scholarly journals From crude industrial waste glycerol to biopropene via Ru mediated hydrodeoxygenation in ionic liquids

2021 ◽  
Author(s):  
Kwinten Janssens ◽  
Maxime Stalpaert ◽  
Mickaël Henrion ◽  
Dirk E. De Vos
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Industrial Waste ◽  
Crude Glycerol ◽  
Catalytic Conversion ◽  
Liquid System ◽  
High Tolerance ◽  
Waste Glycerol

The catalytic conversion of crude glycerol to biopropene was investigated. A bifunctional Ru-ionic liquid system showed a high tolerance for common crude glycerol impurities like water, salts and methanol. After...

scholarly journals HIDROLISIS HASIL DELIGNIFIKASI TANDAN KOSONG KELAPA SAWIT DALAM SISTEM CAIRAN IONIK CHOLINE CHLORIDE

2016 ◽  
Vol 5 (1) ◽  
pp. 27-33
Author(s):  
Gendish Yoricya ◽  
Shinta Aisyah Putri Dalimunthe ◽  
Renita Manurung ◽  
Nimpan Bangun
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Reaction Time ◽  
Choline Chloride ◽  
Liquid System ◽  
Cooking Time ◽  
Raw Material ◽  
Cellulose Content ◽  
Empty Fruit Bunches ◽  
Hydrolysis Conditions

Palm Empty Fruit Bunches (TKKS) was the waste which has a fairly high content of lignocelluloses. Meanwhile, TKKS has not been utilize optimally. With a cellulose content of 45%-50%, TKKS then potentially be used as raw material for bioethanol. In the process of production bioethanol, delignification of lignocellulose the first phase was conducted to dissolve ligament between cellulose, hemicellulose and lignin. In this research, delignification process was carried out using NaOH in the ionic liquid system and without ionic liquids. The purpose of this research was to find out the highest content of cellulose which contained in the TKKS and to determine the hydrolysis of delignification results on palm empty fruit bunches and the best hydrolysis conditions was obtained at the hydrolysis process in the choline chloride ionic liquid system. Delignification process were performed using ionic liquids choline chloride (ChCl) in variety of cooking time with amount different ChCl. This research used TKKS powder cooked at a temperature 130 °C with a variety of cooking time 30, 60, and 90 minutes and the variation of ChCl 10%, 15% and 20% weight of TKKS. Delignification research results used ChCl obtained highest content of cellulose was 40,33%, hemicellulose 20,28%, and lignin 3,62% in cooking treatment 90 minutes and 15% ChCl. While delignification without ChCl obtained highest content of cellulose is 24,98%, hemicellulose 8,25%, and lignin 18,99% in cooking treatment 90 minutes. Delignification process using ChCl be able increase the degree of delignification as big as 61,45%. In the hydrolisis process, the main raw material used cellulose of delignification TKKS result, choline chloride, sulfatl acid, and distilled water. The hydrolysis stage in this research was carried out at temperature 105 0C, catalyst (H2SO4) 10% (w / w) cellulose, ChCl 10%, 15%, and 20% (w / w) cellulose and it was stirred at constant speed 120 rpm with reaction time of 30, 60 and 90 minutes. The result in the hydrolysis stage using ionic liquid obtained glucose. LUFF method analysis showed the maximum result of glucose 37.96% with the best conditions in reaction time 90 minutes and the amount of choline chloride 20%.

scholarly journals Ionic liquids tethered to a preorganised 1,2-diamide motif for extraction of lanthanides

2019 ◽  
Vol 21 (10) ◽  
pp. 2583-2588 ◽  
Author(s):  
Robert Boyd ◽  
Lili Jin ◽  
Peter Nockemann ◽  
Peter K. J. Robertson ◽  
Lorenzo Stella ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Metal Binding ◽  
Liquid System ◽  
Binding Ability ◽  
Metal Binding Ability

The synthesis and metal binding ability of a novel 1,2-diamide functionalised ionic liquid system for lanthanide extractions from water is described in this communication.

Use of selective ionic liquids and ionic liquid/salt mixtures as entrainer in a (vapor + liquid) system to separate n -heptane from toluene

2015 ◽  
Vol 91 ◽  
pp. 156-164 ◽  
Author(s):  
Emilio J. González ◽  
Pablo Navarro ◽  
Marcos Larriba ◽  
Julián García ◽  
Francisco Rodríguez
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Liquid System ◽  
Liquid Salt ◽  
Salt Mixtures ◽  
Vapor Liquid

Binary Ionic Liquid System for Direct Cellulose Etherification

2019 ◽  
Vol 72 (2) ◽  
pp. 101 ◽  
Author(s):  
Takeshi Kakibe ◽  
Satoshi Nakamura ◽  
Kiyokazu Amakuni ◽  
Hajime Kishi
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Reaction Time ◽  
Liquid System ◽  
Cellulose Dissolution

Etherification of cellulose was performed using a mixture of ionic liquids (ILs) playing roles in both cellulose dissolution and catalysis. We investigated the effects of the reaction time and the ratio of these ILs in the mixture. Cellulose etherification was performed in these IL mixtures. The proportion of propoxy cellulose exceeded 2.5 after 24 h.

