scholarly journals Modifications of the CZTSe/Mo back-contact interface by plasma treatments

RSC Advances ◽  
2019 ◽  
Vol 9 (46) ◽  
pp. 26850-26855 ◽  
Author(s):  
Wenjian Chen ◽  
Teoman Taskesen ◽  
David Nowak ◽  
Ulf Mikolajczak ◽  
Mohamed H. Sayed ◽  
...  

Molybdenum (Mo) is the most commonly used back-contact material for copper zinc tin selenide (CZTSe)-based thin-film solar cells. The effect of a pure Ar plasma and a mixed Ar–N2 plasma on the back-contact interface of CZTSe solar cells is reported in this study.

PLoS ONE ◽  
2021 ◽  
Vol 16 (1) ◽  
pp. e0245390
Author(s):  
Wenjian Chen ◽  
Hippolyte Hirwa ◽  
Jörg Ohland ◽  
Teoman Taskesen ◽  
Ulf Mikolajczak ◽  
...  

The formation of molybdenum diselenide (MoSe2) is widely observed at the back-contact interface for copper zinc tin selenide (CZTSe) thin-film solar cells. Depending on individual selenium (Se) supply and thermal conditions for forming CZTSe absorbers on molybdenum (Mo) substrates, the thickness of MoSe2 can vary from a few hundreds of nanometers up to ≈ 1 μm, which is comparable to the commonly adopted thickness of 1 ~ 1.5 μm for CZTSe absorbers. In this study, for controlling the thickness of interfacial MoSe2, thin diffusion barrier layers of silicon oxynitride (SiOxNy) are deposited onto Mo layers prior to the growth of CZTSe absorbers in the fabrication process. As a result, a reduction in the thicknesses of MoSe2 layers is achieved. In terms of energy conversion efficiency (η), CZTSe solar cells grown on Mo/SiOxNy back contacts suffer a deterioration as the SiOxNy layers get thicker. CZTSe solar cells grown on Mo/SiOxNy/Mo back contacts preserve their efficiencies at ≈ 11% with thin 10 nm SiOxNy layers.


2017 ◽  
Vol 5 (2) ◽  
pp. 1700645 ◽  
Author(s):  
Zhaojing Zhang ◽  
Liyong Yao ◽  
Yi Zhang ◽  
Jianping Ao ◽  
Jinlian Bi ◽  
...  

2018 ◽  
Vol 8 (3) ◽  
pp. 871-878 ◽  
Author(s):  
Sanjoy Paul ◽  
Sachit Grover ◽  
Ingrid L. Repins ◽  
Brian M. Keyes ◽  
Miguel A. Contreras ◽  
...  

2002 ◽  
Vol 41 (Part 1, No. 5A) ◽  
pp. 2834-2841 ◽  
Author(s):  
Nowshad Amin ◽  
Akira Yamada ◽  
Makoto Konagai

2013 ◽  
Vol 22 (1) ◽  
pp. 83-89 ◽  
Author(s):  
Pedro M. P. Salomé ◽  
Viktor Fjallstrom ◽  
Adam Hultqvist ◽  
Piotr Szaniawski ◽  
Uwe Zimmermann ◽  
...  

2011 ◽  
Vol 57 (1) ◽  
pp. 73-75 ◽  
Author(s):  
M.C. Wang ◽  
T.C. Chang ◽  
S.W. Tsao ◽  
Y.Z. Chen ◽  
S.C. Tseng ◽  
...  

2012 ◽  
Vol 99 ◽  
pp. 349-355 ◽  
Author(s):  
Hao Lin ◽  
Irfan ◽  
Wei Xia ◽  
Hsiang N. Wu ◽  
Yongli Gao ◽  
...  

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