On the nitroxide mediated polymerization of methacrylates derived from bio-sourced terpenes in miniemulsion, a step towards sustainable products

2020 ◽  
Vol 11 (6) ◽  
pp. 1151-1160 ◽  
Author(s):  
Sayrung Noppalit ◽  
Alexandre Simula ◽  
Laurent Billon ◽  
José M. Asua
Keyword(s):  
Block Copolymers ◽  
Sustainable Products ◽  
Nitroxide Mediated Polymerization

The typical use of toxic solvents, expensive control agents and the need of intermediate purification steps hinders the introduction of bio-sourced monomers into industrially viable block copolymers. This study aims at overcoming these limitations.

Synthesis of poly(methyl methacrylate) and block copolymers by semi-batch nitroxide mediated polymerization

2016 ◽  
Vol 7 (45) ◽  
pp. 6964-6972 ◽  
Author(s):  
N. Ballard ◽  
A. Simula ◽  
M. Aguirre ◽  
J. R. Leiza ◽  
S. van Es ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Polymer Structure ◽  
Solution Polymerization ◽  
Poly Methyl Methacrylate ◽  
Nitroxide Mediated Polymerization

The limits of control of the molecular weight and polymer structure in the semi-batch solution polymerization of methyl methacrylate by NMP are explored.

scholarly journals Nitroxide-mediated polymerization-induced self-assembly of amphiphilic block copolymers with a pH/temperature dual sensitive stabilizer block

2017 ◽  
Vol 8 (27) ◽  
pp. 4014-4029 ◽  
Author(s):  
X. G. Qiao ◽  
P.-Y. Dugas ◽  
B. Charleux ◽  
M. Lansalot ◽  
E. Bourgeat-Lami
Keyword(s):  
Block Copolymers ◽  
Emulsion Polymerization ◽  
Self Assembly ◽  
Small Proportion ◽  
Amphiphilic Block Copolymers ◽  
Temperature Responsive ◽  
Responsive Behavior ◽  
Nitroxide Mediated Polymerization

Comb-like P(PEOMA300-co-MAA-co-S)-SG1 macroalkoxyamine terpolymer initiators with dual pH/temperature responsive behavior were synthesized by nitroxide-mediated polymerization and used to control the emulsion polymerization of BMA with a small proportion of styrene.

Synthesis of amphiphilic diblock copolymers derived from renewable dextran by nitroxide mediated polymerization: towards hierarchically structured honeycomb porous films

2014 ◽  
Vol 5 (18) ◽  
pp. 5310-5319 ◽  
Author(s):  
Senbin Chen ◽  
Marie-Hélène Alves ◽  
Maud Save ◽  
Laurent Billon
Keyword(s):  
Block Copolymers ◽  
Diblock Copolymers ◽  
Porous Films ◽  
Amphiphilic Diblock Copolymers ◽  
Nitroxide Mediated Polymerization ◽  
Linear Block

A novel dextran-SG1 macro-alkoxyamine was designed to afford amphiphilic linear block copolymers synthesized by nitroxide mediated polymerization toward the formation of hierarchically structured bio-resourced honeycomb films.

scholarly journals Nitroxide-Mediated Polymerization-Induced Self-Assembly of Block Copolymers at the Surface of Silica Particles: Toward New Hybrid Morphologies

2017 ◽  
Vol 50 (10) ◽  
pp. 3796-3806 ◽  
Author(s):  
X. G. Qiao ◽  
O. Lambert ◽  
J.-C. Taveau ◽  
P.-Y. Dugas ◽  
B. Charleux ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Self Assembly ◽  
Silica Particles ◽  
Nitroxide Mediated Polymerization
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