Incorporating glycidyl methacrylate into block copolymers using poly(methacrylate-ran -styrene) macroinitiators synthesized by nitroxide-mediated polymerization

2009 ◽  
Vol 47 (10) ◽  
pp. 2574-2588 ◽  
Author(s):  
Benoît Lessard ◽  
Milan Marić
Keyword(s):  
Block Copolymers ◽  
Glycidyl Methacrylate ◽  
Nitroxide Mediated Polymerization

On the nitroxide mediated polymerization of methacrylates derived from bio-sourced terpenes in miniemulsion, a step towards sustainable products

2020 ◽  
Vol 11 (6) ◽  
pp. 1151-1160 ◽  
Author(s):  
Sayrung Noppalit ◽  
Alexandre Simula ◽  
Laurent Billon ◽  
José M. Asua
Keyword(s):  
Block Copolymers ◽  
Sustainable Products ◽  
Nitroxide Mediated Polymerization

The typical use of toxic solvents, expensive control agents and the need of intermediate purification steps hinders the introduction of bio-sourced monomers into industrially viable block copolymers. This study aims at overcoming these limitations.

Facile synthesis of well-controlled poly(glycidyl methacrylate) and its block copolymers via SARA ATRP at room temperature

2015 ◽  
Vol 6 (10) ◽  
pp. 1875-1882 ◽  
Author(s):  
Francisco Catalão ◽  
Joana R. Góis ◽  
A. S. M. Trino ◽  
Arménio C. Serra ◽  
Jorge F. J. Coelho
Keyword(s):  
Block Copolymers ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Catalytic System ◽  
Glycidyl Methacrylate ◽  
Room Temperature ◽  
Atom Transfer ◽  
Facile Synthesis

The detailed synthesis of poly(glycidyl methacrylate) (PGMA) by atom transfer radical polymerization (ATRP) using a catalytic system of Fe(0)/Cu(ii)Br2 at room temperature is reported.

Functionalization-induced self-assembly under ambient conditions via thiol-epoxide “click” chemistry

2020 ◽  
Vol 11 (2) ◽  
pp. 298-303 ◽  
Author(s):  
David H. Howe ◽  
Ken J. Jenewein ◽  
James L. Hart ◽  
Mitra L. Taheri ◽  
Andrew J. D. Magenau
Keyword(s):  
Block Copolymers ◽  
Click Chemistry ◽  
Self Assembly ◽  
Glycidyl Methacrylate ◽  
Polymer Micelles ◽  
Ambient Conditions

Polymer micelles were formed using thiol-epoxide “click” chemistry to trigger functionalization-induced self-assembly (FISA) of block copolymers by modifying a reactive glycidyl methacrylate block with solvophobes.

Modification of glycidyl methacrylate based block copolymers and their aqueous solution behaviours

2019 ◽  
Vol 110 ◽  
pp. 364-377 ◽  
Author(s):  
Gökhan Kocak ◽  
Gökhan Solmaz ◽  
Cansel Tuncer ◽  
Vural Bütün
Keyword(s):  
Aqueous Solution ◽  
Block Copolymers ◽  
Glycidyl Methacrylate

Synthesis of poly(methyl methacrylate) and block copolymers by semi-batch nitroxide mediated polymerization

2016 ◽  
Vol 7 (45) ◽  
pp. 6964-6972 ◽  
Author(s):  
N. Ballard ◽  
A. Simula ◽  
M. Aguirre ◽  
J. R. Leiza ◽  
S. van Es ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Polymer Structure ◽  
Solution Polymerization ◽  
Poly Methyl Methacrylate ◽  
Nitroxide Mediated Polymerization

The limits of control of the molecular weight and polymer structure in the semi-batch solution polymerization of methyl methacrylate by NMP are explored.

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