Photo-Responsivity Improvement of Photo-Mobile Polymers Actuators Based on a Novel LCs/Azobenzene Copolymer and ZnO Nanoparticles Network

The efficiency of photomobile polymers (PMP) in the conversion of light into mechanical work plays a fundamental role in achieving cutting-edge innovation in the development of novel applications ranging from energy harvesting to sensor approaches. Because of their photochromic properties, azobenzene monomers have been shown to be an efficient material for the preparation of PMPs with appropriate photoresponsivity. Upon integration of the azobenzene molecules as moieties into a polymer, they act as an engine, allowing fast movements of up to 50 Hz. In this work we show a promising approach for integrating ZnO nanoparticles into a liquid crystalline polymer network. The addition of such nanoparticles allows the trapping of incoming light, which acts as diffusive points in the polymer matrix. We characterized the achieved nanocomposite material in terms of thermomechanical and optical properties and finally demonstrated that the doped PMP was better performing that the undoped PMP film.

Photochromic Microcapsules for Textile Materials by Spray Drying—Part 1: Production and Characterization of Photochromic Microcapsules

This study, which is the first in a three-part series, deals with the encapsulation of photochromic dyes by spray drying. An aqueous ethyl cellulose dispersion and a spirooxazine-based photochromic dye were used as a shell and core material, respectively. The effects of main encapsulation parameters, such as solvent type, inlet temperature, feed rate, solid content, and aspirator rate were investigated. The encapsulation results were evaluated by scanning electron microscopy (SEM) images, particle size measurements, thermogravimetric analysis (TGA) and X-ray diffraction (XRD). The microcapsules obtained from a water-ethanol mixture exhibited photochromic properties. For microcapsule production, the optimum feed rate, total solid content, and aspirator rate were determined. Capsule formation improved with increased inlet air temperature. Spray drying to produce photochromic microcapsules could be a practical method for production of photochromic smart textiles.