Sodium and Potassium 3,5-Dinitro-4-hydropyrazolate: Three-Dimensional Metal–Organic Frameworks as Promising Super-heat-resistant Explosives

2019 ◽  
Vol 2 (10) ◽  
pp. 7628-7634 ◽  
Author(s):  
Jichuan Zhang ◽  
Jiaheng Zhang ◽  
Gregory H. Imler ◽  
Damon A. Parrish ◽  
Jean’ne M. Shreeve
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Heat Resistant ◽  
Metal Organic ◽  
Sodium And Potassium

scholarly journals Four Novel d10 Metal-Organic Frameworks Incorporating Amino-Functionalized Carboxylate Ligands: Synthesis, Structures, and Fluorescence Properties

2021 ◽  
Vol 9 ◽  
Author(s):  
Wang Xie ◽  
Jie Wu ◽  
Xiaochun Hang ◽  
Honghai Zhang ◽  
Kang shen ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Fluorescence Properties ◽  
Gravimetric Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Quenching Effect ◽  
D10 Metal ◽  
Metal Organic ◽  
Point Symbol

By employment of amino-functionalized dicarboxylate ligands to react with d10 metal ions, four novel metal-organic frameworks (MOFs) were obtained with the formula of {[Cd(BCPAB)(μ2-H2O)]}n (1), {[Cd(BDAB)]∙2H2O∙DMF}n (2), {[Zn(BDAB)(BPD)0.5(H2O)]∙2H2O}n (3) and {[Zn(BDAB)(DBPB)0.5(H2O)]∙2H2O}n (4) (H2BCPAB = 2,5-bis(p-carbonylphenyl)-1-aminobenzene; H2BDAB = 1,2-diamino-3,6-bis(4-carboxyphenyl)benzene); BPD = (4,4′-bipyridine); DBPB = (E,E-2,5-dimethoxy-1,4-bis-[2-pyridin-vinyl]-benzene; DMF = N,N-dimethylformamide). Complex 1 is a three-dimensional (3D) framework bearing seh-3,5-Pbca nets with point symbol of {4.62}{4.67.82}. Complex 2 exhibits a 4,4-connected new topology that has never been reported before with point symbol of {42.84}. Complex 3 and 4 are quite similar in structure and both have 3D supramolecular frameworks formed by 6-fold and 8-fold interpenetrated 2D coordination layers. The structures of these complexes were characterized by single crystal X-ray diffraction (SC-XRD), thermal gravimetric analysis (TGA) and powder X-ray diffraction (PXRD) measurements. In addition, the fluorescence properties and the sensing capability of 2–4 were investigated as well and the results indicated that complex 2 could function as sensor for Cu2+ and complex 3 could detect Cu2+ and Ag+via quenching effect.

Construction of Three-Dimensional Cobalt(II)-Based Metal–Organic Frameworks by Synergy between Rigid and Semirigid Ligands

2012 ◽  
Vol 12 (11) ◽  
pp. 5529-5534 ◽  
Author(s):  
Weiting Yang ◽  
Min Guo ◽  
Fei-Yan Yi ◽  
Zhong-Ming Sun
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Metal Organic

New nitrogen-rich heterocyclic compounds to build 3D energetic metal complexes

CrystEngComm ◽  
2020 ◽  
Vol 22 (27) ◽  
pp. 4573-4579
Author(s):  
Xiaoming Yang ◽  
Yanna Wang ◽  
Weijing Zhang ◽  
Yanli Yin ◽  
Zhimin Li ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Energetic Materials ◽  
Heterocyclic Compounds ◽  
Three Dimensional ◽  
Potassium Salts ◽  
Heat Resistant ◽  
Sodium And Potassium

By introducing hydroxymethyl into nitrogen-rich heterocyclic compounds, we designed and synthesized a new ligand. The three dimensional (3D) energetic metal complexes sodium and potassium salts of new ligand were investigated for heat-resistant energetic materials.

Accurate tuning of rare earth metal–organic frameworks with unprecedented topology for white-light emission

2020 ◽  
Vol 8 (4) ◽  
pp. 1374-1379 ◽  
Author(s):  
Yutong Wang ◽  
Kai Zhang ◽  
Xiaokang Wang ◽  
Xuelian Xin ◽  
Xiurong Zhang ◽  
...  
Keyword(s):  
White Light ◽  
Light Emission ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Earth Metal ◽  
White Light Emission ◽  
One Dimensional ◽  
1D Chain ◽  
Secondary Building Units ◽  
Metal Organic

An unprecedented three-dimensional (3D) (3,4,5)-czkf topological framework (UPC-38) with one-dimensional (1D) chain secondary building units exhibits strong white light emission.

Construction of Three-Dimensional Metal−Organic Frameworks with Helical Character through Coordinative and Supramolecular Interactions

2009 ◽  
Vol 9 (3) ◽  
pp. 1605-1613 ◽  
Author(s):  
Jian-Qiao Chen ◽  
Yue-Peng Cai ◽  
Hua-Cai Fang ◽  
Zheng-Yuan Zhou ◽  
Xu-Lin Zhan ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Supramolecular Interactions ◽  
Metal Organic
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