Unique Thermoelectric Properties Induced by Intrinsic Nanostructuring in a Polycrystalline Thin‐Film Two‐Dimensional Metal–Organic Framework, Copper Benzenehexathiol

2020 ◽  
Vol 217 (23) ◽  
pp. 2000437
Author(s):  
Ryuichi Tsuchikawa ◽  
Neda Lotfizadeh ◽  
Nabajit Lahiri ◽  
Shuwan Liu ◽  
Mackenzie Lach ◽  
...  
Keyword(s):  
Thin Film ◽  
Thermoelectric Properties ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Polycrystalline Thin Film ◽  
Metal Organic ◽  
Organic Framework

scholarly journals Electrochemical deposition and thermoelectric characterisation of a semiconducting 2-D metal–organic framework thin film

2020 ◽  
Vol 8 (26) ◽  
pp. 13197-13206 ◽  
Author(s):  
Maria de Lourdes Gonzalez-Juarez ◽  
Eduardo Flores ◽  
Marisol Martin-Gonzalez ◽  
Iris Nandhakumar ◽  
Darren Bradshaw
Keyword(s):  
Thin Film ◽  
Thermoelectric Properties ◽  
Electrochemical Deposition ◽  
Electrochemical Synthesis ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
First Time ◽  
Organic Framework

The anodic electrochemical synthesis of a Cu3(HHTP)2 thin film and its thermoelectric properties are reported for the first time.

Synthesis and Structure of a Clathrated Two-Dimensional Metal-Organic Framework: [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2·H2O (L = Bis(1-pyrazinylethylidene)hydrazine)

2008 ◽  
Vol 73 (1) ◽  
pp. 24-31
Author(s):  
Dayu Wu ◽  
Genhua Wu ◽  
Wei Huang ◽  
Zhuqing Wang
Keyword(s):  
Metal Organic Framework ◽  
Channel Structure ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Guest Molecules ◽  
X Ray ◽  
Square Planar ◽  
Metal Organic ◽  
Aqueous Meoh ◽  
Organic Framework

The compound [Cd(4,4'-bpy)2(H2O)2](ClO4)2·(L)2 was obtained by the reaction of Cd(ClO4)2, bis(1-pyrazinylethylidene)hydrazine (L) and 4,4'-bipyridine in aqueous MeOH. Single-crystal X-ray diffraction has revealed its two-dimensional metal-organic framework. The 2-D layers superpose on each other, giving a channel structure. The square planar grids consist of two pairs of shared edges with Cd(II) ion and a 4,4'-bipyridine molecule each vertex and side, respectively. The square cavity has a dimension of 11.817 × 11.781 Å. Two guest molecules of bis(1-pyrazinylethylidene)hydrazine are clathrated in every hydrophobic host cavity, being further stabilized by π-π stacking and hydrogen bonding. The results suggest that the hydrazine molecules present in the network serve as structure-directing templates in the formation of crystal structures.

Two-Dimensional Metal–Organic Framework Nanosheets as an Enzyme Inhibitor: Modulation of the α-Chymotrypsin Activity

2017 ◽  
Vol 139 (24) ◽  
pp. 8312-8319 ◽  
Author(s):  
Ming Xu ◽  
Shuai Yuan ◽  
Xin-Yu Chen ◽  
Yu-Jie Chang ◽  
Gregory Day ◽  
...  
Keyword(s):  
Enzyme Inhibitor ◽  
Metal Organic Framework ◽  
Two Dimensional ◽  
Chymotrypsin Activity ◽  
Metal Organic ◽  
Organic Framework

A thin film of naphthalenediimide-based metal-organic framework with electrochromic properties

2021 ◽  
Vol 594 ◽  
pp. 73-79
Author(s):  
Xianfeng Wu ◽  
Kai Wang ◽  
Junyu Lin ◽  
Dan Yan ◽  
Zhiyong Guo ◽  
...  
Keyword(s):  
Thin Film ◽  
Metal Organic Framework ◽  
Electrochromic Properties ◽  
Metal Organic ◽  
Organic Framework
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