Heterometallic trinuclear oxo-centered clusters as single-source precursors for synthesis of stoichiometric monodisperse transition metal ferrite nanocrystals

2020 ◽  
Vol 49 (45) ◽  
pp. 16348-16358
Author(s):  
Karla R. Sanchez-Lievanos ◽  
Mehrin Tariq ◽  
William W. Brennessel ◽  
Kathryn E. Knowles
Keyword(s):  
Transition Metal ◽  
Single Source ◽  
Single Source Precursors ◽  
Phase Pure

Solvothermal reactions of MIIFe2III(μ3-O)(μ2-O2CR)6(H2O)3 (R = CF3, M = Fe, Co, Ni, Cu, Zn) clusters produce monodisperse, phase-pure MFe2O4 nanocrystals.

New Class of Single-Source Precursors for the Synthesis of Main Group−Transition Metal Oxides: Heterobimetallic Pb−Mn β-Diketonates

2009 ◽  
Vol 48 (17) ◽  
pp. 8480-8488 ◽  
Author(s):  
Haitao Zhang ◽  
Jen-Hsien Yang ◽  
Roman V. Shpanchenko ◽  
Artem M. Abakumov ◽  
Joke Hadermann ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Oxides ◽  
Transition Metal Oxides ◽  
Main Group ◽  
Single Source ◽  
Single Source Precursors ◽  
New Class

In Air Synthesis of Bi2S3 and PbS Microcrystals by Thermolysis of Single-Source Precursors

2009 ◽  
Vol 79-82 ◽  
pp. 1343-1346
Author(s):  
Zhen Ni Du ◽  
Yong Cai Zhang
Keyword(s):  
Electron Microscope ◽  
Scanning Electron Microscope ◽  
Inert Gases ◽  
Formation Mechanisms ◽  
Single Source ◽  
X Ray Diffraction ◽  
Single Source Precursors ◽  
X Ray ◽  
Phase Pure ◽  
Scanning Electron

Without the protection of inert gases or vacuum environment, rod-like Bi2S3 and cubic-shaped PbS microcrystals were synthesized directly via pyrolyzing corresponding metal diethyldithiocarbamates in air at 300 °C for 3 h. The products have been characterized by X-ray diffraction and scanning electron microscope, and their possible formation mechanisms were also tentatively proposed. Furthermore, control experiments with multiple-source precursors revealed that our single-source precursors played an important role in preparing phase-pure Bi2S3 and PbS.

scholarly journals N,N-Disubstituted-N′-acylthioureas as modular ligands for deposition of transition metal sulfides

2018 ◽  
Vol 47 (8) ◽  
pp. 2719-2726 ◽  
Author(s):  
Zahra Ali ◽  
Nathaniel E. Richey ◽  
Duane C. Bock ◽  
Khalil A. Abboud ◽  
Javeed Akhtar ◽  
...  
Keyword(s):  
Thin Films ◽  
Chemical Vapor Deposition ◽  
Transition Metal ◽  
Vapor Deposition ◽  
Metal Sulfide ◽  
Chemical Vapor ◽  
Metal Sulfides ◽  
Single Source ◽  
Transition Metal Sulfides ◽  
Single Source Precursors

Readily available N,N-disubstituted-N′-acylthiourea complexes are single source precursors for aerosol assisted chemical vapor deposition of metal sulfide thin films.

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