
Iron Catalysts ◽  
Non Heme Iron

scholarly journals End-On and Side-On Peroxo Derivatives of Non-Heme Iron Complexes with Pentadentate Ligands:  Models for Putative Intermediates in Biological Iron/Dioxygen Chemistry

2003 ◽  
Vol 42 (8) ◽  
pp. 2639-2653 ◽  
Author(s):  
Gerard Roelfes ◽  
Vladislav Vrajmasu ◽  
Kui Chen ◽  
Raymond Y. N. Ho ◽  
Jan-Uwe Rohde ◽  
...  
Keyword(s):  
Iron Complexes ◽  
Heme Iron ◽  
Non Heme Iron ◽  
Pentadentate Ligands ◽  
Derivatives Of
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