A highly crystalline oriented metal–organic framework thin film with an inorganic pillar

2017 ◽  
Vol 53 (73) ◽  
pp. 10112-10115 ◽  
Author(s):  
Yuki Watanabe ◽  
Tomoyuki Haraguchi ◽  
Kazuya Otsubo ◽  
Osami Sakata ◽  
Akihiko Fujiwara ◽  
...  
Keyword(s):  
Thin Film ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

A crystalline oriented metal–organic framework thin film with an anionic inorganic pillar ligand was fabricated for the first time.

scholarly journals Electrochemical deposition and thermoelectric characterisation of a semiconducting 2-D metal–organic framework thin film

2020 ◽  
Vol 8 (26) ◽  
pp. 13197-13206 ◽  
Author(s):  
Maria de Lourdes Gonzalez-Juarez ◽  
Eduardo Flores ◽  
Marisol Martin-Gonzalez ◽  
Iris Nandhakumar ◽  
Darren Bradshaw
Keyword(s):  
Thin Film ◽  
Thermoelectric Properties ◽  
Electrochemical Deposition ◽  
Electrochemical Synthesis ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

The anodic electrochemical synthesis of a Cu3(HHTP)2 thin film and its thermoelectric properties are reported for the first time.

Solvent-Free Powder Synthesis and MOF-CVD Thin Films of the Mesoporous Metal-Organic Framework MAF-6

2019 ◽  
Author(s):  
Timothée Stassin ◽  
Ivo Stassen ◽  
Joao Marreiros ◽  
Alexander John Cruz ◽  
Rhea Verbeke ◽  
...  
Keyword(s):  
Vapor Phase ◽  
Metal Organic Framework ◽  
Chemical Vapor ◽  
Uptake Capacity ◽  
Powder Synthesis ◽  
Crystalline Films ◽  
Metal Organic ◽  
Mesoporous Metal ◽  
First Time ◽  
Organic Framework

A simple solvent- and catalyst-free method is presented for the synthesis of the mesoporous metal-organic framework (MOF) MAF-6 (RHO-Zn(eIm)2) based on the reaction of ZnO with 2-ethylimidazole vapor at temperatures ≤ 100 °C. By translating this method to a chemical vapor deposition (CVD) protocol, mesoporous crystalline films could be deposited for the first time entirely from the vapor phase. A combination of PALS and Kr physisorption measurements confirmed the porosity of these MOF-CVD films and the size of the MAF-6 supercages (diam. ~2 nm), in close agreement with powder data and calculations. MAF-6 powders and films were further characterized by XRD, TGA, SEM, FTIR, PDF and EXAFS. The exceptional uptake capacity of the mesoporous MAF-6 in comparison to the microporous ZIF-8 is demonstrated by vapor-phase loading of a molecule larger than the ZIF-8 windows.

A thin film of naphthalenediimide-based metal-organic framework with electrochromic properties

2021 ◽  
Vol 594 ◽  
pp. 73-79
Author(s):  
Xianfeng Wu ◽  
Kai Wang ◽  
Junyu Lin ◽  
Dan Yan ◽  
Zhiyong Guo ◽  
...  
Keyword(s):  
Thin Film ◽  
Metal Organic Framework ◽  
Electrochromic Properties ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Thin Film Structures of Metal-Organic Framework [Cu3(BTC)2(H2O)3]n on TiO2(110)

2014 ◽  
Vol 82 (5) ◽  
pp. 335-337 ◽  
Author(s):  
Miyuki HASHIMOTO ◽  
Satoshi OKAJIMA ◽  
Toshihiro KONDO ◽  
Kenji HARA ◽  
Wang-Jae CHUN
Keyword(s):  
Thin Film ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Organic Framework

Strain-Controlled Spin Transition in Heterostructured Metal–Organic Framework Thin Film

2021 ◽  
Vol 143 (39) ◽  
pp. 16128-16135
Author(s):  
Tomoyuki Haraguchi ◽  
Kazuya Otsubo ◽  
Osami Sakata ◽  
Akihiko Fujiwara ◽  
Hiroshi Kitagawa
Keyword(s):  
Thin Film ◽  
Metal Organic Framework ◽  
Spin Transition ◽  
Metal Organic ◽  
Organic Framework

Metal–organic frameworks: a universal strategy towards super-elastic hydrogels

2019 ◽  
Vol 10 (18) ◽  
pp. 2263-2272 ◽  
Author(s):  
Huaizhi Liu ◽  
Hao Peng ◽  
Yumeng Xin ◽  
Jiuyang Zhang
Keyword(s):  
Drug Delivery ◽  
Mechanical Performance ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
High Loading ◽  
Loading Capacity ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

We reported for the first time using metal–organic framework (MOF) nanoparticles as effective nanofillers to significantly enhance the mechanical performance of hydrogels. The MOF hydrogels have been developed for drug delivery materials with high loading capacity and much extended drug releasing profiles.

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