Improved Photochromic Properties on Viologen-Based Inorganic–Organic Hybrids by Using π-Conjugated Substituents as Electron Donors and Stabilizers

2013 ◽  
Vol 52 (3) ◽  
pp. 1199-1205 ◽  
Author(s):  
Rong-Guang Lin ◽  
Gang Xu ◽  
Ming-Sheng Wang ◽  
Gang Lu ◽  
Pei-Xin Li ◽  
...  
Keyword(s):  
Electron Donors ◽  
Photochromic Properties

The modulation effect of electron-rich solvents on the supramolecular networks and photochromic properties of naphthalene diimide molecules

CrystEngComm ◽  
2021 ◽  
Author(s):  
Huihui Zhu ◽  
Pengfei Hao ◽  
Qiu Shen ◽  
Junju Shen ◽  
Gaopeng Li ◽  
...  
Keyword(s):  
Electron Donors ◽  
Modulation Effect ◽  
Photochromic Properties ◽  
Naphthalene Diimide ◽  
Supramolecular Networks

The electron-rich solvents can effectively regulate the interfacial contacts of electron donors/acceptors and the photochromic properties of naphthalene diimide molecules.

The impact of positional isomerism on electronic and photochromic properties of 1D zinc-based naphthalene diimide coordination polymers

CrystEngComm ◽  
2020 ◽  
Vol 22 (19) ◽  
pp. 3371-3377 ◽  
Author(s):  
Pengfei Hao ◽  
Huihui Zhu ◽  
Yue Pang ◽  
Junju Shen ◽  
Yunlong Fu
Keyword(s):  
Coordination Polymers ◽  
Electron Donors ◽  
Photochromic Properties ◽  
Naphthalene Diimide ◽  
Positional Isomerism ◽  
The Impact

The positional isomeric DPNDI ligands can effectively modulate the interfacial contacts of electron donors/acceptors and the efficiency of electronic/photochromic properties.

Electronic structure studies of conducting polymers by electron energy-loss spectroscopy

1996 ◽  
Vol 54 ◽  
pp. 160-161
Author(s):  
J. Fink
Keyword(s):  
Electronic Structure ◽  
Conducting Polymers ◽  
Conjugated Polymers ◽  
Electron Acceptors ◽  
Electron Donors ◽  
Light Emitting ◽  
One Dimensional ◽  
New Class ◽  
Electrical Conductivities ◽  
Electron Energy Loss

Conducting polymers comprises a new class of materials achieving electrical conductivities which rival those of the best metals. The parent compounds (conjugated polymers) are quasi-one-dimensional semiconductors. These polymers can be doped by electron acceptors or electron donors. The prototype of these materials is polyacetylene (PA). There are various other conjugated polymers such as polyparaphenylene, polyphenylenevinylene, polypoyrrole or polythiophene. The doped systems, i.e. the conducting polymers, have intersting potential technological applications such as replacement of conventional metals in electronic shielding and antistatic equipment, rechargable batteries, and flexible light emitting diodes.Although these systems have been investigated almost 20 years, the electronic structure of the doped metallic systems is not clear and even the reason for the gap in undoped semiconducting systems is under discussion.

The interaction of electron donors and acceptors

1964 ◽  
Vol 61 ◽  
pp. 20-38 ◽  
Author(s):  
Robert S. Mulliken
Keyword(s):  
Electron Donors

The Influence of Disintegration of Hard Coal Varieties of Different Metamorphism Grade on the Amount of Sorbed Ethane / Wpływ rozdrobnienia odmian węgla kamiennego o różnym stopniu metamorfizmu na ilości sorbowanego etanu

2013 ◽  
Vol 58 (2) ◽  
pp. 449-463 ◽  
Author(s):  
Mieczysław Żyła ◽  
Agnieszka Dudzińska ◽  
Janusz Cygankiewicz
Keyword(s):  
Sorption Isotherms ◽  
Electron Donors ◽  
Hard Coal ◽  
Coal Surface ◽  
Compact Layer ◽  
Compact Structure ◽  
Small Surface ◽  
Mining Works ◽  
The Impact ◽  
Content Of Oxygen

