Influence of Branching on the Conformational Space: Case Study of Tri-sec-butyl Phosphate Using Matrix Isolation Infrared Spectroscopy and DFT Computations

2018 ◽  
Vol 122 (41) ◽  
pp. 8229-8242 ◽  
Author(s):  
N. Ramanathan ◽  
Shubhra Sarkar ◽  
K. Sundararajan ◽  
Aditi Chandrasekar ◽  
K. Sankaran ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Matrix Isolation ◽  
Conformational Space ◽  
Dft Computations ◽  
Space Case

Conformational topography of tris(2-methylbutyl) phosphate and the influence of methyl branching at the non-hyperconjugative carbon on the conformational landscape: insights from matrix isolation infrared spectroscopy and DFT computations

2020 ◽  
Vol 22 (42) ◽  
pp. 24372-24392
Author(s):  
Subramee Sarkar ◽  
Swaroop Chandra ◽  
B. Suryaprasad ◽  
N. Ramanathan ◽  
K. Sundararajan ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Matrix Isolation ◽  
Straight Chain ◽  
Dft Computations ◽  
Conformational Landscape

Branching dramatically reduces the number of conformers of T2MBP relative to its straight chain analogue, while hyperconjugative effects stabilize 'gauche' over 'trans' form, energetically.

CHARACTERIZATION OF A HYDROGEN PEROXIDE-BENZENE COMPLEX USING MATRIX ISOLATION INFRARED SPECTROSCOPY

2019 ◽  
Author(s):  
Jay Amicangelo ◽  
Lia Totleben ◽  
Jacob Oslosky ◽  
Yudhishtara Payagala ◽  
Catherine Kaiser ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Infrared Spectroscopy ◽  
Matrix Isolation
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