The impact of positional isomerism on electronic and photochromic properties of 1D zinc-based naphthalene diimide coordination polymers

CrystEngComm ◽  
2020 ◽  
Vol 22 (19) ◽  
pp. 3371-3377 ◽  
Author(s):  
Pengfei Hao ◽  
Huihui Zhu ◽  
Yue Pang ◽  
Junju Shen ◽  
Yunlong Fu
Keyword(s):  
Coordination Polymers ◽  
Electron Donors ◽  
Photochromic Properties ◽  
Naphthalene Diimide ◽  
Positional Isomerism ◽  
The Impact

The positional isomeric DPNDI ligands can effectively modulate the interfacial contacts of electron donors/acceptors and the efficiency of electronic/photochromic properties.

The Impact of Charge-Distribution on Photochromic Properties in 1D Coordination Polymers

2017 ◽  
Vol 643 (22) ◽  
pp. 1766-1770 ◽  
Author(s):  
Jian-Jun Liu ◽  
Shu-Biao Xia ◽  
Liu Teng ◽  
Chi-Xian He ◽  
Fei-Xiang Cheng ◽  
...  
Keyword(s):  
Charge Distribution ◽  
Coordination Polymers ◽  
Photochromic Properties ◽  
The Impact

The modulation effect of electron-rich solvents on the supramolecular networks and photochromic properties of naphthalene diimide molecules

CrystEngComm ◽  
2021 ◽  
Author(s):  
Huihui Zhu ◽  
Pengfei Hao ◽  
Qiu Shen ◽  
Junju Shen ◽  
Gaopeng Li ◽  
...  
Keyword(s):  
Electron Donors ◽  
Modulation Effect ◽  
Photochromic Properties ◽  
Naphthalene Diimide ◽  
Supramolecular Networks

The electron-rich solvents can effectively regulate the interfacial contacts of electron donors/acceptors and the photochromic properties of naphthalene diimide molecules.

The impact of lone pair–π interactions on photochromic properties in 1-D naphthalene diimide coordination networks

2015 ◽  
Vol 44 (39) ◽  
pp. 17312-17317 ◽  
Author(s):  
Jian-Jun Liu ◽  
Ying-Fang Guan ◽  
Yong Chen ◽  
Mei-Jin Lin ◽  
Chang-Cang Huang ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Lone Pair ◽  
Coordination Networks ◽  
Photochromic Properties ◽  
Π Interactions ◽  
Halogen Atoms ◽  
Naphthalene Diimide ◽  
The Impact

Due to the different lone pair–π interactions between the capped halogen atoms and electron-deficient naphthalene diimide moieties in three isostructural coordination networks, they exhibit different electron-transfer photochromic behaviours upon irradiation.

Positional Isomerism Controlled Electronic and Photochromic Properties of Naphthalene Diimide-Based Chlorozincate Hybrids

2019 ◽  
Vol 20 (1) ◽  
pp. 345-351 ◽  
Author(s):  
Pengfei Hao ◽  
Huihui Zhu ◽  
Yue Pang ◽  
Junju Shen ◽  
Yunlong Fu
Keyword(s):  
Photochromic Properties ◽  
Naphthalene Diimide ◽  
Positional Isomerism

The Influence of Disintegration of Hard Coal Varieties of Different Metamorphism Grade on the Amount of Sorbed Ethane / Wpływ rozdrobnienia odmian węgla kamiennego o różnym stopniu metamorfizmu na ilości sorbowanego etanu

2013 ◽  
Vol 58 (2) ◽  
pp. 449-463 ◽  
Author(s):  
Mieczysław Żyła ◽  
Agnieszka Dudzińska ◽  
Janusz Cygankiewicz
Keyword(s):  
Sorption Isotherms ◽  
Electron Donors ◽  
Hard Coal ◽  
Coal Surface ◽  
Compact Layer ◽  
Compact Structure ◽  
Small Surface ◽  
Mining Works ◽  
The Impact ◽  
Content Of Oxygen

