Engineering interfacial entropic effects to generate giant viscosity changes in nanoparticle embedded polymer thin films

Soft Matter ◽  
2020 ◽  
Vol 16 (16) ◽  
pp. 4065-4073 ◽  
Author(s):  
Aparna Swain ◽  
Nafisa Begam ◽  
Sivasurender Chandran ◽  
M. S. Bobji ◽  
J. K. Basu

We demonstrate a new method to study the viscosity of PNC thin films, consisting of polymer grafted nanoparticles (PGNPs) embedded in un-entangled homopolymer melt films, using atomic force microscopy based force–distance spectroscopy.

Langmuir ◽  
2001 ◽  
Vol 17 (11) ◽  
pp. 3286-3291 ◽  
Author(s):  
Binyang Du ◽  
Ophelia K. C. Tsui ◽  
Qingling Zhang ◽  
Tianbai He

2000 ◽  
Vol 39 (Part 1, No. 6B) ◽  
pp. 3830-3833 ◽  
Author(s):  
Takeshi Fukuma ◽  
Kei Kobayashi ◽  
Toshihisa Horiuchi ◽  
Hirofumi Yamada ◽  
Kazumi Matsushige

1999 ◽  
Vol 14 (3) ◽  
pp. 1084-1090 ◽  
Author(s):  
C. F. Zhu ◽  
I. Lee ◽  
J. W. Li ◽  
C. Wang ◽  
X. Y. Cao ◽  
...  

In this paper, we report atomic force microscopy (AFM) images of a tubular polymer and its supermolecular polymer thin films, operated in contact mode at room temperature in air. The configuration models are also calculated using molecular dynamics. The diameter of the polymer nanotube is about 0.7 nm, the smallest size a tube can have. The results of calculation agree with the experimental results.


Langmuir ◽  
2017 ◽  
Vol 33 (6) ◽  
pp. 1385-1390 ◽  
Author(s):  
Dongshi Guan ◽  
Chloé Barraud ◽  
Elisabeth Charlaix ◽  
Penger Tong

2006 ◽  
Vol 38 (4) ◽  
pp. 842-846 ◽  
Author(s):  
Daniel Franta ◽  
Ivan Ohlídal ◽  
Petr Klapetek ◽  
Růžena Nepustilová ◽  
Svatopluk Bajer

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