Lead-free halide perovskites: review of structure-property relationship, and applications in light emitting devices and radiation detectors

2021 ◽  
Author(s):  
Yuting Gao ◽  
Yufeng Pan ◽  
Feng Zhou ◽  
Guangda Niu ◽  
Chunjie Yan
Keyword(s):  
Radiation Detectors ◽  
Lead Free ◽  
Structure Property ◽  
Excellent Performance ◽  
Widespread Application ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Structure Property Relationship ◽  
Halide Perovskites ◽  
Lead Halide

Lead halide perovskites have demonstrated excellent performance for light emitting diodes and detectors. However, the toxicity of lead (Pb) in the devices severely impedes their widespread application and commercialization. The...

scholarly journals Exploring a lead-free organic–inorganic semiconducting hybrid with above-room-temperature dielectric phase transition

RSC Advances ◽  
2020 ◽  
Vol 10 (30) ◽  
pp. 17492-17496
Author(s):  
Yuyin Wang ◽  
Shiguo Han ◽  
Xitao Liu ◽  
Zhenyue Wu ◽  
Zhihua Sun ◽  
...  
Keyword(s):  
Phase Transition ◽  
Room Temperature ◽  
Light Emitting Diodes ◽  
Lead Free ◽  
Inorganic Hybrid ◽  
Light Emitting ◽  
Dielectric Phase ◽  
Halide Perovskites ◽  
Optoelectronic Applications ◽  
Lead Halide

Recently, organic–inorganic hybrid lead halide perovskites have attracted great attention for optoelectronic applications, such as light-emitting diodes, photovoltaics and optoelectronics.

Efficient light-emitting devices based on mixed-cation lead halide perovskites

2020 ◽  
Vol 77 ◽  
pp. 105546 ◽  
Author(s):  
Zewu Xiao ◽  
Qi Wang ◽  
Xiaoyuan Wu ◽  
Yanting Wu ◽  
Jie Ren ◽  
...  
Keyword(s):  
Light Emitting ◽  
Light Emitting Devices ◽  
Mixed Cation ◽  
Halide Perovskites ◽  
Lead Halide

scholarly journals Control of spontaneous emission rate in lead halide perovskite film on hyperbolic metamaterial

2021 ◽  
Vol 2015 (1) ◽  
pp. 012153
Author(s):  
Pavel Tonkaev ◽  
Sergey Makarov
Keyword(s):  
Radiative Recombination ◽  
Emission Rate ◽  
Optoelectronic Devices ◽  
Spontaneous Emission Rate ◽  
Hyperbolic Metamaterials ◽  
Light Emitting ◽  
Hyperbolic Metamaterial ◽  
Light Emitting Devices ◽  
Halide Perovskites ◽  
Lead Halide

Abstract Hyperbolic metamaterials represent a class of nanophotonic architectures with the possibility of controlling density of optical states. Due to this property, hyperbolic metamaterials can be employed as meta-electrodes in optoelectronic devices. On the other hand, lead halide perovskites have several promising properties for application in light-emitting devices. Moreover, a perovskite film is easily deposited on a hyperbolic metamaterial surface. Here, we theoretically show how to accelerate radiative recombination in a perovskite film with a hyperbolic metamaterial. This effect can be applied in light-emitting devices, where radiative recombination is extremely important.

Efficient organic manganese (II) bromide green-light-emitting diodes enabled by manipulating hole and electron transport layer

2021 ◽  
Author(s):  
Hyunsik Im ◽  
Atanu Jana ◽  
Vijaya Gopalan Sree ◽  
QIANKAI BA ◽  
Seong Chan Cho ◽  
...  
Keyword(s):  
Light Emitting Diodes ◽  
Green Light ◽  
Transport Layer ◽  
Lead Free ◽  
Electron Transport Layer ◽  
Flat Panel Displays ◽  
Flat Panel ◽  
Inorganic Hybrid ◽  
Light Emitting ◽  
Light Emitting Devices

Lead-free, non-toxic transition metal-based phosphorescent organic–inorganic hybrid (OIH) compounds are promising for next-generation flat-panel displays and solid-state light-emitting devices. In the present study, we fabricate highly efficient phosphorescent green-light-emitting diodes...

scholarly journals Photostable and Uniform CH3NH3PbI3 Perovskite Film Prepared via Stoichiometric Modification and Solvent Engineering

Nanomaterials ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 405
Author(s):  
Daocheng Hong ◽  
Mingyi Xie ◽  
Yuxi Tian
Keyword(s):  
Solar Cells ◽  
Optoelectronic Devices ◽  
Solvent Engineering ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Coverage Ratio ◽  
Fabrication Procedure ◽  
Fabrication Condition ◽  
Halide Perovskites ◽  
Photoluminescence Efficiency

