ESTIMATION OF NUCLEAR FUSION REQUIREMENTS IN BUBBLES DURING ULTRA-HIGH-PRESSURE, ULTRA-HIGH-TEMPERATURE CAVITATION PROMOTED BY MAGNETIC FIELD

In the present work, a strong magnetic field was applied near the outlet of the water jet nozzle to promote the generation of multifunction cavitation bubbles. Because these bubbles contained charged species, the bubbles experienced a Lorentz force due to the magnetic field and collided with greater force. As such, the internal bubble pressure exceeded the threshold value required for fusion to occur. The expansion of these charged bubbles in response to ultrasonic irradiation affected adjacent charged bubbles so that the energy density of the atoms in the bubbles was greater than the fusion threshold. The results of this work strongly suggest that the formation of bubbles via the UTPC process in conjunction with a strong magnetic field may result in bubble fusion.

Positively-charged plasmonic nanostructures for SERS sensing applications

Integration of ligands equipped with quaternary amines on plasmonic surfaces generates positively-charged nanomaterials suitable for electrostatically binding negatively-charged species paving the way for their application in SERS sensing.

Global Existence and Temporal Decay of Large Solutions for the Poisson--Nernst--Planck Equations in Low Regularity Spaces

We are concerned with the global existence and decay rates of large solutions for the Poisson–Nernst–Planck equations. Based on careful observation of algebraic structure of the equations and using the weighted Chemin–Lerner type norm, we obtain the global existence and optimal decay rates of large solutions without requiring the summation of initial densities of a negatively and positively charged species is small enough. Moreover, the large solution is obtained for initial data belonging to the low regularity Besov spaces with different regularity and integral indices for the different charged species, which indicates more specific coupling relations between the negatively and positively charged species.

Capillary ionic liquid electrospray: beam compositional analysis by orthogonal time-of-flight mass spectrometry

Orthogonal time-of-flight mass spectrometry has been used to characterize the kinetic energy and charged species distributions from an in vacuo electrospray ion source for four different ionic liquids at volumetric flow rates between 0.3 and 3.3 nanolitres per second. In all cases, the mass spectra revealed charged species consisting of singly charged and multiply charged ions as well as two broad, unresolved droplet distributions occurring in the 104 to 106 atomic mass unit per charge range. The mean jet velocity and mean jet breakup potential were established from analysis of the energy profile of the high mass-to-charge droplets. At the jet breakup point, we find the energy loss and the jet diameter flow rate dependence of the electrospray beam to be similar to that determined by Gamero-Castaño (Phys. Fluids, vol. 20, 2008, 032103; Phys. Rev. Fluids, vol. 8, 2021, 013701) for 1-ethyl-3-methylimidazolium bis(trifluromethylsulfonyl)imide at similar volumetric flow rates. Similar trends are observed for all four liquids over the flow regime. A jet instability analysis revealed that jet electrification and viscous effects drive the jet breakup from the case of an uncharged, inviscid jet; jet breakup occurs at droplet and jet radius ratios that deviate from 1.89. Using the analytically determined ratio and the beam profile, different species are modelled to reconstruct the mass spectra; primary droplets constitute only a fraction of the total species present. The populations of the species are discussed.

EQCM Analysis of the Insertion Phenomena in a n-Doped Poly-Alkyl-Terthiophene With Regioregular Pattern of Substitution

In the present work, we have undertaken the study of the n-doping process in poly-3,3″-didodecyl-2,2′:5′,2″-terthiophene (poly-33″-DDTT) employing the electrochemical quartz crystal microbalance (EQCM). The present study aims at understanding how cathodic charge in n-doped poly-33″-DDTT is compensated. For this purpose, the in situ analysis of the variations of the polymeric mass has been considered. Poly-33″-DDTT was obtained as a thin coating onto a metallic substrate via the anodic coupling of the corresponding monomer 3,3″-didodecyl-2,2′:5′,2″-terthiophene (33″-DDTT). When subjected to electrochemical n-doping in the polarization interval -2.5 ≤ Eappl ≤ 0 V vs. Ag/Ag+, the films of poly-33″-DDTT varied their mass according to a mechanism of cations insertion during n-doping and cations extraction during polymer neutralization. In fact, the electrochemical doping of polythiophenes requires the accompanying exchange of charged species to maintain the electroneutrality within the structure of the polymer in all states of polarization. At the end of a full electrochemical cycle (consisting of the n-doping and the successive neutralization of poly-33″-DDTT), the polymer retains a fraction of the mass acquired during n-doping, thus manifesting the phenomena of mass trapping. The combined analysis of electrochemical and microgravimetric data suggests that poly-33″-DDTT in the n-doped state undergoes (or electrocatalyzes) uncontrolled electrochemical reactions that are not accompanied by mass variations.