Ethane constitutes an explosive gas. It most often accompanies methane realizing during exploitation and mining works. In this paper the results of ethane sorption have been discussed on three grain classes of six selected hard coal samples collected from active Polish coalmines. On the basis of obtained results, it has been stated that the tested hard coals prove differentiated sorption power with reference to ethane. Te extreme amount of ethane is sorbed by low carbonized hard coal from “Jaworzno” coalmine. This sort of coal shows great porosity, and great content of oxygen and moisture. The least amount of ethane is sorbed by hard coal from “Sośnica” coalmine. This sort of coal possesses relatively a great deal of ash contents. Together with the process of coal disintegration, the amount of sorbed ethane increases for all tested coal samples. Between tested coals there are three medium carbonized samples collected from “Pniówek”, “Chwałowice” “Zofiówka” coalmines which are characterized by small surface values counted according to model BET from nitrogen sorption isotherms determined at the temperature of 77.5 K. The samples of these three coals prove the highest, from between tested coals, increase of ethane sorption occurring together with their disintegration. These samples disintegrated to 0,063-0,075 mm grain class sorb ethane in the amount corresponding with the sorption quantity of low carbonized coal from “Jaworzno” coalmine in 0.5-0.7 mm grain class. It should be marked that the low carbonized samples collected from “Jaworzno” and Wesoła” coalmines possess large specific surface and great porosity and belong to coal group of “loose” spatial structure. Regarding profusion of sorbed ethane on disintegrated medium carbonized samples from “Pniówek”, “Zofiówka”, “Chwałowice” coalmines it can be supposed that in the process of coal disintegration, breaking their “compact’ structure occurs. Loosened structure of medium carbonized coals results in increasing accessibility of ethane particles to sorption centres both electron donors and electron acceptors which are present on hard coal surface. The surface sorption centre increase may result in formation a compact layer of ethane particles on coal surface. In the formed layer, not only the strengths of vertical binding of ethane particles with the coal surface appear but also the impact of horizontal strengths appears which forms a compact layer of sorbed ethane particles. The surface layer of ethane particles may lead to explosion.

Design and Characterization of Novel Dirhodium Coordination Polymers - The Impact of Ligand Size on Selectivity in Asymmetric Cyclopropanation

2021 ◽  
Author(s):  
Zhenzhong Li ◽  
Lorenz Roesler ◽  
Till Wissel ◽  
Hergen Breitzke ◽  
Kathrin Hofmann ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Ligand Exchange ◽  
Dicarboxylic Acids ◽  
Sem Images ◽  
Asymmetric Cyclopropanation ◽  
The Impact

Three chiral dirhodium coordination polymers Rh2-Ln (n=1-3) have been synthesized via ligand exchange between dirhodium trifluoroacetate Rh2(TFA)4 and differently sized chiral dicarboxylic acids derived from L-tert-leucine. SEM images indicate that...

Involvement of various anions in tuning the structure of silver(I) coordination polymers based on the S- donor ligands: Syntheses, crystal structure and uptake properties

CrystEngComm ◽  
2021 ◽  
Author(s):  
susan soleymani babadi ◽  
Azizollah Beheshti ◽  
Maryam bahrani ◽  
Behrang Salahshour nia ◽  
Hamid Reza Zafarian ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Donor Ligands ◽  
Counter Ions ◽  
Coordination Ability ◽  
The Impact

An investigation of the impact of shape, size and coordination ability of the counter ions was carried out on a five silver(I)- 1, 2- bis (1-methylthioimidazolyl) ethane coordination polymers namely,...

The impact of electron donors and anode potentials on the anode-respiring bacteria community

2017 ◽  
Vol 101 (21) ◽  
pp. 7997-8005 ◽  
Author(s):  
Xianbin Ying ◽  
Kun Guo ◽  
Wei Chen ◽  
Yuan Gu ◽  
Dongsheng Shen ◽  
...  
Keyword(s):  
Electron Donors ◽  
The Impact ◽  
Anode Respiring Bacteria

Improved Photochromic Properties on Viologen-Based Inorganic–Organic Hybrids by Using π-Conjugated Substituents as Electron Donors and Stabilizers

2013 ◽  
Vol 52 (3) ◽  
pp. 1199-1205 ◽  
Author(s):  
Rong-Guang Lin ◽  
Gang Xu ◽  
Ming-Sheng Wang ◽  
Gang Lu ◽  
Pei-Xin Li ◽  
...  
Keyword(s):  
Electron Donors ◽  
Photochromic Properties
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