Heats of Solution of Some Sodium and Potassium Salts in Water and in Water-Methanol Mixtures

1992 ◽  
Vol 57 (11) ◽  
pp. 2227-2234 ◽  
Author(s):  
Ján Benko ◽  
Oľga Vollárová
Keyword(s):  
Transfer Functions ◽  
Enthalpies Of Solution ◽  
Potassium Salts ◽  
Solvent Interactions ◽  
Heats Of Solution ◽  
Solvent Molecules ◽  
Sodium And Potassium

The enthalpies of solution ∆Hs0 were determined for NaSCN, KSCN, NaBrO3, KBrO3, NaClO3, KClO3, NaIO4, KMnO4, KNO2 and NaNO2 in water-methanol mixtures. The transfer functions ∆Ht0 of the salts and anions were calculated based on the extrathermodynamic TPTB assumption. The ∆Ht0 values of the anion obtained from the sodium and potassium salts were compared. The differences observed, particularly at higher concentrations of the cosolvent, are discussed with respect to the interactions between the solvent molecules and the solute-solvent interactions.

Synthesis of Sulfoquinovose and Sulfoquinovosyl Diacylglycerides, and a Fluorogenic Substrate for Sulfoquinovosidases

2019 ◽  
Author(s):  
Yunyang Zhang ◽  
Janice Mui ◽  
Thimali Arumaperuma ◽  
James P. Lingford ◽  
ETHAN GODDARD-BORGER ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Fluorogenic Substrate ◽  
Potassium Salts ◽  
X Ray ◽  
Sulfoquinovosyl Diacylglycerol ◽  
Sodium And Potassium

<p>The sulfolipid sulfoquinovosyl diacylglycerol (SQDG) and its headgroup, the sulfosugar sulfoquinovose (SQ), are estimated to harbour up to half of all organosulfur in the biosphere. SQ is liberated from SQDG and related glycosides by the action of sulfoquinovosidases (SQases). We report a 10-step synthesis of SQDG that we apply to the preparation of saturated and unsaturated lipoforms. We also report an expeditious synthesis of SQ and (<sup>13</sup>C<sub>6</sub>)SQ, and X-ray crystal structures of sodium and potassium salts of SQ. Finally, we report the synthesis of a fluorogenic SQase substrate, methylumbelliferyl a-D-sulfoquinovoside, and examination of its cleavage kinetics by two recombinant SQases.</p>

Transfer Thermodynamic Functions ∆Gt0, ∆Ht0 and T∆St0 of cis- and trans-[CoCl2(en)2]+ Isomers in Aqueous Mixtures of Methanol, tert-Butyl Alcohol and Acetonitrile

2000 ◽  
Vol 65 (9) ◽  
pp. 1455-1463
Author(s):  
Oľga Vollárová ◽  
Ján Benko
Keyword(s):  
Enthalpy Of Solution ◽  
Transfer Functions ◽  
Partial Molar Volumes ◽  
Butyl Alcohol ◽  
Aqueous Mixtures ◽  
Aqueous Methanol ◽  
Solvent Interactions ◽  
Tert Butyl Alcohol ◽  
Surface Charge Distribution ◽  
Cis And Trans

The solubility, partial molar volume and standard integral molar enthalpy of solution of cis- and trans-[CoCl2(en)2]Cl in water, aqueous methanol, aqueous tert-butyl alcohol and aqueous acetonitrile are reported. The transfer functions ∆Gt0, ∆Ht0 and T∆St0 as well as partial molar volumes are used to obtain information on the solute-solvent interactions. Results obtained are discussed in terms of differences in the surface charge distribution in isomeric coordination species.

Self-assembly of sodium and potassium betulinates into hydro- and organo-gels: entrapment and removal studies of fluorophores and synthesis of gel–gold nanoparticle hybrid materials

RSC Advances ◽  
2016 ◽  
Vol 6 (21) ◽  
pp. 17290-17296 ◽  
Author(s):  
Braja Gopal Bag ◽  
Shib Shankar Dash
Keyword(s):  
Gold Nanoparticle ◽  
Hybrid Materials ◽  
Betulinic Acid ◽  
Self Assembly ◽  
Solvent Mixtures ◽  
Potassium Salts ◽  
Aqueous Solvent Mixtures ◽  
Aqueous Solvent ◽  
Removal Studies ◽  
Sodium And Potassium

Sodium and potassium salts of a renewable nano-sized triterpenoid betulinic acid have been prepared and their self-assembly properties in water and aqueous solvent mixtures have been studied.

New nitrogen-rich heterocyclic compounds to build 3D energetic metal complexes

CrystEngComm ◽  
2020 ◽  
Vol 22 (27) ◽  
pp. 4573-4579
Author(s):  
Xiaoming Yang ◽  
Yanna Wang ◽  
Weijing Zhang ◽  
Yanli Yin ◽  
Zhimin Li ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Energetic Materials ◽  
Heterocyclic Compounds ◽  
Three Dimensional ◽  
Potassium Salts ◽  
Heat Resistant ◽  
Sodium And Potassium

By introducing hydroxymethyl into nitrogen-rich heterocyclic compounds, we designed and synthesized a new ligand. The three dimensional (3D) energetic metal complexes sodium and potassium salts of new ligand were investigated for heat-resistant energetic materials.

How many solvent molecules are required to solvate chiral 1,2-diols with hydrogen bonding solvents? A VCD spectroscopic study

2020 ◽  
Vol 22 (3) ◽  
pp. 1525-1533 ◽  
Author(s):  
Luisa Weirich ◽  
Juliana Magalhães de Oliveira ◽  
Christian Merten
Keyword(s):  
Hydrogen Bonding ◽  
Spectroscopic Study ◽  
Spectroscopic Analysis ◽  
Model Systems ◽  
Solvent Interactions ◽  
Solvent Molecules

A VCD spectroscopic analysis of selected model systems for solute–solvent interactions of chiral diols with hydrogen bonding solvents DMSO and ACN.

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