Computational prediction of hetero-interpenetration in metal–organic frameworks

2017 ◽  
Vol 53 (12) ◽  
pp. 1953-1956 ◽  
Author(s):  
Ohmin Kwon ◽  
Sanghoon Park ◽  
Hong-Cai Zhou ◽  
Jihan Kim
Keyword(s):  
Material Properties ◽  
Metal Organic Frameworks ◽  
Computational Prediction ◽  
Novel Materials ◽  
Metal Organic

The computational generation of hetero-interpenetrated metal–organic frameworks can lead to novel materials with synergistic material properties.

scholarly journals Block co-polyMOFs: morphology control of polymer–MOF hybrid materials

2019 ◽  
Vol 10 (6) ◽  
pp. 1746-1753 ◽  
Author(s):  
Sergio Ayala ◽  
Kyle C. Bentz ◽  
Seth M. Cohen
Keyword(s):  
Block Copolymers ◽  
Hybrid Materials ◽  
Metal Organic Frameworks ◽  
Morphology Control ◽  
Novel Materials ◽  
Metal Organic

Block copolymers were used to generate metal–organic frameworks (MOFs) as novel materials (block co-polyMOFs, BCPMOFs) with controlled morphologies.

scholarly journals Metal Organic Frameworks: Synthesis and Application

Molecules ◽  
2020 ◽  
Vol 25 (4) ◽  
pp. 960 ◽  
Author(s):  
Victoria F. Samanidou ◽  
Eleni A. Deliyanni
Keyword(s):  
Metal Organic Frameworks ◽  
Novel Materials ◽  
Metal Organic

The concept of metal–organic frameworks (MOFs) was first introduced in 1990; nowadays they are among the most promising novel materials [...]

The introduction of functional side groups and the application of the mixed-linker concept in divalent MIL-53(Ni) materials

2020 ◽  
Vol 49 (26) ◽  
pp. 9148-9154
Author(s):  
Johannes Bitzer ◽  
Alba Titze-Alonso ◽  
Abdelkarim Roshdy ◽  
Wolfgang Kleist
Keyword(s):  
Material Properties ◽  
Metal Organic Frameworks ◽  
Characterization Techniques ◽  
Metal Organic

Divalent MIL-53(Ni) metal–organic frameworks with 2-bromoterephthalate and terephthalate linkers feature interesting material properties as proven by various characterization techniques.

scholarly journals Tunable Metal-Organic Frameworks for Heat Transformation Applications

2018 ◽  
Author(s):  
Somboon Chaemchuen ◽  
Xuan Xiao ◽  
Nikom Klomkliang ◽  
Mekhman S. Yusubov ◽  
Francis Verpoort
Keyword(s):  
Material Properties ◽  
Metal Organic Frameworks ◽  
Working Fluid ◽  
Material Structure ◽  
Framework Design ◽  
Metal Organic ◽  
Related Application ◽  
Heat Transformation ◽  
Adsorbent Materials ◽  
Broad Overview

Metal-Organic Frameworks (MOFs) are a subclass of porous materials that have unique properties such as varieties of structures from different metals and organic linkers, tunable porosity from a structure or framework design, etc. Moreover, modification/functionalization of the material structure could optimize the material properties and demonstrate high potential for a selected application. MOF materials exhibit exceptional properties and make these materials widely applicable including in energy storage and heat transformation applications. This review aims to give a broad overview of MOFs and their development as adsorbent materials having the potential for heat transformation applications. We summarize current investigations, developments, and possibilities of metal-organic frameworks (MOFs) especially the tuning of the porosity and hydrophobic/hydrophilic design required for this specific application. These materials applied as adsorbent are promising in the thermal driven adsorption for heat transformation using water as working fluid and related application.

scholarly journals Tunable Metal–Organic Frameworks for Heat Transformation Applications