Physicochemical Insights of the Organic Matter Particles Dispersed in Wastewaters Induced by Bio-Polyelectrolytes

The turbidity and color of the water are mainly caused by colloidal particles. These particles remain in suspension for a long time and can even pass through a very fine filter medium, since they do not have a tendency to agglomerate. Due to this, polyelectrolytes such as chitosan have been used in coagulation-flocculation processes because they dissociate into charged species in solution and these contribute to charges or dissociable groups which are covalently bound to its structure. With the zeta potential measurements (ζ) vs. pH and particle size, the ideal dose of bio-polyelectrolyte was determined with which, the isoelectric point (IEP) was reached, generating electroneutrality in the system, removing 92% of the chemical oxygen demand (COD). The results discussed here represent a sustainable alternative to the water reuse and sanitation problem of the fish processing industry. The use of bio-polyelectrolytes offers that the by-products obtained from the coagulation-flocculation process can be reused and recovered for other uses.

Enhanced Electrokinetic Remediation of Cadmium (Cd)-Contaminated Soil With Interval Power breaking

This study compared electrokinetic (EK) remediation with and without interval power breaking in the removal of total and plant available cadmium (Cd) in the soil. Two laboratory experiments, i.e. EK remediation with interval power breaking (24-12 h power-on-off cycles) and conventional EK remediation (continuous power supply) with the same accumulated time (192 h) of power supply were conducted to remove soil Cd. After the EK remediation by interval power breaking, the total Cd removal efficiency in the soil rose to 38%, in comparison to 28% by the conventional EK remediation. As for the plant available Cd, the removal efficiency was enhanced from 52% to 63%. Additionally, the electric current during the EK remediation and electric conductivity after the EK remediation were higher in the soil treated by interval power breaking, which indicated an enhanced desorption and/or migration of charged species. It further meant that the higher removal efficiency of soil Cd by interval power breaking could be related to the enhanced desorption and/or migration of Cd species. This study indicated that both conventional EK remediation and EK remediation with interval power breaking were effective methods to remove soil Cd but EK remediation with interval power breaking was more efficient.

S+ Implantation in Oxide Ices: Relevance to Europa

<p>The implantation of reactive charged species within low-temperature solids is relevant to astrochemistry and may lead to physico-chemical changes within the solid, such as the formation of new molecules which incorporate the projectile. We have performed the high-fluence (>10<sup>16</sup> ions cm<sup>–2</sup>) implantation of S<sup>+</sup> into CO, CO<sub>2</sub> and H<sub>2</sub>O ices at 20 and 70 K. Our results show that implantation into CO and CO<sub>2</sub> results in the formation of SO<sub>2</sub> at 20 K, although no evidence of SO<sub>2</sub> was observed at 70 K. Implantation into H<sub>2</sub>O yields H<sub>2</sub>SO<sub>4</sub> hydrates. These results are applicable to Europa; one of the Galilean moons of Jupiter.</p>

Controllability of pore size on macroporous sol-gel silica films embedding rhodamine 6G

A facile method is reported to synthesize macroporous silica films embedding rhodamine 6G. The films were obtained by sol-gel and spin-coating processes. Results pointed out a dependence of pore formation on the addition of rhodamine 6G in the film composition. The probable formation process of the pores was attributed to the aggregation of charged species from rhodamine 6G. Although the pores were randomly distributed on the film surface, the pore size was tuned at certain extent by controlling the evaporation and condensation rates at early stages of spin coating. Results indicated that the evaporation rate determined the pore size distribution of the films.