Conformational topography of tris(2-methylbutyl) phosphate and the influence of methyl branching at the non-hyperconjugative carbon on the conformational landscape: insights from matrix isolation infrared spectroscopy and DFT computations

2020 ◽  
Vol 22 (42) ◽  
pp. 24372-24392
Author(s):  
Subramee Sarkar ◽  
Swaroop Chandra ◽  
B. Suryaprasad ◽  
N. Ramanathan ◽  
K. Sundararajan ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Matrix Isolation ◽  
Straight Chain ◽  
Dft Computations ◽  
Conformational Landscape

Branching dramatically reduces the number of conformers of T2MBP relative to its straight chain analogue, while hyperconjugative effects stabilize 'gauche' over 'trans' form, energetically.

Influence of Branching on the Conformational Space: Case Study of Tri-sec-butyl Phosphate Using Matrix Isolation Infrared Spectroscopy and DFT Computations

2018 ◽  
Vol 122 (41) ◽  
pp. 8229-8242 ◽  
Author(s):  
N. Ramanathan ◽  
Shubhra Sarkar ◽  
K. Sundararajan ◽  
Aditi Chandrasekar ◽  
K. Sankaran ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Matrix Isolation ◽  
Conformational Space ◽  
Dft Computations ◽  
Space Case

CHARACTERIZATION OF A HYDROGEN PEROXIDE-BENZENE COMPLEX USING MATRIX ISOLATION INFRARED SPECTROSCOPY

2019 ◽  
Author(s):  
Jay Amicangelo ◽  
Lia Totleben ◽  
Jacob Oslosky ◽  
Yudhishtara Payagala ◽  
Catherine Kaiser ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Infrared Spectroscopy ◽  
Matrix Isolation
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