Nanomaterials ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 661 ◽  
Author(s):  
Somboon Chaemchuen ◽  
Xuan Xiao ◽  
Nikom Klomkliang ◽  
Mekhman Yusubov ◽  
Francis Verpoort
Keyword(s):  
Energy Storage ◽  
Material Properties ◽  
Metal Organic Frameworks ◽  
Working Fluid ◽  
Material Structure ◽  
Framework Design ◽  
Metal Organic ◽  
Heat Transformation ◽  
Adsorbent Materials ◽  
Broad Overview

Metal–Organic Frameworks (MOFs) are a subclass of porous materials that have unique properties, such as varieties of structures from different metals and organic linkers and tunable porosity from a structure or framework design. Moreover, modification/functionalization of the material structure could optimize the material properties and demonstrate high potential for a selected application. MOF materials exhibit exceptional properties that make these materials widely applicable in energy storage and heat transformation applications. This review aims to give a broad overview of MOFs and their development as adsorbent materials with potential for heat transformation applications. We have briefly overviewed current explorations, developments, and the potential of metal–organic frameworks (MOFs), especially the tuning of the porosity and the hydrophobic/hydrophilic design required for this specific application. These materials applied as adsorbents are promising in thermal-driven adsorption for heat transformation using water as a working fluid and related applications.

scholarly journals Review of Solid State Hydrogen Storage Methods Adopting Different Kinds of Novel Materials

2015 ◽  
Vol 2015 ◽  
pp. 1-18 ◽  
Author(s):  
Renju Zacharia ◽  
Sami ullah Rather
Keyword(s):  
Solid State ◽  
Hydrogen Storage ◽  
Metal Organic Frameworks ◽  
Hydrogen Energy ◽  
Positive Direction ◽  
Novel Materials ◽  
Metal Organic ◽  
Energy Economy ◽  
Storage Methods ◽  
Metal Doped

Overview of advances in the technology of solid state hydrogen storage methods applying different kinds of novel materials is provided. Metallic and intermetallic hydrides, complex chemical hydride, nanostructured carbon materials, metal-doped carbon nanotubes, metal-organic frameworks (MOFs), metal-doped metal organic frameworks, covalent organic frameworks (COFs), and clathrates solid state hydrogen storage techniques are discussed. The studies on their hydrogen storage properties are in progress towards positive direction. Nevertheless, it is believed that these novel materials will offer far-reaching solutions to the onboard hydrogen storage problems in near future. The review begins with the deficiencies of current energy economy and discusses the various aspects of implementation of hydrogen energy based economy.

Planar tetracoordinate carbon in tungstenacyclobutadiene from alkyne metathesis and expanded structures

2016 ◽  
Vol 45 (4) ◽  
pp. 1769-1778 ◽  
Author(s):  
Premaja R. Remya ◽  
Cherumuttathu H. Suresh
Keyword(s):  
Metal Organic Frameworks ◽  
Alkyne Metathesis ◽  
3 Dimensional ◽  
Novel Materials ◽  
New Strategy ◽  
Metal Organic ◽  
C Center ◽  
The Way

Establishing the Cβ of tungstenacyclobutadiene (WCBD) as a ptC center paves the way for a new strategy to make novel materials containing multiple ptC centers. The 1-, 2- and 3-dimensional expansion of the WCBD motifs provides access to ptC-incorporated new metal–organic frameworks.

Metal-Organic Frameworks

2021 ◽  
Author(s):  
Lars Öhrström ◽  
Francoise M. Amombo Noa
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic

Substrate templated synthesis of single-phase and uniform Zr-porphyrin-based metal–organic frameworks

2020 ◽  
Vol 7 (1) ◽  
pp. 221-231
Author(s):  
Seong Won Hong ◽  
Ju Won Paik ◽  
Dongju Seo ◽  
Jae-Min Oh ◽  
Young Kyu Jeong ◽  
...  
Keyword(s):  
Chemical Bath Deposition ◽  
Single Phase ◽  
Metal Organic Frameworks ◽  
Templated Synthesis ◽  
Pore Structures ◽  
Phase Pure ◽  
Metal Organic ◽  
Cbd Method

We successfully demonstrate that the chemical bath deposition (CBD) method is a versatile method for synthesizing phase-pure and uniform MOFs by controlling their nucleation stages and pore structures.

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