Solution-processed organometal halide perovskites (OMHPs) have been widely used in optoelectronic devices, and have exhibited brilliant performance. One of their generally recognized advantages is their easy fabrication procedure. However, such a procedure also brings uncertainty about the opto-electric properties of the final samples and devices, including morphology, stability, coverage ratio, and defect concentration. Normally, one needs to find a balanced condition, because there is a competitive relation between these parameters. In this work, we fabricated CH3NH3PbI3 films by carefully changing the ratio of the PbI2 to CH3NH3I, and found that the stoichiometric and solvent engineering not only determined the photoluminescence efficiency and defects in the materials, but also affected the photostability, morphology, and coverage ratio. Combining solvent engineering and the substitution of PbI2 by Pb(Ac)2, we obtained an optimized fabrication condition, providing uniform CH3NH3PbI3 films with both high photoluminescence efficiency and high photostability under either I-rich or Pb-rich conditions. These results provide an optimized fabrication procedure for CH3NH3PbI3 and other OMHP films, which is crucial for the performance of perovskite-based solar cells and light emitting devices.

scholarly journals Lead-Free Halide Double Perovskites: A Review of the Structural, Optical, and Stability Properties as Well as Their Viability to Replace Lead Halide Perovskites

Metals ◽  
2018 ◽  
Vol 8 (9) ◽  
pp. 667 ◽  
Author(s):  
Edson Meyer ◽  
Dorcas Mutukwa ◽  
Nyengerai Zingwe ◽  
Raymond Taziwa
Keyword(s):  
Solar Cells ◽  
Perovskite Solar Cells ◽  
Lead Free ◽  
Double Perovskites ◽  
Stability Properties ◽  
Perovskite Materials ◽  
Halide Perovskites ◽  
Halide Perovskite ◽  
Light Absorbers ◽  
Lead Halide

Perovskite solar cells employ lead halide perovskite materials as light absorbers. These perovskite materials have shown exceptional optoelectronic properties, making perovskite solar cells a fast-growing solar technology. Perovskite solar cells have achieved a record efficiency of over 20%, which has superseded the efficiency of Gräztel dye-sensitized solar cell (DSSC) technology. Even with their exceptional optical and electric properties, lead halide perovskites suffer from poor stability. They degrade when exposed to moisture, heat, and UV radiation, which has hindered their commercialization. Moreover, halide perovskite materials consist of lead, which is toxic. Thus, exposure to these materials leads to detrimental effects on human health. Halide double perovskites with A2B′B″X6 (A = Cs, MA; B′ = Bi, Sb; B″ = Cu, Ag, and X = Cl, Br, I) have been investigated as potential replacements of lead halide perovskites. This work focuses on providing a detailed review of the structural, optical, and stability properties of these proposed perovskites as well as their viability to replace lead halide perovskites. The triumphs and challenges of the proposed lead-free A2B′B″X6 double perovskites are discussed here in detail.

scholarly journals Origin of unusual bandgap shift and dual emission in organic-inorganic lead halide perovskites

2016 ◽  
Vol 2 (10) ◽  
pp. e1601156 ◽  
Author(s):  
M. Ibrahim Dar ◽  
Gwénolé Jacopin ◽  
Simone Meloni ◽  
Alessandro Mattoni ◽  
Neha Arora ◽  
...  
Keyword(s):  
Density Functional ◽  
Valence Band Maximum ◽  
Dual Emission ◽  
Time Resolved ◽  
Light Emitting ◽  
Light Emitting Devices ◽  
Perovskite Materials ◽  
Halide Perovskites ◽  
Dynamics Simulations ◽  
Increasing Temperature

Emission characteristics of metal halide perovskites play a key role in the current widespread investigations into their potential uses in optoelectronics and photonics. However, a fundamental understanding of the molecular origin of the unusual blueshift of the bandgap and dual emission in perovskites is still lacking. In this direction, we investigated the extraordinary photoluminescence behavior of three representatives of this important class of photonic materials, that is, CH3NH3PbI3, CH3NH3PbBr3, and CH(NH2)2PbBr3, which emerged from our thorough studies of the effects of temperature on their bandgap and emission decay dynamics using time-integrated and time-resolved photoluminescence spectroscopy. The low-temperature (<100 K) photoluminescence of CH3NH3PbI3and CH3NH3PbBr3reveals two distinct emission peaks, whereas that of CH(NH2)2PbBr3shows a single emission peak. Furthermore, irrespective of perovskite composition, the bandgap exhibits an unusual blueshift by raising the temperature from 15 to 300 K. Density functional theory and classical molecular dynamics simulations allow for assigning the additional photoluminescence peak to the presence of molecularly disordered orthorhombic domains and also rationalize that the unusual blueshift of the bandgap with increasing temperature is due to the stabilization of the valence band maximum. Our findings provide new insights into the salient emission properties of perovskite materials, which define their performance in solar cells and light-emitting devices.

Tunable ultra-uniform Cs4PbBr6 perovskites with efficient photoluminescence and excellent stability for high-performance white light-emitting diodes

2021 ◽  
Author(s):  
Yao Li ◽  
Kaimin Du ◽  
Manli Zhang ◽  
Xuan Gao ◽  
Yu Lu ◽  
...  
Keyword(s):  
White Light ◽  
High Performance ◽  
Light Emitting Diodes ◽  
Metal Halide ◽  
Light Emitting ◽  
New Class ◽  
Halide Perovskites ◽  
White Light Emitting Diodes ◽  
Lead Halide ◽  
Excellent Stability

Metal halide perovskites are a new class of promising materials in optoelectronic applications. As optoelectronic properties of the lead halide perovskites are determined largely by their morphology, the morphology of...

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