Solvent-induced single-crystal-to-single-crystal transformation and tunable magnetic properties of 1D azido-Cu(ii) chains with a carboxylate bridge

2019 ◽  
Vol 48 (30) ◽  
pp. 11268-11277 ◽  
Author(s):  
Xiangyu Liu ◽  
Xiufang Ma ◽  
Jinhui Yang ◽  
Shuchang Luo ◽  
Zheng Wang ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Solvent Effect ◽  
Structural Transformation ◽  
Coordination Polymers ◽  
Crystal Transformation ◽  
Carboxylate Bridge ◽  
Copper Coordination

The solvent effect leads to structural transformation and tunable magnetism of chain-like azido-copper coordination polymers.

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

Pillar–template strategy switching the redox activity and magnetic properties of trisphenylamine-based coordination polymers

CrystEngComm ◽  
2020 ◽  
Vol 22 (18) ◽  
pp. 3155-3163
Author(s):  
Ya-Ru Qiu ◽  
Bang Li ◽  
Yan Zhou ◽  
Jian Su ◽  
Jing-Yuan Ge
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Transformation Method ◽  
Redox Activity ◽  
Crystal Transformation

A pillar–template strategy was used to modify the redox activity and magnetic properties of trisphenylamine-based coordination polymers via a single-crystal-to-single-crystal transformation method.

Temperature-induced structural transformations accompanied by changes in magnetic properties of two copper coordination polymers

CrystEngComm ◽  
2020 ◽  
Vol 22 (20) ◽  
pp. 3482-3488 ◽  
Author(s):  
Jing Tu ◽  
Hongjuan Chen ◽  
Hongju Tian ◽  
Xianyong Yu ◽  
Baishu Zheng ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Structural Transformations ◽  
Organic Ligands ◽  
Coordination Modes ◽  
Copper Compounds ◽  
Copper Coordination

Two ferromagnetic copper compounds have been synthesized under different temperature, which represented the rare example of structural transformations resulting from the coordination modes of organic ligands supported by magnetic results.

scholarly journals Modification of Structure and Magnetic Properties in Coordination Assemblies Based on [Cu(cyclam)]2+ and [W(CN)8]3−

Crystals ◽  
2019 ◽  
Vol 9 (1) ◽  
pp. 45 ◽  
Author(s):  
Aleksandra Pacanowska ◽  
Mateusz Reczyński ◽  
Beata Nowicka
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Structural Transformation ◽  
Water Solution ◽  
Building Blocks ◽  
Alcohol Solution ◽  
Slow Diffusion ◽  
Crystal Structural ◽  
Water Alcohol

The 1D {[CuII(cyclam)]3[WV(CN)8]2.5H2O}n (1·5H2O) (cyclam = 1,4,8,11-tetraazacyclotetradecane) coordination polymer of ladder topology can be obtained in water-alcohol solution from [Cu(cyclam)]2+ and [W(CN)8]3− building blocks. Upon dehydration, 1·5H2O undergoes a single-crystal-to-single-crystal structural transformation to the anhydrous {[CuII(cyclam)]3[WV(CN)8]2}n (1) form, which retains the same topology, but is characterized by shorter Cu-W distances and significantly more bent CN-bridges. The deformation of the coordination skeleton is reflected in magnetic properties: the predominant intra-chain interactions change from ferromagnetic in 1·5H2O to antiferromagnetic in 1. The reaction between the same building blocks in water solution under slow diffusion conditions leads to the formation of a 0D {[CuII(cyclam)(H2O)]2[CuII(cyclam)][WV(CN)8]2}.3H2O pentanuclear assembly (2·3H2O).

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