The introduction of functional side groups and the application of the mixed-linker concept in divalent MIL-53(Ni) materials

2020 ◽  
Vol 49 (26) ◽  
pp. 9148-9154
Author(s):  
Johannes Bitzer ◽  
Alba Titze-Alonso ◽  
Abdelkarim Roshdy ◽  
Wolfgang Kleist
Keyword(s):  
Material Properties ◽  
Metal Organic Frameworks ◽  
Characterization Techniques ◽  
Metal Organic

Divalent MIL-53(Ni) metal–organic frameworks with 2-bromoterephthalate and terephthalate linkers feature interesting material properties as proven by various characterization techniques.

scholarly journals Tunable Metal-Organic Frameworks for Heat Transformation Applications

2018 ◽  
Author(s):  
Somboon Chaemchuen ◽  
Xuan Xiao ◽  
Nikom Klomkliang ◽  
Mekhman S. Yusubov ◽  
Francis Verpoort
Keyword(s):  
Material Properties ◽  
Metal Organic Frameworks ◽  
Working Fluid ◽  
Material Structure ◽  
Framework Design ◽  
Metal Organic ◽  
Related Application ◽  
Heat Transformation ◽  
Adsorbent Materials ◽  
Broad Overview

Metal-Organic Frameworks (MOFs) are a subclass of porous materials that have unique properties such as varieties of structures from different metals and organic linkers, tunable porosity from a structure or framework design, etc. Moreover, modification/functionalization of the material structure could optimize the material properties and demonstrate high potential for a selected application. MOF materials exhibit exceptional properties and make these materials widely applicable including in energy storage and heat transformation applications. This review aims to give a broad overview of MOFs and their development as adsorbent materials having the potential for heat transformation applications. We summarize current investigations, developments, and possibilities of metal-organic frameworks (MOFs) especially the tuning of the porosity and hydrophobic/hydrophilic design required for this specific application. These materials applied as adsorbent are promising in the thermal driven adsorption for heat transformation using water as working fluid and related application.

scholarly journals Tunable Metal–Organic Frameworks for Heat Transformation Applications

Nanomaterials ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 661 ◽  
Author(s):  
Somboon Chaemchuen ◽  
Xuan Xiao ◽  
Nikom Klomkliang ◽  
Mekhman Yusubov ◽  
Francis Verpoort
Keyword(s):  
Energy Storage ◽  
Material Properties ◽  
Metal Organic Frameworks ◽  
Working Fluid ◽  
Material Structure ◽  
Framework Design ◽  
Metal Organic ◽  
Heat Transformation ◽  
Adsorbent Materials ◽  
Broad Overview

Metal–Organic Frameworks (MOFs) are a subclass of porous materials that have unique properties, such as varieties of structures from different metals and organic linkers and tunable porosity from a structure or framework design. Moreover, modification/functionalization of the material structure could optimize the material properties and demonstrate high potential for a selected application. MOF materials exhibit exceptional properties that make these materials widely applicable in energy storage and heat transformation applications. This review aims to give a broad overview of MOFs and their development as adsorbent materials with potential for heat transformation applications. We have briefly overviewed current explorations, developments, and the potential of metal–organic frameworks (MOFs), especially the tuning of the porosity and the hydrophobic/hydrophilic design required for this specific application. These materials applied as adsorbents are promising in thermal-driven adsorption for heat transformation using water as a working fluid and related applications.

Computational prediction of hetero-interpenetration in metal–organic frameworks

2017 ◽  
Vol 53 (12) ◽  
pp. 1953-1956 ◽  
Author(s):  
Ohmin Kwon ◽  
Sanghoon Park ◽  
Hong-Cai Zhou ◽  
Jihan Kim
Keyword(s):  
Material Properties ◽  
Metal Organic Frameworks ◽  
Computational Prediction ◽  
Novel Materials ◽  
Metal Organic

The computational generation of hetero-interpenetrated metal–organic frameworks can lead to novel materials with synergistic material properties.

Metal–organic frameworks with Lewis acidity: synthesis, characterization, and catalytic applications

CrystEngComm ◽  
2017 ◽  
Vol 19 (29) ◽  
pp. 4066-4081 ◽  
Author(s):  
Zhigang Hu ◽  
Dan Zhao
Keyword(s):  
Heterogeneous Catalysis ◽  
Lewis Acid ◽  
Metal Organic Frameworks ◽  
Acid Sites ◽  
Lewis Acidity ◽  
Lewis Acid Sites ◽  
Design And Synthesis ◽  
Characterization Techniques ◽  
Metal Organic ◽  
Catalytic Applications

In this highlight, we review the recent development in the design and synthesis of metal–organic frameworks with Lewis acidity, the characterization techniques of Lewis acid sites, and their applications in heterogeneous catalysis.

Metal oxide integrated metal organic frameworks (MO@MOF): rational design, fabrication strategy, characterization and emerging photocatalytic applications

2021 ◽  
Author(s):  
Satyabrata Subudhi ◽  
Suraj Prakash Tripathy ◽  
Kulamani Parida
Keyword(s):  
Metal Oxide ◽  
Rational Design ◽  
Metal Organic Frameworks ◽  
Synthesis Route ◽  
Characterization Techniques ◽  
Metal Organic ◽  
Photocatalytic Applications

This review focuses on the possible synthesis route, characterization techniques, and mechanistic pathways involved in the photocatalytic applications of MO@MOFs.

Metal-Organic Frameworks

2021 ◽  
Author(s):  
Lars Öhrström ◽  
Francoise M. Amombo Noa
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic

Substrate templated synthesis of single-phase and uniform Zr-porphyrin-based metal–organic frameworks

2020 ◽  
Vol 7 (1) ◽  
pp. 221-231
Author(s):  
Seong Won Hong ◽  
Ju Won Paik ◽  
Dongju Seo ◽  
Jae-Min Oh ◽  
Young Kyu Jeong ◽  
...  
Keyword(s):  
Chemical Bath Deposition ◽  
Single Phase ◽  
Metal Organic Frameworks ◽  
Templated Synthesis ◽  
Pore Structures ◽  
Phase Pure ◽  
Metal Organic ◽  
Cbd Method

We successfully demonstrate that the chemical bath deposition (CBD) method is a versatile method for synthesizing phase-pure and uniform MOFs by controlling their nucleation stages and pore structures.

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