scholarly journals Exploring a lead-free organic–inorganic semiconducting hybrid with above-room-temperature dielectric phase transition

RSC Advances ◽  
2020 ◽  
Vol 10 (30) ◽  
pp. 17492-17496
Author(s):  
Yuyin Wang ◽  
Shiguo Han ◽  
Xitao Liu ◽  
Zhenyue Wu ◽  
Zhihua Sun ◽  
...  

Recently, organic–inorganic hybrid lead halide perovskites have attracted great attention for optoelectronic applications, such as light-emitting diodes, photovoltaics and optoelectronics.

Author(s):  
Hyunsik Im ◽  
Atanu Jana ◽  
Vijaya Gopalan Sree ◽  
QIANKAI BA ◽  
Seong Chan Cho ◽  
...  

Lead-free, non-toxic transition metal-based phosphorescent organic–inorganic hybrid (OIH) compounds are promising for next-generation flat-panel displays and solid-state light-emitting devices. In the present study, we fabricate highly efficient phosphorescent green-light-emitting diodes...


Author(s):  
Yao Li ◽  
Kaimin Du ◽  
Manli Zhang ◽  
Xuan Gao ◽  
Yu Lu ◽  
...  

Metal halide perovskites are a new class of promising materials in optoelectronic applications. As optoelectronic properties of the lead halide perovskites are determined largely by their morphology, the morphology of...


2019 ◽  
Vol 5 (8) ◽  
pp. eaaw8072 ◽  
Author(s):  
Yuequn Shang ◽  
Yuan Liao ◽  
Qi Wei ◽  
Ziyu Wang ◽  
Bo Xiang ◽  
...  

Organic-inorganic hybrid halide perovskites are emerging as promising materials for next-generation light-emitting diodes (LEDs). However, the poor stability of these materials has been the main obstacle challenging their application. Here, we performed first-principles calculations, revealing that the molecule dissociation energy of Dion-Jacobson (DJ) structure using 1,4-bis(aminomethyl)benzene molecules as bridging ligands is two times higher than the typical Ruddlesden-Popper (RP) structure based on phenylethylammonium ligands. Accordingly, LEDs based on the DJ structure show a half-lifetime over 100 hours, which is almost two orders of magnitude longer compared with those based on RP structural quasi–two-dimensional perovskite. To the best of our knowledge, this is the longest lifetime reported for all organic-inorganic hybrid perovskites operating at the current density, giving the highest external quantum efficiency (EQE) value. In situ tracking of the film composition in operation indicates that the DJ structure was maintained well after continuous operation under an electric field.


RSC Advances ◽  
2020 ◽  
Vol 10 (61) ◽  
pp. 37161-37167 ◽  
Author(s):  
K. P. O. Mahesh ◽  
Che-Yu Chang ◽  
Wei-Li Hong ◽  
Tzu-Hsiang Wen ◽  
Pei-Hsuan Lo ◽  
...  

Organometal halide perovskites are attracting a great deal of attention because of their long carrier diffusion lengths, wide wavelength tunability, and narrow-band emission.


2019 ◽  
Vol 6 (1) ◽  
pp. 233-237 ◽  
Author(s):  
Jing Zhang ◽  
Shiguo Han ◽  
Xitao Liu ◽  
Chengmin Ji ◽  
Kewen Tao ◽  
...  

We have reported a lead-free organic–inorganic hybrid compound, (hexamethyleneimine)2BiBr5 (1), which undergoes three successive phase transitions in the vicinity of room temperature.


Author(s):  
Yuting Gao ◽  
Yufeng Pan ◽  
Feng Zhou ◽  
Guangda Niu ◽  
Chunjie Yan

Lead halide perovskites have demonstrated excellent performance for light emitting diodes and detectors. However, the toxicity of lead (Pb) in the devices severely impedes their widespread application and commercialization. The...


Nanoscale ◽  
2021 ◽  
Author(s):  
Mingfei Zheng ◽  
Guojia Fang

Metal halide perovskites, as a newly emerging light-emitter, have been attracting considerable attention on luminescent materials and devices, due to their superior optoelectronic properties and potential practical applications. Recently, perovskite...


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