Ethane constitutes an explosive gas. It most often accompanies methane realizing during exploitation and mining works. In this paper the results of ethane sorption have been discussed on three grain classes of six selected hard coal samples collected from active Polish coalmines. On the basis of obtained results, it has been stated that the tested hard coals prove differentiated sorption power with reference to ethane. Te extreme amount of ethane is sorbed by low carbonized hard coal from “Jaworzno” coalmine. This sort of coal shows great porosity, and great content of oxygen and moisture. The least amount of ethane is sorbed by hard coal from “Sośnica” coalmine. This sort of coal possesses relatively a great deal of ash contents. Together with the process of coal disintegration, the amount of sorbed ethane increases for all tested coal samples. Between tested coals there are three medium carbonized samples collected from “Pniówek”, “Chwałowice” “Zofiówka” coalmines which are characterized by small surface values counted according to model BET from nitrogen sorption isotherms determined at the temperature of 77.5 K. The samples of these three coals prove the highest, from between tested coals, increase of ethane sorption occurring together with their disintegration. These samples disintegrated to 0,063-0,075 mm grain class sorb ethane in the amount corresponding with the sorption quantity of low carbonized coal from “Jaworzno” coalmine in 0.5-0.7 mm grain class. It should be marked that the low carbonized samples collected from “Jaworzno” and Wesoła” coalmines possess large specific surface and great porosity and belong to coal group of “loose” spatial structure. Regarding profusion of sorbed ethane on disintegrated medium carbonized samples from “Pniówek”, “Zofiówka”, “Chwałowice” coalmines it can be supposed that in the process of coal disintegration, breaking their “compact’ structure occurs. Loosened structure of medium carbonized coals results in increasing accessibility of ethane particles to sorption centres both electron donors and electron acceptors which are present on hard coal surface. The surface sorption centre increase may result in formation a compact layer of ethane particles on coal surface. In the formed layer, not only the strengths of vertical binding of ethane particles with the coal surface appear but also the impact of horizontal strengths appears which forms a compact layer of sorbed ethane particles. The surface layer of ethane particles may lead to explosion.

Yttrium Oxyhydrides for Photochromic Applications: Correlating Composition and Optical Response

2018 ◽  
Author(s):  
Dmitrii Moldarev ◽  
Elbruz M. Baba ◽  
Marcos V. Moro ◽  
Chang C. You ◽  
Smagul Zh. Karazhanov ◽  
...  
Keyword(s):  
Medical Devices ◽  
Ternary Diagram ◽  
Optical And Electrical Properties ◽  
Ambient Conditions ◽  
Elastic Recoil ◽  
Elastic Recoil Detection Analysis ◽  
Photochromic Properties ◽  
Smart Windows ◽  
Elastic Recoil Detection ◽  
Detection Analysis

It has been recently demonstrated that yttrium oxyhydride(YHO) films can exhibit reversible photochromic properties when exposed to illumination at ambient conditions. This switchable optical propertyenables their utilization in many technological applications, such as smart windows, sensors, goggles, medical devices, etc. However, how the composition of the films affects their optical properties is not fully clear and therefore demands a straightforward investigation. In this work, the composition of YHO films manufactured by reactive magnetron sputtering under different conditions is deduced in a ternary diagram from Time-of-Flight Elastic Recoil Detection Analysis (ToF-ERDA). The results suggest that stable compounds are formed with a specificchemical formula – YH<sub>2-δ</sub>O<sub>δ</sub>. In addition, optical and electrical properties of the films are investigated, and a correlation with their compositions is established. The corresponding photochromic response is found in a specific oxygen concentration range (0.45 < δ < 1.5) with maximum and minimum of magnitude on the lower and higher border, respectively.

Sulfonamides Are an Overlooked Class of Electron Donors in Luminogenic Luciferins and Fluorescent Dyes

2018 ◽  
Author(s):  
Deepak K. Sharma ◽  
Spencer T. Adams ◽  
Kate L. Liebmann ◽  
Adam Choi ◽  
Stephen Miller
Keyword(s):  
Fluorescent Dyes ◽  
Bright Light ◽  
Firefly Luciferase ◽  
Electron Donors ◽  
Light Emitting

Many fluorophores, and all bright light-emitting substrates for firefly luciferase, contain hydroxyl or amine electron donors. Here we show that sulfonamides can serve as replacements for these canonical groups. Unlike “caged” carboxamides, sulfonamide analogues enable bioluminescence, and sulfonamidyl luciferins, coumarins, rhodols, and rhodamines are fluorescent in water. Sulfonamide donors thus have previously unappreciated potential to expand the functional repertoire of luminescent molecules.

Spectral and kinetic manifestations of chain flexibility and polarity in reversible photoisomerization of spironaphthoxazine-based acrylic copolymers

2021 ◽  
Author(s):  
Vahid Hamrang ◽  
Ali Reza Mahdavian
Keyword(s):  
Photochromic Properties ◽  
Chain Flexibility ◽  
Acrylic Copolymers

Future advances of photoresponsive materials essentially depend on our knowledge about how the substrates, and typically their Tg and polarity, affect photochromic properties. Here, these were followed in two separate...

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