Pillar–template strategy switching the redox activity and magnetic properties of trisphenylamine-based coordination polymers

CrystEngComm ◽  
2020 ◽  
Vol 22 (18) ◽  
pp. 3155-3163
Author(s):  
Ya-Ru Qiu ◽  
Bang Li ◽  
Yan Zhou ◽  
Jian Su ◽  
Jing-Yuan Ge
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Transformation Method ◽  
Redox Activity ◽  
Crystal Transformation

A pillar–template strategy was used to modify the redox activity and magnetic properties of trisphenylamine-based coordination polymers via a single-crystal-to-single-crystal transformation method.

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

Solvent-induced single-crystal-to-single-crystal transformation and tunable magnetic properties of 1D azido-Cu(ii) chains with a carboxylate bridge

2019 ◽  
Vol 48 (30) ◽  
pp. 11268-11277 ◽  
Author(s):  
Xiangyu Liu ◽  
Xiufang Ma ◽  
Jinhui Yang ◽  
Shuchang Luo ◽  
Zheng Wang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Solvent Effect ◽  
Structural Transformation ◽  
Coordination Polymers ◽  
Crystal Transformation ◽  
Carboxylate Bridge ◽  
Copper Coordination

The solvent effect leads to structural transformation and tunable magnetism of chain-like azido-copper coordination polymers.

Expanding uranyl dicyanoaurate coordination polymers into the second and third dimensions

2020 ◽  
Vol 98 (7) ◽  
pp. 365-372
Author(s):  
Matthew L. Brown ◽  
Daniel B. Leznoff
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Solvothermal Synthesis ◽  
Linear Chain ◽  
Three Dimensional ◽  
Synthesis And Characterization ◽  
Crystal Transformation ◽  
System A

The solvothermal synthesis and characterization of a three-dimensional, interpenetrated uranyl dicyanoaurate coordination polymer, K2(UO2)2(UO2)2(Au(CN)2)2(O)2(NO3)4, from UO2(NO3)2·6H2O and KAu(CN)2 is described. The structure contains a three-dimensional (3D) lattice of planar tetranuclear uranyl–oxo–nitrate clusters connected by dicyanoaurate linkers, with the rotation of the clusters providing the increased dimensionality. The material undergoes a reversible single-crystal to single-crystal transformation on exposure to water vapour, which is taken up in the channels of the 3D system. A second uranyl dicyanoaurate coordination polymer of the form [UO2(DMSO)3(H2O)(Au(CN)2)][Au(CN)2] was structurally characterized as a linear chain of dicyanoaurate units connected by gold–gold bonds with pendant uranyl–water–DMSO adducts that are hydrogen bonded into a two-dimensional sheet. Both materials exhibit emission arising from both the uranyl moiety and the gold(I) centre and represent the first multidimensional uranyl–dicyanoaurate coordination polymers.

Two scandium-based coordination polymers: rapid ultrasound-assisted synthesis, crystal transformation, and catalytic properties

CrystEngComm ◽  
2021 ◽  
Author(s):  
Rui Liu ◽  
Yansong Jiang ◽  
Yiran Gong ◽  
Yu Fu ◽  
Jieyu Shen ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Catalytic Properties ◽  
Ultrasound Waves ◽  
Catalytic Activities ◽  
Crystal Transformation ◽  
Ultrasound Assisted

Assisted by ultrasound waves, a Sc-based coordination polymer CP 1 was synthesized successfully. With 1 as the precursor, another stable CP 2 can be obtained by single-crystal to single-crystal transformation and 2 exhibited good catalytic activities.

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