Ionic Liquids of Bis(alkylethylenediamine)silver(I) Salts and the Formation of Silver(0) Nanoparticles from the Ionic Liquid System

2008 ◽  
Vol 14 (16) ◽  
pp. 5047-5056 ◽  
Author(s):  
Masayasu Iida ◽  
Chihiro Baba ◽  
Michiko Inoue ◽  
Hibiki Yoshida ◽  
Eiji Taguchi ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Liquid System

Room Temperature Depolymerization of Lignin using a Protic and Metal Based-Ionic Liquid System: A Mild Method of Catalytic Conversion and Value Addition

2021 ◽  
Author(s):  
Mohit J Mehta ◽  
Akshay Kulshrestha ◽  
Shweta Sharma ◽  
Arvind Kumar
Keyword(s):  
Ionic Liquid ◽  
Room Temperature ◽  
Catalytic Conversion ◽  
Liquid System ◽  
Value Addition ◽  
System A ◽  
Harsh Conditions

Lignin is one of the most abundant biopolymers which can be utilized to synthesize various chemicals via its depolymerization. However, depolymerization of lignin generally occurs under very harsh conditions. Herein,...

Mapping the “Extra Solvent Power, ESP” of Ionic Liquids for Monomers, Polymers and Globular Nanoparticles

2017 ◽  
Author(s):  
Jose A. Pomposo
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Linear Polymers ◽  
Green Solvents ◽  
Ionic Polymers ◽  
First Time ◽  
Solvent Power

Understanding the miscibility behavior of ionic liquid (IL) / monomer, IL / polymer and IL / nanoparticle mixtures is critical for the use of ILs as green solvents in polymerization processes, and to rationalize recent observations concerning the superior solubility of some proteins in ILs when compared to standard solvents. In this work, the most relevant results obtained in terms of a three-component Flory-Huggins theory concerning the “Extra Solvent Power, ESP” of ILs when compared to traditional non-ionic solvents for monomeric solutes (case I), linear polymers (case II) and globular nanoparticles (case III) are presented. Moreover, useful ESP maps are drawn for the first time for IL mixtures corresponding to case I, II and III. Finally, a potential pathway to improve the miscibility of non-ionic polymers in ILs is also proposed.

Dynamics of Ion Locking in Doubly Polymerized Ionic Liquids

2020 ◽  
Author(s):  
Swati Arora ◽  
Julisa Rozon ◽  
Jennifer Laaser
Keyword(s):  
Dielectric Constant ◽  
Ionic Liquid ◽  
Ionic Liquids ◽  
Ion Pairs ◽  
Polymer Chains ◽  
Ion Motion ◽  
Charged Species ◽  
Broadband Dielectric Spectroscopy ◽  
Covalently Linked ◽  
Insight Into

<div>In this work, we investigate the dynamics of ion motion in “doubly-polymerized” ionic liquids (DPILs) in which both charged species of an ionic liquid are covalently linked to the same polymer chains. Broadband dielectric spectroscopy is used to characterize these materials over a broad frequency and temperature range, and their behavior is compared to that of conventional “singly-polymerized” ionic liquids (SPILs) in which only one of the charged species is attached to the polymer chains. Polymerization of the DPIL decreases the bulk ionic conductivity by four orders of magnitude relative to both SPILs. The timescales for local ionic rearrangement are similarly found to be approximately four orders of magnitude slower in the DPILs than in the SPILs, and the DPILs also have a lower static dielectric constant. These results suggest that copolymerization of the ionic monomers affects ion motion on both the bulk and the local scales, with ion pairs serving to form strong physical crosslinks between the polymer chains. This study provides quantitative insight into the energetics and timescales of ion motion that drive the phenomenon of “ion locking” currently under investigation for new classes of organic electronics.</div>

Ionic Liquid Assisted Synthesis of Some 2-Aminobenzenethiols

2019 ◽  
Vol 16 (7) ◽  
pp. 550-555
Author(s):  
Dinesh K. Jangid ◽  
Keshav L. Ameta ◽  
Surbhi Dhadda ◽  
Anjali Guleria ◽  
Prakash G. Goswami ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Comparative Study ◽  
Maximum Yield ◽  
Efficient Synthesis ◽  
Target Molecules ◽  
Presence And Absence

Ionic Liquid assisted efficient synthesis of some 2-aminobenzenethiols has been reported using three different Ionic Liquids (ILs) namely methylimidazolium tetrafluoroborate [MIM]+[BF4]−, methylimidazolium chloride [MIM]+[Cl]− and methylimidazolium nitrate [MIM]+[NO3]−. A comparative study has been carried out for the synthesis of target molecules in the presence and absence of IL, leading to conclusion that maximum yield has been observed with [MIM]+[BF4]−.

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