Intermetallic transfer of unsymmetrical borylene fragments: isolation of the second early-transition-metal terminal borylene complex and other rare species

Bret B. Macha; Debabrata Dhara; Krzysztof Radacki; Rian D. Dewhurst; Holger Braunschweig

doi:10.1039/d0dt03557b

Intermetallic transfer of unsymmetrical borylene fragments: isolation of the second early-transition-metal terminal borylene complex and other rare species

Dalton Transactions ◽

10.1039/d0dt03557b ◽

2020 ◽

Vol 49 (48) ◽

pp. 17719-17724

Author(s):

Bret B. Macha ◽

Debabrata Dhara ◽

Krzysztof Radacki ◽

Rian D. Dewhurst ◽

Holger Braunschweig

Keyword(s):

Transition Metal ◽

Rare Species ◽

Elimination Method ◽

Early Transition Metal ◽

Transfer Capability ◽

Group 6 ◽

Transition Metal Fragments ◽

Early Transition

We report the synthesis of group 6 borylene complexes by the salt elimination method and study their borylene transfer capability to other transition metal fragments, providing new borylene complexes that are inaccessible by other routes.

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[ As 3 M ( As 3 Pb 3 )] 3‐ (M= Nb, Ta): Ternary Heterometallic Clusters with Early Transition Metal Atoms and Aromatic [Pb 3 ] 2‐

Chinese Journal of Chemistry ◽

10.1002/cjoc.202100161 ◽

2021 ◽

Author(s):

Cong‐Cong Shu ◽

Lei Qiao ◽

Alvaro Muñoz‐Castro ◽

Zhong‐Ming Sun

Keyword(s):

Transition Metal ◽

Heterometallic Clusters ◽

Early Transition Metal ◽

Metal Atoms ◽

Transition Metal Atoms ◽

Early Transition

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Chemical Bonding and Electronic Structure of the Early Transition Metal Borides: ScB, TiB, VB, YB, ZrB, NbB, LaB, HfB, TaB, and WB

The Journal of Physical Chemistry A ◽

10.1021/acs.jpca.1c02886 ◽

2021 ◽

Author(s):

Dakota M. Merriles ◽

Christopher Nielson ◽

Erick Tieu ◽

Michael D. Morse

Keyword(s):

Electronic Structure ◽

Transition Metal ◽

Chemical Bonding ◽

Early Transition Metal ◽

Metal Borides ◽

Early Transition

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How bulk and surface properties of Ti4SiC3, V4SiC3, Nb4SiC3 and Zr4SiC3 tune reactivity: A computational study

Faraday Discussions ◽

10.1039/d1fd00004g ◽

2021 ◽

Author(s):

Matthew Quesne ◽

C. Richard A. Catlow ◽

Nora Henriette De Leeuw

Keyword(s):

Carbon Dioxide ◽

Transition Metal ◽

Surface Properties ◽

In Silico ◽

Computational Study ◽

Max Phase ◽

Early Transition Metal ◽

Silicon Carbides ◽

Carbon Dioxide Hydrogenation ◽

Early Transition

We present several in silico insights into the MAX-phase of early transition metal silicon carbides and explore how these affect carbon dioxide hydrogenation. Periodic desity functional methodology is applied to...

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Platinum supported on early transition metal carbides: Efficient electrocatalysts for methanol electro-oxidation reaction in alkaline electrolyte

Chemical Engineering Journal ◽

10.1016/j.cej.2020.126670 ◽

2021 ◽

Vol 406 ◽

pp. 126670

Author(s):

Olabode T. Ajenifujah ◽

Amideddin Nouralishahi ◽

Sarah Carl ◽

Shawn C. Eady ◽

Zhao Jiang ◽

...

Keyword(s):

Transition Metal ◽

Oxidation Reaction ◽

Alkaline Electrolyte ◽

Metal Carbides ◽

Early Transition Metal ◽

Transition Metal Carbides ◽

Electro Oxidation ◽

Early Transition

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Compositional Phase Change of Early Transition Metal Diselenide (VSe 2 and TiSe 2 ) Ultrathin Films by Postgrowth Annealing

Advanced Materials Interfaces ◽

10.1002/admi.202000497 ◽

2020 ◽

Vol 7 (15) ◽

pp. 2000497

Author(s):

Manuel Bonilla ◽

Sadhu Kolekar ◽

Jiangfeng Li ◽

Yan Xin ◽

Paula Mariel Coelho ◽

...

Keyword(s):

Transition Metal ◽

Phase Change ◽

Ultrathin Films ◽

Early Transition Metal ◽

Postgrowth Annealing ◽

Early Transition

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Titania as an Early Transition Metal Oxide with a High Density of Lewis Acid Sites Workable in Water

The Journal of Physical Chemistry C ◽

10.1021/jp404523r ◽

2013 ◽

Vol 117 (31) ◽

pp. 16028-16033 ◽

Cited By ~ 70

Author(s):

Kiyotaka Nakajima ◽

Ryouhei Noma ◽

Masaaki Kitano ◽

Michikazu Hara

Keyword(s):

Transition Metal ◽

Metal Oxide ◽

Lewis Acid ◽

Transition Metal Oxide ◽

Acid Sites ◽

High Density ◽

Lewis Acid Sites ◽

Early Transition Metal ◽

Early Transition

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ChemInform Abstract: Interstitial Hydrogen in the Early-Transition-Metal Halides.

ChemInform ◽

10.1002/chin.198739005 ◽

1987 ◽

Vol 18 (39) ◽

Author(s):

J. K. BURDETT ◽

G. J. MILLER

Keyword(s):

Transition Metal ◽

Metal Halides ◽

Early Transition Metal ◽

Interstitial Hydrogen ◽

Early Transition

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Interstitial hydrogen in the early transition-metal halides

Journal of the American Chemical Society ◽

10.1021/ja00247a040 ◽

1987 ◽

Vol 109 (13) ◽

pp. 4092-4104 ◽

Cited By ~ 11

Author(s):

Jeremy K. Burdett ◽

Gordon J. Miller

Keyword(s):

Transition Metal ◽

Metal Halides ◽

Early Transition Metal ◽

Interstitial Hydrogen ◽

Early Transition

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Oxazoline Early Transition Metal Complexes: Functionalizable Achiral Titanium(IV), Titanium(III), Zirconium(IV), Vanadium(III), and Chiral Zirconium(IV) Bis(oxazoline) Complexes

Inorganic Chemistry ◽

10.1021/ic00115a020 ◽

1995 ◽

Vol 34 (11) ◽

pp. 2921-2930 ◽

Cited By ~ 41

Author(s):

Pier Giorgio Cozzi ◽

Carlo Floriani ◽

Angiola Chiesi-Villa ◽

Corrado Rizzoli

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Early Transition Metal ◽

Early Transition

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Passivity and its breakdown on sputter-deposited amorphous Al-early transition metal alloys in 1 M HCl at 30°C

Corrosion Science ◽

10.1016/0010-938x(90)90130-w ◽

1990 ◽

Vol 31 ◽

pp. 349-354 ◽

Cited By ~ 63

Author(s):

H. Yoshioka ◽

Q. Yan ◽

H. Habazaki ◽

A. Kawashima ◽

K. Asami ◽

...

Keyword(s):

Transition Metal ◽

Metal Alloys ◽

Early Transition Metal ◽

Transition Metal Alloys ◽

Sputter Deposited ◽

Early Transition

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