scholarly journals Selective water-based oxychlorination of phenol with hydrogen peroxide catalyzed by manganous sulfate

RSC Advances ◽  
2017 ◽  
Vol 7 (22) ◽  
pp. 13467-13472 ◽  
Author(s):  
Hongchuan Xin ◽  
Shilei Yang ◽  
Baigang An ◽  
Zengjian An

An efficient, VOC free method for the synthesis of 2,4-dichlorophenol, with simple product separation and a recyclable catalyst is developed.

2021 ◽  
Vol 23 (5) ◽  
pp. 1965-1971
Author(s):  
Fabian Schmidt ◽  
Bastian Zehner ◽  
Marlene Kaposi ◽  
Markus Drees ◽  
János Mink ◽  
...  

Surface-active imidazolium nitrates activate hydrogen peroxide, which enables the epoxidation of olefins. The micelles solubilise the substrate in the aqueous oxidant phase and allow for simple product separation and catalyst recycling.


Synlett ◽  
2020 ◽  
Vol 31 (13) ◽  
pp. 1303-1307
Author(s):  
Zhi-Gang Ren ◽  
David James Young ◽  
Wei Yang ◽  
Wen-Di Xu ◽  
Jin-Jiao Ning

The diphosphine ligand N,N-bis(diphenylphosphanylmethyl)-aniline (bdppma) and PdCl2 afforded a Suzuki–Miyaura catalyst [(bdppma­)PdCl2] that was highly efficient at an ultralow catalyst loading (0.001 mol%) in 20:1 H2O–EtOH. This low catalyst loading in an aqueous solvent system permitted simple product separation by direct filtration without the need for chromatography. The ligand bdppma imparted surprisingly better reactivity than that achieved with other bidentate diphosphine ligands, but the catalytic system had a slightly narrower substrate scope than some similar Pd catalysts reported previously.


2004 ◽  
Vol 116 (31) ◽  
pp. 4189-4191 ◽  
Author(s):  
Valentina Trevisan ◽  
Michela Signoretto ◽  
Stefano Colonna ◽  
Vincenza Pironti ◽  
Giorgio Strukul

2019 ◽  
Vol 68 (2) ◽  
pp. 125-131 ◽  
Author(s):  
Ryuta UEKI ◽  
Ryota KATO ◽  
Yoshitaka IMAIZUMI ◽  
Yoko IWAMOTO ◽  
Waqar A. JADOON ◽  
...  

2017 ◽  
Vol 46 (16) ◽  
pp. 5202-5209 ◽  
Author(s):  
Olga V. Zalomaeva ◽  
Vasilii Yu. Evtushok ◽  
Gennadii M. Maksimov ◽  
Raisa I. Maksimovskaya ◽  
Oxana A. Kholdeeva

The divanadium-substituted polyoxometalate (Bu4N)5−nHn[γ-PW10V2O40] (n = 1–2) is an efficient and recyclable catalyst used for the synthesis of coenzyme Q0 using hydrogen peroxide as a green oxidant.


2019 ◽  
Vol 85 ◽  
pp. 9-14 ◽  
Author(s):  
Lars-Flemming Pedersen ◽  
Paula Rojas-Tirado ◽  
Erik Arvin ◽  
Per Bovbjerg Pedersen

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