scholarly journals Electrochemical deposition and thermoelectric characterisation of a semiconducting 2-D metal–organic framework thin film

2020 ◽  
Vol 8 (26) ◽  
pp. 13197-13206 ◽  
Author(s):  
Maria de Lourdes Gonzalez-Juarez ◽  
Eduardo Flores ◽  
Marisol Martin-Gonzalez ◽  
Iris Nandhakumar ◽  
Darren Bradshaw
Keyword(s):  
Thin Film ◽  
Thermoelectric Properties ◽  
Electrochemical Deposition ◽  
Electrochemical Synthesis ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

The anodic electrochemical synthesis of a Cu3(HHTP)2 thin film and its thermoelectric properties are reported for the first time.

A highly crystalline oriented metal–organic framework thin film with an inorganic pillar

2017 ◽  
Vol 53 (73) ◽  
pp. 10112-10115 ◽  
Author(s):  
Yuki Watanabe ◽  
Tomoyuki Haraguchi ◽  
Kazuya Otsubo ◽  
Osami Sakata ◽  
Akihiko Fujiwara ◽  
...  
Keyword(s):  
Thin Film ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

A crystalline oriented metal–organic framework thin film with an anionic inorganic pillar ligand was fabricated for the first time.

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

A thin film of naphthalenediimide-based metal-organic framework with electrochromic properties

2021 ◽  
Vol 594 ◽  
pp. 73-79
Author(s):  
Xianfeng Wu ◽  
Kai Wang ◽  
Junyu Lin ◽  
Dan Yan ◽  
Zhiyong Guo ◽  
...  
Keyword(s):  
Thin Film ◽  
Metal Organic Framework ◽  
Electrochromic Properties ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Efficient electrochemical synthesis of a manganese-based metal–organic framework for H2 and CO2 uptake

2021 ◽  
Vol 23 (3) ◽  
pp. 1220-1227
Author(s):  
Aisha Asghar ◽  
Naseem Iqbal ◽  
Tayyaba Noor ◽  
Benson M. Kariuki ◽  
Luke Kidwell ◽  
...  
Keyword(s):  
Electrochemical Synthesis ◽  
Metal Organic Framework ◽  
Co2 Uptake ◽  
Metal Organic ◽  
Organic Framework

Electrochemical synthesis, from manganese strips and dissolved linker, of a new amine-containing manganese-based metal–organic framework with enhanced CO2 uptake.

Electrochemical synthesis of metal organic framework films with proton conductive property

2017 ◽  
Vol 301 ◽  
pp. 125-132 ◽  
Author(s):  
Feng Zhang ◽  
Tingting Zhang ◽  
Xiaoqin Zou ◽  
Xiaoqiang Liang ◽  
Guangshan Zhu ◽  
...  
Keyword(s):  
Electrochemical Synthesis ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Conductive Property ◽  
Organic Framework
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