Enabling superior hybrid capacitive deionization performance in NASICON-structured Na3MnTi(PO4)3/C by incorporating a two-species redox reaction

2021 ◽  
Vol 9 (11) ◽  
pp. 6898-6904
Author(s):  
Shiyong Wang ◽  
Gang Wang ◽  
Chi He ◽  
Ningbo Gao ◽  
Bing Lu ◽  
...  

Na3MnTi(PO4)3/C with two-species redox reactions was evaluated as an HCDI electrode for the first time that showed a high CDI performance.

2020 ◽  
Author(s):  
Kehua Dai ◽  
Jing Mao ◽  
Zengqing Zhuo ◽  
Guo Ai ◽  
Wenfeng Mao ◽  
...  

<div>Lattice oxygen redox reactions (ORR) offers opportunities for developing highcapacity batteries, however, suffers the notoriously high voltage hysteresis and low initial coulombic efficiency, which hinder its practical applications. Particularly, ORR was widely considered inherent to these kinetic issues. In this paper, unambiguous evidence of strong and reversible ORR is found in Na<sub>2/3</sub>Ni<sub>1/3</sub>Mn<sub>2/3</sub>O<sub>2</sub>, which displays negligible voltage hysteresis (0.1 V) and high initial coulombic efficiency with a highly stable electrochemical profile. Our independent and quantitative analysis of all the Ni, Mn and O states consistently interpret the redox mechanism of Na<sub>2/3</sub>Ni<sub>1/3</sub>Mn<sub>2/3</sub>O<sub>2</sub>, which reveals, for the first time, a conventional 3d transition-metal ORR system with facile kinetics and highly stable electrochemical profile that previously found only in cationic redox systems.</div>


2019 ◽  
Vol 6 (7) ◽  
pp. 1433-1437 ◽  
Author(s):  
Ziming Wang ◽  
Xingtao Xu ◽  
Jeonghun Kim ◽  
Victor Malgras ◽  
Ran Mo ◽  
...  

Metal–organic framework/polypyrrole hybrids are synthesized and directly used in capacitive deionization for the first time.


2018 ◽  
Vol 9 (23) ◽  
pp. 5178-5182 ◽  
Author(s):  
Xiaodan Huang ◽  
Yang Liu ◽  
Chao Liu ◽  
Jun Zhang ◽  
Owen Noonan ◽  
...  

An aluminum–selenium battery powered by the reversible redox reaction of Se/Se2Cl2 has been developed for the first time.


RSC Advances ◽  
2017 ◽  
Vol 7 (52) ◽  
pp. 32552-32558 ◽  
Author(s):  
Jiali Wang ◽  
Baozhan Zheng ◽  
Jinlan Xiao ◽  
Xiaoling Liu ◽  
Hongyun Ji ◽  
...  

The phenomenon of self-driven motion of mercury drop was found for the first time in NaIO4/H2SO4 solution, which is based on the electrons transfer from aluminum to mercury by redox reaction.


RSC Advances ◽  
2015 ◽  
Vol 5 (80) ◽  
pp. 65068-65073 ◽  
Author(s):  
Dan Chen ◽  
Kai Yang ◽  
Hongyu Wang ◽  
Jun Zhou ◽  
Huining Zhang

Pectin-stabilized nanoscale zero-valent iron was used to removal Cr(vi) and the main mechanisms were redox reaction and adsorption.


2021 ◽  
Vol 21 (1) ◽  
pp. 353
Author(s):  
Fauziah Fauziah

Oxidation-Reduction Reactions (Redox) are one of the hardest reactions to equalize, this means that it is hard to determine the suitable Reaction Coefficient. An easier and more logical train of thought is to remember that a Reduction and an Oxidation reaction happens simultaneously. A Redox Reaction has two methods in order to equalize, that which is by using the “Change in Oxidation Number” method or the “Half-Reaction (Ion-Electron)” method. The students’ skills in completing a Redox Reaction can be observed in the grades that they have achieved. This observation is intended to find out if there is a difference in students’ grades if you were to teach them about the equalization of Redox Reactions using either of these two methods (the “Change in Oxidation Number” method and the “Half-Reaction” method).  The population in this observation consists of the students of Class XII IPA 1 and Class XII IPA 2 of SMAS PERTIWI Jambi that are studying Oxidation-Reduction Reactions. Sample members consist of the students of Class XII IPA 1 and the students of Class XII IPA 3 of SMAS Pertiwi Jambi. The measuring instrument used is a test that has fulfilled standards. Normality tests and Homogeneity tests of the sample in question has been done before the Hypothetical test was implemented.  The average grades of students using the “Change in Oxidation Number” method and the “Half-Reaction” method is 11.75 and 10.8 respectively. The T-value of calculations is approximately 1.81 while the T-value of tables is approximately 2.00. With the Level of Significance being 0.05.  From the data provided above, it can be concluded that there is no difference in student grades whether the “Change in Oxidation Numbers” method or the “Half-Reaction” method is used to equalize Redox Reactions in applicative aspects.


2018 ◽  
Vol 6 (30) ◽  
pp. 14644-14650 ◽  
Author(s):  
Shiyong Wang ◽  
Gang Wang ◽  
Tingting Wu ◽  
Yunqi Zhang ◽  
Fei Zhan ◽  
...  

BCN nanosheets show a pore structure with a high specific surface area and are investigated as CDI electrode materials for the first time.


2020 ◽  
Vol 8 (5) ◽  
pp. 2222-2245 ◽  
Author(s):  
Jin Liu ◽  
Hao Zhang ◽  
Ming Qiu ◽  
Zehua Peng ◽  
Michael K. H. Leung ◽  
...  

Different dimensional supports for non-precious-metal single-atom catalysts play significant roles in their fabrication and electrocatalytic activities for oxygen redox reactions.


2020 ◽  
Vol 8 (3) ◽  
pp. 1443-1450 ◽  
Author(s):  
Yong Liu ◽  
Yue Zhang ◽  
Yuchen Zhang ◽  
Qing Zhang ◽  
Xin Gao ◽  
...  

Highly efficient pseudo-capacitive deionization systems equipped with flow-through electrodes are developed for the first time based on the utilization of MoC nanoparticle-embedded carbon nanofiber aerogels as electrode materials.


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