Conformational Landscape of Tri-n-butyl Phosphate: Matrix Isolation Infrared Spectroscopy and Systematic Computational Analysis

2017 ◽  
Vol 121 (32) ◽  
pp. 6108-6121 ◽  
Author(s):  
N. Ramanathan ◽  
K. Sundararajan ◽  
K. S. Viswanathan
Keyword(s):  
Infrared Spectroscopy ◽  
Computational Analysis ◽  
Matrix Isolation ◽  
Conformational Landscape

Conformational topography of tris(2-methylbutyl) phosphate and the influence of methyl branching at the non-hyperconjugative carbon on the conformational landscape: insights from matrix isolation infrared spectroscopy and DFT computations

2020 ◽  
Vol 22 (42) ◽  
pp. 24372-24392
Author(s):  
Subramee Sarkar ◽  
Swaroop Chandra ◽  
B. Suryaprasad ◽  
N. Ramanathan ◽  
K. Sundararajan ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Matrix Isolation ◽  
Straight Chain ◽  
Dft Computations ◽  
Conformational Landscape

Branching dramatically reduces the number of conformers of T2MBP relative to its straight chain analogue, while hyperconjugative effects stabilize 'gauche' over 'trans' form, energetically.

CHARACTERIZATION OF A HYDROGEN PEROXIDE-BENZENE COMPLEX USING MATRIX ISOLATION INFRARED SPECTROSCOPY

2019 ◽  
Author(s):  
Jay Amicangelo ◽  
Lia Totleben ◽  
Jacob Oslosky ◽  
Yudhishtara Payagala ◽  
Catherine Kaiser ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Infrared Spectroscopy ◽  
Matrix Isolation

scholarly journals Probing the conformational landscape and thermochemistry of DNA dinucleotide anions via helium nanodroplet infrared action spectroscopy

2020 ◽  
Vol 22 (33) ◽  
pp. 18400-18413
Author(s):  
Daniel A. Thomas ◽  
Rayoon Chang ◽  
Eike Mucha ◽  
Maike Lettow ◽  
Kim Greis ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Helium Nanodroplets ◽  
Action Spectroscopy ◽  
Conformational Landscape ◽  
Kinetic Trapping

Kinetic trapping in helium nanodroplets enables measurement of conformer thermochemistry via infrared spectroscopy at 0.4 K.

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